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61.
Ileana A. Zucchi 《European Polymer Journal》2006,42(4):815-822
Films that can be reversibly switched from opaque to transparent states by varying temperature (TRLS films), have potential applications in thermal sensors, optical devices, recording media, etc. A dispersion of organic crystals in a thermoset may be used for these purposes provided that at temperatures higher than the melting point there is a matching of refractive indices of both phases. A model system consisting on a dispersion of diphenyl (DP) crystals in an epoxy matrix based on diglycidyl ether of bisphenol A and m-xylylenediamine, was analyzed as a possible TRLS film encapsulated between transparent covers to avoid sublimation of DP. To obtain a uniform dispersion of DP-rich domains in the epoxy matrix by polymerization-induced phase separation, it was necessary to add 5 wt% of polystyrene (PS) to the initial formulation. Phase separation induced by polymerization at 80 °C led to a dispersion of PS/DP domains in the epoxy matrix due to the low compatibility of PS with the epoxy and its high compatibility with DP. Crystallization and melting processes were confined to the interior of dispersed domains leading to an excellent reproducibility of the optical properties of TRLS films in the course of successive heating-cooling cycles. 相似文献
62.
Hae‐Jeong Lee Christopher L. Soles Da‐Wei Liu Barry J. Bauer Wen‐Li Wu 《Journal of Polymer Science.Polymer Physics》2002,40(19):2170-2177
X‐ray reflectivity has been used to determine the mass uptake of probe molecules in porous thin films supported on thick silicon wafers. The adsorption occurs by capillary condensation when the films are exposed to probe vapor at controlled partial vapor pressures. The probe solvent partial pressure was varied by mixing saturated air and dry air at constant temperature or by changing sample temperature at a constant vapor concentration. Pore size distribution in the films can be calculated from the probe uptake with typical porosimetric approaches such as the application of the Kelvin equation to convert partial pressure into pore size. For illustration, the pore size distribution of three different nanoporous thin films, the primary candidate of ultra‐low‐k interlevel dielectrics in the next generation of integrated circuit chips, was determined with this technique. These samples represent different generations of low‐k dielectrics developed by industry. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2170–2177, 2002 相似文献
63.
Summary Further to Gilpin's observations in liquid chromatography of the irreversible transformation of alkyl grafts, following the replacement of an organic mobile phase by an aqueous one, we describe some gas chromatographic experiments which lead to similar (log Vs, I/T) plots, as a consequence of the same solvent release process.We use paraffin films on siliceous supports or hydroxylated liquid substrates or C22-alkyl bonded silica. These experiments demonstrate that this irreversible transition and the melting-like reversible transition are completely different phenomena. They confirm the existence of at least three kinds of monomeric alkyl films. 相似文献
64.
Jeffrey T. Culp Franz Frye Mark W. Meisel Daniel R. Talham 《Coordination chemistry reviews》2005,249(23):2642-2648
Studies of metal cyanide thin films prepared directly at interfaces are reviewed. The systems range from monolayers, single-layer analogs of Prussian blue-like networks, to bulk powders prepared as thin films. Monolayer networks are prepared at the air/water interface and transferred to solid supports using Langmuir-Blodgett film methods. Films of bulk materials are prepared directly on solid surfaces using a templated sequential deposition procedure. The magnetic properties of the films have been explored, and in some cases, these monolayers and surface films give rise to new behavior that is only possible because of the fabrication method or thin film architecture. The methods of synthesis can generate oriented samples, even when the materials are poorly crystalline. Furthermore, the interface-assembled networks are inherently anisotropic, leading to phenomena not present in the solid-state analogs, such as anisotropic photomagnetism in a thin film of RbjCok[Fe(CN)6]l·nH2O. 相似文献
65.
A method for preparation of capillary columns and traps with a very thick film (up to 100 μm) of stationary phase is described. The principle of this method is based on an immediate fixation of a film of prepolymer, formed during dynamic coating. Thus, the development of film irregularities, such as are caused by Rayleigh instability is avoided. Fixation of the film is conveniently accomplished by heat-accelerated crosslinking as was demonstrated in this work, where a commercially available silicone prepolymer (Sylgard 184, Dow Corning) was employed. The low phase ratio columns which thus can be prepared are interesting both in chromatography with dense mobile phases and as enrichment devices. Examples of the latter application are shown, where trace organic components from air and water were concentrated. 相似文献
66.
The disadvantages of Normally White Twisted Nematic Liquid Crystal Display (NW-TN-LCD) were discussed. The reason that the negative birefringent polyimide thin filmswere used to compensate NW-TN-LCD to decrease off-axis leakage, improve contrast ratiosand enlarge viewing angles was explained in this paper. A certain polyimide thin film wastaken as an example to show compensation effect on NW-TN-LCD. 相似文献
67.
The gas-phase photocatalytic oxidation of aniline on a new kind of porous nano-TiO2 composite films is investigated. The composite film was prepared on glass fiber with the water glass as binders and dilute
H2SO4 solution as solidifying reagent. The surface characters were observed by scanning electron microscope. The photocatalytic
degradation of aniline on the composite films was carried out in a TiO2/UV system. Some important factors affecting the photodegradation, such as the concentration of TiO2, the initial concentration of aniline, and the existing water vapor, are also studied. The product of photocatalytic oxidation
was detected by Fourier transform-Infrared. The partial intermediate products were absorbed on TiO2 surface, which resulted in catalyst deactivation. But when it was irradiated under UV illumination or solar irradiation for
some time, the catalyst could be reused without loss of catalytic activity.
Translated from the Journal of Wuhan University (Natural Science Edition), 2005, 51(2) (in Chinese) 相似文献
68.
Mao-fengZhang Qiao-hongYao Chun-huiHuang Wei-xiaoCao 《高分子科学》2005,(1):27-27
A kind of azo-containing resin (Azo-R) was synthesized by a simple way through the coupling reaction of 2-nitro-N-methyldiphenylamine-4-diazoresin (NDR) with phenol, and a new covalentely attached multilayer film from Azo-R as H-donor and photosensitive diazoresin, diphenylamine-4-diazoresin (DR) as H-acceptor via H-bonding attraction by selfassembly technique has been fabricated. Following the decomposition of diazonium group of DR under exposure to UV light, the H-bonds between the layers of the film convert to covalent bonds and the film becomes very stable toward polar solvents or electrolyte aqueous solutions. Thus the UV-irradiated azo-containing films can be used to measure photocurrent in a conventional three-electrode photoelectrochemical cell using KCl as supporting electrolyte. It was confirmed that the azo-containing multilayer film is responsible for the photocurrent generation. 相似文献
69.
S. Tamai J. Kamada T. Ono T. Kuroki K. Goto A. Yamaguchi 《Journal of polymer science. Part A, Polymer chemistry》2002,40(3):423-428
Polyimide containing an indan unit and alkyl moiety with a high molecular weight was prepared from 5,7‐diamino‐1,1,4,6‐tetramethylindan and 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride. This polyimide was amorphous and soluble in common organic solvents, such as tetrahydrofuran, chloroform, and cyclopentanone. Thermogravimetry of the polyimide showed good thermal stability, indicating that a 10% weight loss of the polyimide was observed at 500 °C in nitrogen. The glass‐transition temperature of the polyimide was not observed by DSC measurement between room temperature and 400 °C at a heating rate of 10 °C/min (Apparatus: DSC3100 MAC Science Co., Ltd.). Transparency of the polyimide at 365 nm was 80%. The polyimide acted as a photosensitive resist of negative type by UV radiation. The resist had a sensitivity of 31 mJ/cm2 and a contrast of 2.3 when it was developed with cyclopentanone at room temperature. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 40: 423–428, 2002 相似文献
70.
Results of permittivity measurements, electromagnetic interference shielding effectiveness, and heat generation due to microwave absorption in conducting polymer coated textiles are reported and discussed. The intrinsically conducting polymer, polypyrrole, doped with anthraquinone-2-sulfonic acid (AQSA) or para-toluene-2-sulfonic acid (pTSA) was applied on textile substrates and the resulting materials were investigated in the frequency range 1-18 GHz. The 0.54 mm thick conducting textile/polypyrrole composites absorbed up to 49.5% of the incident 30-35 W microwave radiation. A thermography station was used to monitor the temperature of these composites during the irradiation process, where absorption was confirmed via visible heat losses. Samples with lower conductivity showed larger temperature increases caused by microwave absorption compared to samples with higher conductivity. A sample with an average sheet resistivity of 150 Ω/sq. showed a maximum temperature increase of 5.27 °C, whilst a sample with a lower resistivity (105 Ω/sq.) rose by 3.85 °C. 相似文献