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181.
I. Capek J. Chudej S. Janí
kov 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):804-820
The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (Rp) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the Rp versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003 相似文献
182.
183.
Shiyue Fang 《Tetrahedron letters》2004,45(43):7987-7990
A reversible biotinylation phosphoramidite was synthesized and incorporated onto the 5′-end of an oligoribonucleotide on a solid phase synthesizer. After cleavage and deprotection, the crude synthetic oligomer mixture was incubated with NeutrAvidin® coated microspheres, and the failure sequences removed by washing with a buffer followed by treating the microspheres with tetrabutylammonium fluoride to give a high quality unmodified full-length oligoribonucleotide. 相似文献
184.
二维渗流中的最短开穿透 总被引:1,自引:0,他引:1
在二维边渗流模型中,设/rn/=min(/r/:r是正方形「0,n」^2的开穿透),这里/r/表示r的长度,本文证明了在上临界状态有limE/rn//n=λ,在临界状态时,我们对E/n/给出了上界,并对一个rnrn给出了E/rn/的下界。 相似文献
185.
激光相干阵列探测中的二元全息光栅 总被引:2,自引:0,他引:2
从外差阵列探测出发,围绕木振光束整形问题,就计算全息位相光栅在激光相干雷达系统中的应用进行了理论及实施方面的研究,得出较好的结果。 相似文献
186.
注入控制铜蒸气激光方向性时间过程测量 总被引:1,自引:0,他引:1
实验研究了注入控制对铜蒸气激光非稳腔输出光束质量的影响,从输出光发散角时间分辨过程的测量结果说明注入加速被注入腔内激光发散角的减小过程。由于被注入腔内放大自发辐射的存在,为得到较好的注入控制效果,注入光的脉宽和进入被注入腔的延时必须恰当。 相似文献
187.
A method of simulated annealing in optimization of a computer generated holo-gram(CGH)is presented.The characteristics of energy in annealing curve are analyzed.Thecooling schedule such as giving an initial temperature,the temperature function,the numberof interactions and stopping criterion are discussed.As an example,an optimization of phaserelief kinoform,a CGH with multiple phase levels,is implemented. 相似文献
188.
利用相位共轭技术补偿光纤中色散效应的条件 总被引:1,自引:0,他引:1
利用相位共轭器的频率反转特性的,补偿光纤中的色散效应,在理论上和实验上得到了证明.由色散脉冲的傅里叶交换确定了光纤中二次色散效应可以被忽略的条件,得到了共轭器的反射率和带宽与非线性介质的长度L,参数|K|L之间的关系曲线,找到了影响补偿效果的主要因素. 相似文献
189.
用温度场论方法计算了F-L模型在有限温度和密度下的状态方程,分析了压强对净重子数密度的等温线.结果表明,在平均场近似下,F-L模型所给出的退禁闭相变为一级相变. 相似文献
190.
Recent X-ray diffraction studies on α-quartz (SiO2) by Kingmaet al [1], have shown the occurrence of a reversible, crystalline-to-crystalline, phase transition just prior to amorphization
at ≈ 21 GPa. This precursor transition has also been confirmed by our recent molecular dynamics simulation study [2]. In order
to investigate the possibility of a similar behaviour in other isostructural compounds, which also undergo pressure induced
amorphization, α-GeO2 and α-AlPO4 (berlinite form) were studied using energy dispersive X-ray diffraction. In either of these materials, no such phase transition
is detected prior to amorphization. The onset of amorphization and its reversal is found to be time dependent in GeO2. 相似文献