全文获取类型
收费全文 | 756篇 |
免费 | 139篇 |
国内免费 | 226篇 |
专业分类
化学 | 782篇 |
晶体学 | 17篇 |
力学 | 4篇 |
综合类 | 9篇 |
数学 | 4篇 |
物理学 | 305篇 |
出版年
2024年 | 4篇 |
2023年 | 21篇 |
2022年 | 41篇 |
2021年 | 49篇 |
2020年 | 48篇 |
2019年 | 46篇 |
2018年 | 49篇 |
2017年 | 59篇 |
2016年 | 74篇 |
2015年 | 54篇 |
2014年 | 70篇 |
2013年 | 123篇 |
2012年 | 48篇 |
2011年 | 45篇 |
2010年 | 33篇 |
2009年 | 38篇 |
2008年 | 38篇 |
2007年 | 39篇 |
2006年 | 28篇 |
2005年 | 23篇 |
2004年 | 21篇 |
2003年 | 20篇 |
2002年 | 17篇 |
2001年 | 19篇 |
2000年 | 11篇 |
1999年 | 11篇 |
1998年 | 13篇 |
1997年 | 8篇 |
1996年 | 10篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1982年 | 6篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 3篇 |
排序方式: 共有1121条查询结果,搜索用时 15 毫秒
61.
利用超声-水热法、使用油酸钠辅助合成钨酸铋(Bi2WO6)量子点/纳米片修饰的石墨相氮化碳(g-C3N4)(Bi2WO6/g-C3N4)复合光催化剂。 通过X射线粉末衍射(XRD)、透射电子显微镜(TEM)、傅里叶变换红外光谱(FT-IR)、紫外可见漫反射光谱(UV-Vis DRS)、N2吸附-脱附等技术手段获得Bi2WO6/g-C3N4催化剂的组成、结构和光吸收性能,分析合成机理。 以罗丹明B(RhB)水溶液为模拟污染物,考察Bi2WO6/g-C3N4复合催化剂的可见光催化活性。 结果表明:g-C3N4和Bi2WO6的质量比为3:7的Bi2WO6/g-C3N4-30具有最有效的异质界面,电化学阻抗和光电流测试结果显示该催化剂的光生载流子传输速率快、复合率低,可见光照射120 min对RhB的降解率达到95.8%;通过活性物质捕捉实验获知光生空穴是光催化反应中的主要活性物质,分析异质界面对光催化活性的影响,进而提出光催化反应机理。 相似文献
62.
Wei-Chen Cui Wenxuan Zhao Ming Gao Wei Liu Dr. Shaozhong Wang Prof. Yong Liang Prof. Zhu-Jun Yao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16506-16510
A visible-light-driven radical silylative cyclization of aza-1,6-dienes featuring an acrylonitrile or acrylate moiety and an electron-neutral olefin was developed, which allows for stereoselective synthesis of densely functionalized piperidines in a highly atom-economical manner. Depending on the substitution pattern of the electron-neutral olefin, poor-to-excellent diastereoselectivity was observed. It was suggested that the 6-exo-trig cyclization was initiated by a chemoselective addition of silyl radical toward electron-deficient olefin and the geometry of the remaining olefin is closely associated with the cis-stereoselectivity. DFT calculations supported that a transition state with a cyano group locating at the axial position of the forming piperidine ring might be involved, in which either the increase of 1,3-diaxial repulsion or the lack of hydrogen bonding interaction will diminish diastereoselectivity. 相似文献
63.
Several new methyl-substituted indenyl ferrocenes were prepared by metathesis reactions of the indenide (generated from the appropriate indene with BuLi) with ferrous chloride. The indenides used to prepare new ferrocenes were: 2-methyl-, 1,2-dimethyl-, 4,7-dimethyl-, 1,4,7-trimethyl-, and 1,3,4,7-tetramethyl-indenide. These indenyl ferrocenes, along with those prepared from indenide, 1-methylindenide, and 1,3-dimethylindenide, were then characterized by 1H and 13C NMR, UV/visible spectroscopy, cyclic voltammetry and mass spectrometry. The cyclic voltammetry showed an additive relationship between oxidation potential and the number of methyl groups which is also position-dependent, whereas the UV/visible spectra showed two absorptions essentially unaffected by methyl substitution. Additionally, bis(2-methylindenyl)iron(II) and bis(4,7-dimethylindenyl)iron(II) were characterized by X-ray crystallography. 相似文献
64.
Hanghang Zhou Dr. Ying Luo Dr. Jun Xu Dr. Lidan Deng Prof. Dr. Zheng Wang Prof. Dr. Hong He 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(68):e202202044
Cubic-like CaTaO2N photocatalysts with high crystallinity and uniform particle size were successfully prepared by the flux-assisted nitridation method. The growth of CaTaO2N single crystals under different synthesis conditions was systematically investigated to understand the effects of the crystallinity and optical property on photocatalytic performance of CO2 reduction. Moreover, the modification of CaTaO2N single crystals with core-shell Ni−Ag bicomponent cocatalyst by two-step decoration process gave a 2.4 times higher amount of CO evolution than the deposition of sole Ag cocatalyst, because of the synergistic effects of bicomponent cocatalyst on the interfacial electron transfer and surface catalytic process. This study provides a valuable way to construct high-crystalline photocatalysts with effective bicomponent cocatalyst for visible-light-driven CO2 reduction with H2O. 相似文献
65.
Jonathan Berry Prof. Dr. Thisbe K. Lindhorst Dr. Guillaume Despras 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(39):e202200354
Azobenzene photoswitches are valuable tools for controlling properties of molecular systems with light. We have been investigating azobenzene glycoconjugates to probe carbohydrate-protein interactions and to design glycoazobenzene macrocycles with chiroptical and physicochemical properties modulated by light irradiation. To date, direct conjugation of glycosides to azobenzenes was performed by reactions providing target compounds in limited yields. We therefore sought a more effective and reliable coupling method. In this paper, we report on a straightforward thioarylation of azobenzene derivatives with glycosyl thiols as well as other thiols, thereby increasing the scope of azobenzene conjugation. Even challenging unsymmetrical conjugates can be achieved in good yields via sequential or one-pot procedures. Importantly, red-shifted azoswitches, which are addressed with visible light, were easily functionalized. Additionally, by oxidation of the sulfide bridge to the respective sulfones, both the photochromic and the thermal relaxation properties of the core azobenzene can be tuned. Utilizing this option, we realized orthogonal three-state photoswitching in mixtures containing two distinct azobenzene thioglycosides. 相似文献
66.
Donglei Wei Huili Li Chuanqing Yang Jianmin Fu Hou Chen Liangjiu Bai Wenxiang Wang Huawei Yang Lixia Yang Ying Liang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(10):1588-1594
Acridone as a new kind of visible light photocatalyst has been developed to catalyze metal free atom transfer radical polymerization (ATRP). The photocatalyst possess low excited state potential as can undergo an oxidative quenching pathway to initiate ATRP of vinyl monomers. Kinetic study and light on/off reaction demonstrate the “living”/controlled nature of the polymerization by light. Block copolymers can be achieved by using PMMA as macroinitiator to reinitiate polymerization of other vinyl monomers, which shows highly preserved Br chain-end functionality in the synthesized polymers. Moreover, the polymerization can be conducted under air atmosphere as most photocatalysts need anaerobic condition, which may give inspiration of further application of this kind of photocatalyst. 相似文献
67.
Muna E. Raypah Ahmad Fairuz Omar Jelena Muncan Musfirah Zulkurnain Abdul Rahman Abdul Najib 《Molecules (Basel, Switzerland)》2022,27(7)
Honey is a natural product that is considered globally one of the most widely important foods. Various studies on authenticity detection of honey have been fulfilled using visible and near-infrared (Vis-NIR) spectroscopy techniques. However, there are limited studies on stingless bee honey (SBH) despite the increase of market demand for this food product. The objective of this work was to present the potential of Vis-NIR absorbance spectroscopy for profiling, classifying, and quantifying the adulterated SBH. The SBH sample was mixed with various percentages (10–90%) of adulterants, including distilled water, apple cider vinegar, and high fructose syrup. The results showed that the region at 400–1100 nm that is related to the color and water properties of the samples was effective to discriminate and quantify the adulterated SBH. By applying the principal component analysis (PCA) on adulterants and honey samples, the PCA score plot revealed the classification of the adulterants and adulterated SBHs. A partial least squares regression (PLSR) model was developed to quantify the contamination level in the SBH samples. The general PLSR model with the highest coefficient of determination and lowest root means square error of cross-validation ( and ) was acquired. The aquaphotomics analysis of adulteration in SBH with the three adulterants utilizing the short-wavelength NIR region (800–1100 nm) was presented. The structural changes of SBH due to adulteration were described in terms of the changes in the water molecular matrix, and the aquagrams were used to visualize the results. It was revealed that the integration of NIR spectroscopy with aquaphotomics could be used to detect the water molecular structures in the adulterated SBH. 相似文献
68.
Varsha R. Mehto Akanksha Mehto Dhirendra Kumar Gupta Rajendra Kumar Pandey 《中国化学会会志》2016,63(11):935-946
This paper presents our results on the successful fabrication of HCl‐doped polyaniline (PANI)/ZnO nanocomposites via an electrochemical synthesis route. Different weight percents of ZnO nanoparticles were uniformly dispersed in the PANI matrix. The interaction between the dispersed ZnO nanoparticle and PANI was studied using X‐ray diffraction, ultraviolet–visible absorption spectroscopy, photoluminescence (PL) spectroscopy, X‐ray photoelectron spectroscopy, atomic force microscopy, thermogravimetry, and transmission electron microscopy. It is shown that the doping state of the PANI/ZnO nanocomposite is highly improved as compared to that of PANI. The dispersed PANI/ZnO nanocomposites exhibit enhanced PL behavior and thermal stability. 相似文献
69.
70.
乙烯在纳米催化剂InVO4-TiO2上的可见光降解 总被引:1,自引:0,他引:1
The InVO4-TiO2 nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degradation of ethylene in the gaseous phase under visible light irradiation (λ>450 nm). The results indicate that both of pure TiO2 and InVO4 or their simple mixture show no photocatalytic activities for degradation of ethylene under visible light irradiation. However, as-synthesized InVO4-TiO2 catalyzes the degradation of ethylene into CO2 under visible light irradiation. In addition, the interaction between InVO4 and TiO2 results in some structural distortion to all the crystal forms of TiO2 in as-synthesized catalyst InVO4-TiO2. 相似文献