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131.
132.
New metal based triazoles (1–12) have been synthesized by the interaction of novel Schiff base ligands (L1–L3) with the Co(II), Ni(II), Cu(II) and Zn(II) metal ions. The Schiff base ligands and their all metal(II) complexes have been thoroughly characterized using various physical, analytical and spectroscopic techniques. In vitro bacterial and fungal inhibition studies were carried out to examine the antibacterial and antifungal profile of the Schiff bases in comparison to their metal(II) complexes against two Gram‐positive, four Gram‐negative and six fungal strains. The bioactivity data showed the metal(II) complexes to have more potent antibacterial and antifungal activity than their uncomplexed parent Schiff bases against one or more bacterial and fungal species. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
133.
Abstract Poly(lactic acid) macromonomers with methacrylate terminal functionality have been synthesized from the cyclic dimer of lactic acid (referred to as lactide) with 2-hydroxyethyl methacrylate (HEMA) as initiator and stannous 2-ethyl hexanoate as catalyst. The macromonomers were characterized with FT-IR, NMR, GPC, DSC, WAXS, and CD. The molecular weights of the macromonomers ranging from M n 1425 to 19,169 are predictable from the lactide/HEMA ratio in the polymerization feeds. The properties of the macromonomers vary with the stereochemistry of the lactide and the composition. Circular dichroism measurements demonstrate that there is little racemization during polymerization. 相似文献
134.
Andreas Uwe Meyer Karolína Straková Dr. Tomáš Slanina Prof. Dr. Burkhard König 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(25):8694-8699
Alkyl‐ and aryl vinyl sulfones were obtained by eosin Y (EY)‐mediated visible‐light photooxidation of sulfinate salts and the reaction of the resulting S‐centered radicals with alkenes. Optimized reaction conditions, the sulfinate and alkene scope, and X‐ray structural analyses of several reaction products are provided. A detailed spectroscopic study explains the reaction mechanism, which proceeds through the EY radical cation as key intermediate oxidizing the sulfinate salts. 相似文献
135.
N-heterocyclic carbenes (NHCs) have been utilized as Brønsted base to catalyze the hydrothiolation reaction between alkynes and thiols to produce the vinyl sulfides stereoselectively. 相似文献
136.
Yu Shinke Arihiro Kanazawa Shokyoku Kanaoka Sadahito Aoshima 《Journal of polymer science. Part A, Polymer chemistry》2012,50(24):5041-5048
Living cationic polymerization of a vinyl ether with a naphthyl group [2‐(2‐naphthoxy)ethyl vinyl ether, βNpOVE] was achieved using base‐assisting initiating systems with a Lewis acid. The Et1.5AlCl1.5/1,4‐dioxane or ethyl acetate system induced the living cationic polymerization of βNpOVE in toluene at 0 °C. The living nature of this reaction was confirmed by a monomer addition experiment, followed by 1H NMR and matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry (MALDI‐TOF‐MS) analyses. In contrast, the polymerization of αNpOVE was not fully controlled; under similar conditions, it produced polymers with broad molecular weight distributions. The 1H NMR and MALDI‐TOF‐MS spectra of the resultant poly(αNpOVE) revealed that the products had undesirable structures derived from Friedel–Crafts alkylation. The higher reactivity of αNpOVE in electrophilic substitution reactions, such as the Friedel–Crafts reaction, was attributable to the greater electron density of the naphthyl ring, which was calculated based on frontier orbital theory. The naphthyl groups significantly affected the properties of the resultant polymer. For example, the glass transition temperatures (Tg) of poly(NpOVE)s are higher by approximately 40 °C than that of poly(2‐phenoxyethyl vinyl ether). © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
137.
Reiko Saito Yoichi Saito Hideyasu Kamoshita Yoichi Tokubuchi 《Journal of polymer science. Part A, Polymer chemistry》2012,50(16):3444-3451
Highly heterotactic poly(4‐vinyl pyridine)s (P4VPs) with the fraction of mr content (fmr) > 0.81 were synthesized by free radical polymerization of 4‐vinyl pyridine (4VP) with randomly methylated β‐cyclodextrin (β‐RMCD) in acidic aqueous media of HNO3 and CF3COOH at 40 °C. The heterotacticity of P4VP strongly depended on the neutralization of 4VP. The complete neutralization of 4VP with HNO3 or CF3COOH increased the heterotacticity of P4VP, whereas atactic P4VP was obtained in water. The partial decomposition of β‐RMCD by HCl reduced the heterotacticity of P4VP (fmr ≈ 0.74). The structures of inclusion complexed monomers were determined by Job's plot, 2D NMR with nuclear Overhauser enhancement spectroscopy analyses, and simulation by MM2. The 1:2 complex with [β‐RMCD]:[4VP] with meso placement of 4VPs in β‐RMCD was formed when 4VP was completely neutralized with acid, whereas the 1:1 complex was formed in water. The mechanism of heterospecific control by using β‐RMCD was proposed. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
138.
Fengyang Deng Bin Xu Yong Gao Zheng Liu Duanguang Yang Huaming Li 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3767-3774
In this study, a series of linear poly(triazole)s (PTAs) were successfully synthesized by the metal‐ and solvent‐free, thermal click polymerization of diazide and dialkyne (A2 + B2) monomers. All click polymerizations proceeded smoothly at 80 °C in an open atmosphere without protection from oxygen and moisture. After being polymerized for 36 h, the crude polymer was further fractionated into three fractions using a multistep precipitation method. By selectively choosing precipitating agents, this process produced poly(triazole) fractions with low polydispersity index (<1.30). The resulting PTAs are soluble in common organic solvents and stable at a temperature up to 320 °C. Furthermore, the methyl benzoate moieties in the main chain can serve as useful building blocks for further postpolymerization functionalization, yielding 1,2,4‐triazole derivatives. This functionalization strategy offers potential for the development of novel triazole‐based materials. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
139.
Stephen M. June Philippe Bissel Timothy E. Long 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3797-3805
Copper(I) catalyzed azide‐alkyne 1,3‐Huisgen cycloaddition reaction afforded the synthesis of triazole‐containing polyesters and segmented block copolyesters at moderate temperatures. Triazole‐containing homopolyesters exhibited significantly increased (~40 °C) glass transition temperatures (Tg) relative to high temperature, melt synthesis of polyesters with analogous structures. Quantitative synthesis of azido‐terminated poly(propylene glycol) (PPG) allowed for the preparation of segmented polyesters, which exhibited increased solubility and mechanical ductility relative to triazole‐containing homopolyesters. Differential scanning calorimetry demonstrated a soft segment (SS) Tg near ?60 °C for the segmented polyesters, consistent with microphase separation. Tensile testing revealed Young's moduli ranging from 7 to 133 MPa as a function of hard segment (HS) content, and stress at break values approached 10 MPa for 50 wt % HS segmented click polyesters. Dynamic mechanical analysis demonstrated an increased rubbery plateau modulus with increased HS content, and the Tg's of both the SS and HS did not vary with composition, confirming microphase separation. Atomic force microscopy also indicated microphase separated and semicrystalline morphologies for the segmented click polyesters. This is the first report detailing the preparation of segmented copolyesters using click chemistry for the formation of ductile membranes with excellent thermomechanical response. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
140.
Chia‐Shing Wu Ya‐Ju Yang Szu‐Wen Fang Yun Chen 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3875-3884
This study reports the synthesis, curing, and optoelectronic properties of a solution‐processable, thermally cross‐linkable electron‐ and hole‐blocking material containing fluorene‐core and three periphery N‐phenyl‐N‐(4‐vinylphenyl)benzeneamine ( FTV ). The FTV exhibited good thermal stability with Td above 478 °C in nitrogen atmosphere. The FTV is readily cross‐linked via terminal vinyl groups by heating at 160 °C for 30 min to obtain homogeneous film with excellent solvent resistance. Multilayer PLED device [ITO/PEDOT:PSS/cured‐ FTV /MEH‐PPV/Ca (50 nm)/Al (100 nm)] was successfully fabricated using solution processed. Inserting cured‐ FTV is between PEDOT:PSS and MEH‐PPV results in simultaneous reduction in hole injection from PEDOT:PSS to MEH‐PPV and blocking in electron transport from MEH‐PPV to anode. The maximum luminance and maximum current efficiency were enhanced from 1810 and 0.27 to 4640 cd/m2 and 1.08 cd/A, respectively, after inserting cured‐ FTV layer. Current results demonstrate that the thermally cross‐linkable FTV enhances not only device efficiency but also film homogeneity after thermal curing. FTV is a promising electron‐ and hole‐blocking material applicable for the fabrication of multilayer PLEDs based on PPV derivatives. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 000: 000–000, 2012 相似文献