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31.
由“从正则分布出发,在小涨落近似下得出的能量涨落分布公式”求得的能量涨落的二次矩与直接由正则分布求得的二次矩完全相同,但分别由二求得的高次矩并不完全相同。 相似文献
32.
Reaction diffusion systems on cylindrical domains with terms that vary rapidly and periodically in the unbounded direction can be analyzed by averaging techniques. Here, using iterated normal form transformations and Gevrey regularity of bounded solutions, we prove a result on exponential averaging for such systems, i.e., we show that traveling wave solutions can be described by a spatially homogenous equation and exponentially small remainders. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
33.
本文设计了直接蒸馏-顶空分析-预柱低温富集-毛细管色谱-质谱联机分析技术,有效地提取、浓缩、分离和鉴定了藿香的香气成分。实现了天然产物微量多组分的联机快速分析。并首次在霍香的头香成分中发现了乙酸甲酯、3-甲基丁酮、3-甲基-3-丁烯酮等一系列分子量小、易挥发的成分。 相似文献
34.
This paper overviews the electro-optical and thermal performances of different types of infrared detectors manufactured by
Sofradir. The detector’s fabrication processes and detector’s performance are shortly described. New staring arrays are more
compact and offer system solutions required by infrared market. Special attention is directed to some reliability advantages
of new dewar design. Finally, the development trends for highest resolution infrared detector are discussed.
The paper presented there appears in Infrared Photoelectronics, edited by Antoni Rogalski, Eustace L. Dereniak, Fiodor F. Sizov, Proc. SPIE Vol. 5957, 59570U (2005). 相似文献
35.
David Loffreda 《Surface science》2006,600(10):2103-2112
Adsorption thermodynamics based on density functional theory (DFT) calculations are exposed for the interaction of several multifunctional molecules with Pt and Au(1 1 0)-(1 × 2) surfaces. The Gibbs free adsorption energy explicitly depends on the adsorption internal energy, which is derived from DFT adsorption energy, and the vibrational entropy change during the chemisorption process. Zero-point energy (ZPE) corrections have been systematically applied to the adsorption energy. Moreover the vibrational entropy change has been computed on the basis of DFT harmonic frequencies (gas and adsorbed phases, clean surfaces), which have been extended to all the adsorbate vibrations and the metallic surface phonons. The phase diagrams plotted in realistic conditions of temperature (from 100 to 400 K) and pressure (0.15 atm) show that the ZPE corrected adsorption energy is the main contribution. When strong chemisorption is considered on the Pt surface, the multifunctional molecules are adsorbed on the surface in the considered temperature range. In contrast for weak chemisorption on the Au surface, the thermodynamic results should be held cautiously. The systematic errors of the model (choice of the functional, configurational entropy and vibrational entropy) make difficult the prediction of the adsorption-desorption phase boundaries. 相似文献
36.
37.
Adsorption structures of the pentacene (C22H14) molecule on the clean Si(0 0 1)-2 × 1 surface were investigated by scanning tunneling microscopy (STM) in conjunction with density functional theory calculations and STM image simulations. The pentacene molecules were found to adsorb on four major sites and four minor sites. The adsorption structures of the pentacene molecules at the four major sites were determined by comparison between the experimental and the simulated STM images. Three out of the four theoretically identified adsorption structures are different from the previously proposed adsorption structures. They involve six to eight Si-C covalent chemical bonds. The adsorption energies of the major four structures are calculated to be in the range 67-128 kcal/mol. It was also found that the pentacene molecule hardly hopped on the surface when applying pulse bias voltages on the molecule, but was mostly decomposed. 相似文献
38.
Shoaib Ahmad 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):309-318
The mechanisms and processes of the formation of the regenerative soot in a graphite hollow cathode discharge that produces
and emits carbon clusters are presented. Mass spectrometry with a specially designed E×B velocity filter analyzes the entire range of the charged clusters from C
1 to ∼C
4300. The state of the carbon vapour within the source is evaluated by using the characteristic line emissions from the carbonaceous
discharge whose formative mechanisms depend upon the kinetic and potential sputtering of the sooted cathode. The carbonaceous
discharge generates atomic and ionic C and its clusters C
m (m≥ 2), noble gas metastable atoms and ions, energetic electrons and photons in the cavity of the graphite hollow cathode. The
parameters of soot formation and its recycling depend critically on the discharge parameters, the geometry of the hollow cathode
and 3D profile of the cusp magnetic field contours.
Received 2nd July 2001 and Received in final form 10 September 2001 相似文献
39.
偶氮苯衍生物三阶非线性的四波混频研究 总被引:7,自引:0,他引:7
用皮秒Nd:YAG激光器的倍频光(532nm)对具有离域π-共轭电子云结构的偶氮苯类样品材料作简并四波混频补给,测得三阶非线性电极化率x^(3)和它们的时间响应分别为10^-9esu和20ps,并对影响x^(3)的瞬时光栅作用和x^(3)的响应时间人了讨论。 相似文献
40.
Xia Chen 《Journal of Theoretical Probability》2006,19(3):721-739
We establish moderate and small deviations for the ranges of integer valued random walks. Our theorems apply to the limsup
and the liminf laws of the iterated logarithm.
We establish moderate and small deviations for the ranges of integer valued random walks. Our theorems apply to the limsup
and the liminf laws of the iterated logarithm. 相似文献