Trace 1300气相色谱仪故障排查与期间核查

使用赛默飞Trace 1300气相色谱仪进行环境样品分析过程中,出现了FID信号变弱、点火困难的现象,严重影响检测数据的准确性,干扰正常分析工作。从样品性质、仪器方法的设置、气路系统以及检测系统进行故障排查,确定故障原因为FID喷嘴堵塞,点火线圈锈蚀严重。对维修好后的气相色谱仪进行期间核查,核查结果:基线噪声为0.066 pA,基线漂移(30 min)为0.321 pA,FID检测限为0.094 1 ng/s,定性重复性为0.062%,定量重复性为1.41%,均满足技术指标要求。     

Comparison of different gas models to calculate the spring force of a hydropneumatic suspension

When developing any simulation model some compromise must be made between computational efficiency and the accuracy of the model. This study compares the performance of three ideal gas (IG) law variations (IG with the energy equation (EE), isothermal and adiabatic), and two real gas approaches (Benedict Webb Rubin (BWR) equation with and without the EE) to model the spring force of a hydropneumatic suspension. These models are compared with experimental data obtained from laboratory tests on a single hydropneumatic suspension unit. Both the BWR and IG models with the EE offer a significant improvement in correlation compared to the models without the EE. The real gas BWR approach offers a small improvement over the IG approach under the test conditions. The best (BWR with EE) and worst (IG isothermal) models are then used to model the spring forces in a full vehicle model of a 4 × 4 Sports Utility vehicle (SUV). The data is again compared with experimental results and the BWR model with the EE correlates significantly better than the IG isothermal model. It is thus concluded that the inclusion of the EE will yield significantly better results and it should only be omitted if the parameters investigated are not sensitive to errors in the spring model.     

一种拓宽凸球面压电换能器指向性的方法

利用有限元和边界元耦合的方法对涂环氧树脂后的压电陶瓷凸球面换能器进行了指向性仿真计算,发现这种形式的换能器具有较宽的指向性开角。实验测量结果证明了上述结论。     

两相自然循环系统静态流量漂移及其实验验证

本文基于均相模型,运用非线性分岔理论,计算预测了两相自然循环系统静态分岔(流量漂移)解图。定义了对应系统静态分岔点的理论最大输热能力限,讨论了实际流量漂移发生点。同时分析了系统的迟滞效应及系统压力、入口阻力等对分岔解图的影响。首次用针对性实验验证了两相自然循环静态分岔及其迟滞现象;对有关参数效应亦进行了实验验证研究。     

Automated structure verification based on 1H NMR prediction

A unique opportunity exists when an experimental NMR spectrum is obtained for which a specific chemical structure is anticipated. A process of Verification--the confirmation of a postulated structure--is now possible, as opposed to Elucidation-the de novo determination of a structure. A method for automated structure verification is suggested, which compares the chemical shifts, intensities and multiplicities of signals in an experimental 1H NMR spectrum with those from a predicted spectrum for the proposed structure. A match factor (MF) is produced and used to classify the spectrum-structure match into one of three categories, correct, ambiguous, or incorrect. The verification result is also augmented by the spectrum assignment obtained as part of the verification process. This method was tested on a set of synthetic spectra and several sets of experimental spectra, all of which were automatically prepared from raw data. Taking into account even the most problematic structures, with many labile protons present and poor prediction accuracy, 50% of all spectra can still be automatically verified without any false positives or negatives. In a blind test on a typical set of data, it is shown that fewer than 31% of the structures would need manual evaluation. This means that a system is possible whereby 69% of the spectra are prepared and evaluated automatically, and never need to be seen or evaluated by a human.     

About the formulation,verification and validation of the hypersonic flow solver Eilmer

We describe the formulation of the gas dynamics and high‐temperature thermochemical modules of the Eilmer code, an open‐source Navier–Stokes solver for transient compressible flow in two and three dimensions. The core gas dynamics formulation is based on finite‐volume cells, and the thermochemical effects are handled with specialised updating schemes that are coupled into the overall time‐stepping scheme. Verification of the code is explored via a number of case studies that use analytic and semi‐analytic solutions as comparison. These include both smooth and shocked flows and are used to demonstrate the order of spatial accuracy of the code. Cases include manufactured solutions for rather abstract inviscid and viscous flow, an idealised detonation wave supported by a curved body, and the transient flow of an idealised but high‐performance shock tube. Validation of the inviscid gas dynamics and thermochemical models is then explored using data from a selection of experimental studies. These studies include ballistic range experiments with chemically‐inert noble gases and high‐temperature chemically‐reacting air. These comparisons show that the code performs well and they provide a lesson in considering a range of experimental data rather than relying upon isolated data points for validation. These verification and validation cases are described in full detail and will be useful for other code developers of high‐temperature compressible flow solvers. Copyright © 2013 John Wiley & Sons, Ltd.     

基于VMM的SATA控制器功能验证

针对专用集成电路(ASIC)设计中功能验证的效率和完备性问题,以验证方法学手册(VMM)为基础搭建了串行高级技术附件(SATA)控制器分层式验证平台.验证组件的实现大量重用验证知识产权核(VIP),在采用随机激励的基础上以覆盖率统计驱动验证的过程,根据SATA控制器的功能设计记分牌进行结果的自动化比对.实验结果表明,这些方法提高了功能验证的效率,保证了验证的完备性,最终功能覆盖率达到98.25%.     

机载光电/惯性组合着舰导引算法的地面验证

研究了机载光电/惯性组合着舰导引新算法,综合光电探测系统获得的跑道成像信息和机载惯性导航信息,建立导引参数与成像信息之间的数学模型,利用最小二乘法估计舰/机相对位姿,补偿舰船纵摇、横摇及沉浮运动并预测舰载机着舰位置,以实现近程导引舰载机半自动或自动安全着舰。在算法研究的基础上,进行了地面车载验证实验。实验采用缩比方案,以着降跑道模拟器模拟运动中的着降跑道。试验车模拟舰载机,通过相对位姿关系的一致性模拟着舰过程。试验结果验证了着舰导引系统方案的可行性和有效性,为飞行实验奠定技术基础,有利于提高其安全性。     

8mm波段含水量对砂土辐射特性影响研究

毫米波技术应用的基础是物体在毫米波波段的辐射特性的差异,但现阶段物体在毫米波波段的辐射特性的研究缺乏相关理论和试验验证支撑,因此进行了8mm波段砂土辐射特性和含水量相关关系的建模和仿真研究,通过菲涅尔折射定律及理想介质面波的连续性推导出了理想介质面的反射率计算公式,然后利用该公式进行了8mm波段水面辐射特性和含水量对砂土辐射特性影响的仿真,最后通过测量和计算增加砂土含水量对砂土辐射特性影响的定性试验进行仿真结果的定性验证。试验结果和仿真结果一致,砂土随着含水量的增加发射率在下降,砂土的亮温在下降,通过这一结论可以通过砂土亮温的变化定性反演出砂土含水量的变化,从而为毫米波技术在监测含水量等方面的应用提供一定的理论研究和试验验证支撑。     

基于虚拟现实的动车组维修性验证系统研究与设计

针对动车组维修性验证方法不足的问题,提出了采用虚拟仿真手段对维修性进行验证的方法;结合动车组系统的特点,对基于虚拟现实的动车组维修性验证系统进行了方案设计,给出了维修性验证具体流程,研究了三维虚拟样机建模的基本方法;虚拟维修性验证系统有效提高了动车组维修性设计效率,缩短了研制周期,是一种实现动车组维修性并行优化设计的有效方法。