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101.
Synthesis of Single‐Crystalline Spinel LiMn2O4 Nanorods for Lithium‐Ion Batteries with High Rate Capability and Long Cycle Life 下载免费PDF全文
Xiuqiang Xie Dr. Dawei Su Dr. Bing Sun Jinqiang Zhang Prof. Dr. Chengyin Wang Prof. Dr. Guoxiu Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(51):17125-17131
The long‐standing challenge associated with capacity fading of spinel LiMn2O4 cathode material for lithium‐ion batteries is investigated. Single‐crystalline spinel LiMn2O4 nanorods were successfully synthesized by a template‐engaged method. Porous Mn3O4 nanorods were used as self‐sacrificial templates, into which LiOH was infiltrated by a vacuum‐assisted impregnation route. When used as cathode materials for lithium‐ion batteries, the spinel LiMn2O4 nanorods exhibited superior long cycle life owing to the one‐dimensional nanorod structure, single‐crystallinity, and Li‐rich effect. LiMn2O4 nanorods retained 95.6 % of the initial capacity after 1000 cycles at 3C rate. In particular, the nanorod morphology of the spinel LiMn2O4 was well‐preserved after a long‐term cycling, suggesting the ultrahigh structural stability of the single crystalline spinel LiMn2O4 nanorods. This result shows the promising applications of single‐crystalline spinel LiMn2O4 nanorods as cathode materials for lithium‐ion batteries with high rate capability and long cycle life. 相似文献
102.
Assembly of Na3V2(PO4)3 Nanoparticles Confined in a One‐Dimensional Carbon Sheath for Enhanced Sodium‐Ion Cathode Properties 下载免费PDF全文
Dr. Satoshi Kajiyama Dr. Jun Kikkawa Junichi Hoshino Dr. Masashi Okubo Dr. Eiji Hosono 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(39):12636-12640
Structural and morphological control is an effective approach for improvement of electrochemical properties in rechargeable batteries. One‐dimensionally assembled structure composed of NASICON‐type Na3V2(PO4)3 nanoparticles were fabricated through an electrospinning method to meet the requirements for the development of efficient electrode materials in Na‐ion batteries. High‐temperature treatment of electrospun precursor fibers under an argon flow provides a nonwoven fabric of nanowires comprising crystallographically oriented nanoparticles of NASICON‐type Na3V2(PO4)3 within a carbon sheath. The mesostructure comprising NASICON‐type Na3V2(PO4)3 and carbon give a short sodium‐ion transport pass and an efficient electron conduction pass. Electrochemical properties of NASICON‐type Na3V2(PO4)3 are improved on the basis of one‐dimensional nanostructures designed in the present study. 相似文献
103.
Hierarchical Mesoporous SnO Microspheres as High Capacity Anode Materials for Sodium‐Ion Batteries 下载免费PDF全文
Dawei Su Xiuqiang Xie Prof. Guoxiu Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(11):3192-3197
Mesoporous SnO microspheres were synthesised by a hydrothermal method using NaSO4 as the morphology directing agent. Field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and high‐resolution transmission electron microscopy (HRTEM) analyses showed that SnO microspheres consist of nanosheets with a thickness of about 20 nm. Each nanosheet contains a mesoporous structure with a pore size of approximately 5 nm. When applied as anode materials in Na‐ion batteries, SnO microspheres exhibited high reversible sodium storage capacity, good cyclability and a satisfactory high rate performance. Through ex situ XRD analysis, it was found that Na+ ions first insert themselves into SnO crystals, and then react with SnO to generate crystalline Sn, followed by Na–Sn alloying with the formation of crystalline NaSn2 phase. During the charge process, there are two slopes corresponding to the de‐alloying of Na–Sn compounds and oxidisation of Sn, respectively. The high sodium storage capacity and good electrochemical performance could be ascribed to the unique hierarchical mesoporous architecture of SnO microspheres. 相似文献
104.
Synthesis of Two‐Dimensional Transition‐Metal Phosphates with Highly Ordered Mesoporous Structures for Lithium‐Ion Battery Applications 下载免费PDF全文
Dan Yang Dr. Ziyang Lu Dr. Xianhong Rui Xiao Huang Dr. Hai Li Dr. Jixin Zhu Wenyu Zhang Prof. Yeng Ming Lam Prof. Huey Hoon Hng Prof. Hua Zhang Prof. Qingyu Yan 《Angewandte Chemie (International ed. in English)》2014,53(35):9352-9355
Materials with ordered mesoporous structures have shown great potential in a wide range of applications. In particular, the combination of mesoporosity, low dimensionality, and well‐defined morphology in nanostructures may exhibit even more attractive features. However, the synthesis of such structures is still challenging in polar solvents. Herein, we report the preparation of ultrathin two‐dimensional (2D) nanoflakes of transition‐metal phosphates, including FePO4, Mn3(PO4)2, and Co3(PO4)2, with highly ordered mesoporous structures in a nonpolar solvent. The as‐obtained nanoflakes with thicknesses of about 3.7 nm are constructed from a single layer of parallel‐packed pore channels. These uniquely ordered mesoporous 2D nanostructures may originate from the 2D assembly of cylindrical micelles formed by the amphiphilic precursors in the nonpolar solvent. The 2D mesoporous FePO4 nanoflakes were used as the cathode for a lithium‐ion battery, which exhibits excellent stability and high rate capabilities. 相似文献
105.
Organic Dicarboxylate Negative Electrode Materials with Remarkably Small Strain for High‐Voltage Bipolar Batteries 下载免费PDF全文
Dr. Nobuhiro Ogihara Tomomi Yasuda Yoshihiro Kishida Dr. Tetsu Ohsuna Kaito Miyamoto Dr. Nobuko Ohba 《Angewandte Chemie (International ed. in English)》2014,53(43):11467-11472
As advanced negative electrodes for powerful and useful high‐voltage bipolar batteries, an intercalated metal–organic framework (iMOF), 2,6‐naphthalene dicarboxylate dilithium, is described which has an organic‐inorganic layered structure of π‐stacked naphthalene and tetrahedral LiO4 units. The material shows a reversible two‐electron‐transfer Li intercalation at a flat potential of 0.8 V with a small polarization. Detailed crystal structure analysis during Li intercalation shows the layered framework to be maintained and its volume change is only 0.33 %. The material possesses two‐dimensional pathways for efficient electron and Li+ transport formed by Li‐doped naphthalene packing and tetrahedral LiO3C network. A cell with a high potential operating LiNi0.5Mn1.5O4 spinel positive and the proposed negative electrodes exhibited favorable cycle performance (96 % capacity retention after 100 cycles), high specific energy (300 Wh kg?1), and high specific power (5 kW kg?1). An 8 V bipolar cell was also constructed by connecting only two cells in series. 相似文献
106.
Changchang Xu Li Li Fangyuan Qiu Cuihua An Yanan Xu Ying Wang Yijing Wang Lifang Jiao Huatang Yuan 《天然气化学杂志》2014,(3):397-402
Assisted by graphene oxide(GO),nano-sized LiMn0.6Fe0.4PO4 with excellent electrochemical performance was prepared by a facile hydrothermal method as cathode material for lithium ion battery.SEM and TEM images indicate that the particle size of LiMn0.6Fe0.4PO4(S2)was about 80 nm in diameter.The discharge capacity of LiMn0.6Fe0.4PO4 nanoparticles was 140.3 mAh-g^1 in the first cycle.It showed that graphene oxide was able to restrict the growth of LiMn0.6Fe0.4PO4 and it in situ reduction of GO could improve the electrical conductivity of LiMn0.6Fe0.4PO4 material. 相似文献
107.
Herein,we report on the synthesis and lithium storage properties of electrospun one-dimensional(1D) CuFe_2O_4 nanomaterials.1D CuFe_2O_4nanotubes and nanorods were fabricated by a single spinneret electrospinning method followed by thermal decomposition for removal of polymers from the precursor fibers.The as-prepared CuFe_2O_4 nanotubes with wall thickness of ~50 nm presented diameters of ~150 nm and lengths up to several millimeters.It was found that phase separation between the electrospun composite materials occured during the electrospinning process,while the as-spun precursor nanofibers composed of polyacrylonitrile(PAN),polyvinylpyrrolidone(PVP) and metal salts might possess a core-shell structure(PAN as the core and PVP/metal salts composite as the shell) and then transformed to a hollow structure after calcination.Moreover,as a demonstration of the functional properties of the 1D nanostructure.CuFe_2O_4 nanotubes and nanorods were investigated as anodes for lithium ion batteries(LIBs).It was demonstrated that CuFe_2O_4 nanotubes not only delivered a high reversible capacity of ~816 mAh·g~(-1) at a current density of 200 mA·g~(-1)over 50 cycles,but also showed superior rate capability with respect to counterpart nanorods.Probably,the enhanced electrochemical performance can be attributed to its high specific surface areas as well as the unique hollow structure. 相似文献
108.
In the present work,an interconnected sandwich carbon/Si-SiO2/carbon nanospheres composite was prepared by template method and carbon thermal vapor deposition(TVD).The carbon conductive layer can not only efficiently improve the electronic conductivity of Si-based anode,but also play a key role in alleviating the negative effect from huge volume expansion over discharge/charge of Si-based anode.The resulting material delivered a reversible capacity of 1094 mAh/g,and exhibited excellent cycling stability.It kept a reversible capacity of 1050 mAh/g over 200 cycles with a capacity retention of 96%. 相似文献
109.
110.
Pauline Jaumaux Qi Liu Dr. Dong Zhou Xiaofu Xu Tianyi Wang Yizhou Wang Feiyu Kang Prof. Baohua Li Prof. Guoxiu Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(23):9219-9227
The deployment of high-energy-density lithium-metal batteries has been greatly impeded by Li dendrite growth and safety concerns originating from flammable liquid electrolytes. Herein, we report a stable quasi-solid-state Li metal battery with a deep eutectic solvent (DES)-based self-healing polymer (DSP) electrolyte. This electrolyte was fabricated in a facile manner by in situ copolymerization of 2-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)ethyl methacrylate (UPyMA) and pentaerythritol tetraacrylate (PETEA) monomers in a DES-based electrolyte containing fluoroethylene carbonate (FEC) as an additive. The well-designed DSP electrolyte simultaneously possesses non-flammability, high ionic conductivity and electrochemical stability, and dendrite-free Li plating. When applied in Li metal batteries with a LiMn2O4 cathode, the DSP electrolyte effectively suppressed manganese dissolution from the cathode and enabled high-capacity and a long lifespan at room and elevated temperatures. 相似文献