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231.
Antonio Castellanos Xiaoping Jia Carlos Soria-Hoyo Jose Manuel Valverde 《Particuology》2011,9(6):659-662
The propagation velocity (vs) of an ultrasonic signal through a granular material depends on the type of interparticle contact. For noncohesive glass beads, a power law behavior for consolidation stresses applied (σc) above 1 MPa has been measured in previous work. This equation is compatible with Hertz's interaction law between elastic solids. In the present work, we have tested the propagation velocity of ultrasound signals through a sample of fine powder. The tensile strength and compactivity of the powder were previously measured by means of the Seville powder tester (SPT), indicating plastic deformation of the surface asperities in contact for small to moderate consolidation stresses. However, the measurements of ultrasound propagation at high consolidations presented here are compatible with Hertz's law. This finding suggests that for high consolidation stresses, surface asperities are flattened, and it is therefore the elastic deformation of the bulk of the particles that determines the transmission of ultrasonic pulses. 相似文献
232.
Takuo Okuchi Naotaka Tomioka Narangoo Purevjav Jun Abe Stefanus Harjo Wu Gong 《高压研究》2013,33(2):273-280
Neutron powder diffraction measurements of 0.9 mm3 of mixture of deuterated brucite and pressure medium were conducted at pressures to 2.8 GPa, using an opposed anvil cell and a medium-resolution diffractometer at Japan Proton Accelerator Research Complex pulsed neutron source. Spurious-free diffraction patterns were successfully obtained and refined to provide all structural parameters including Debye–Waller factors. Tilting of hydroxyl dipoles of brucite toward one of the three nearest-neighbor oxygen anions was confirmed to be substantial at pressure as low as 1.5 GPa. By this application, technical feasibility to analyze such a small sample has been newly established, which would be useful to extend the applications of neutron diffraction at high pressures. 相似文献
233.
目前粉末ACEL器件有三类:玻璃屏、塑料软屏和搪瓷屏.目前商品化的电致发光材料,每炉料大约在100~200克之间,粒度在10μm左右,不能满足产业化的需求.影响发光材料亮度、寿命、粒度的主要因素有Cu的浓度、灼烧时间、退火方式和灼烧气氛[1,2,3]... 相似文献
234.
General and practical method for the synthesis of silyl ethers in the presence of zinc powder under mild conditions has been described. 相似文献
235.
NiMn2O4纳米粉体的相变过程和晶粒生长行为研究 总被引:1,自引:0,他引:1
王疆瑛 《新疆大学学报(理工版)》1998,15(2):49-51
采用溶胶凝胶法(Sol-Gel)制备NiMn2O4纳米粉体.用X射线衍射(XRD)法,热分析仪研究NiMn2O4纳米粉体的相变过程.用X射线衍射线线宽法,透射电子显微镜(TEM)研究晶粒长大行为.研究结果表明:热处理温度小于670°C,存在非晶晶化过程和向NiMn2O4尖晶石主晶相转变等相变过程,晶粒尺寸缓慢增大,热处理温度在于670°C,粉体的相结构为NiMn2O4尖晶石相.晶粒尺寸较快增长.相变过程严重影响了晶粒长大行为. 相似文献
236.
Gregory G Wildgoose Shelley J Wilkins Gareth R Williams Robert R France David L Carnahan Li Jiang Timothy G J Jones Richard G Compton 《Chemphyschem》2005,6(2):352-362
We demonstrate that graphite powder and multiwalled carbon nanotubes (MWCNTs) can be derivatised by 4-nitrobenzylamine (4-NBA) simply by stirring the graphite powder or MWCNTs in a solution of acetonitrile containing 10 mM 4-NBA. We propose that 4-NBA partially intercalates at localised edge-plane or edge-plane-like defect sites and this hypothesis with a range of experimental data provided by electrochemistry in both aqueous and nonaqueous media, electron microscopy and X-ray powder diffraction. 相似文献
237.
A. A. Lichmanov Ch. M. Briskina V. M. Markushev V. N. Lichmanova N. P. Soshchin 《Journal of Applied Spectroscopy》1998,65(5):818-825
A degree of coherence of powder-laser radiation of 10–20% is estimated by the magnitude of the image contrast for a speckle,
although cases are recorded where it attains 40–50%. It is found that as the average speckle intensity increases, the contrast
decreases. It is established that the minimum, dimensions of the generation region in powders are 20–30 μm. Cases of existence
of several generation centers simultaneously are noted. An attempt to interpret the results obtained is made.
Institute of Radio Engineering and Electronics, Russian Academy of Sciences, 11, Mokhovaya St., Moscow, 103907. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 5, pp. 780–786, September–October, 1998. 相似文献
238.
Magnesium dicyanamide tetrahydrate Mg[N(CN)2]2 · 4 H2O was synthesized by aqueous ion exchange starting from Na[N(CN)2] and Mg(NO3)2 · 6 H2O. The crystal structure was solved and refined on the basis of powder X‐ray diffraction data (P21/c, Z = 2, a = 737.50(2), b = 732.17(1), c = 971.67(2) pm, β = 98.074(1)°, wRp = 0.059, Rp = 0.046, RF = 0.075). In the crystal there are neutral complexes [Mg[N(CN)2]2(H2O)4] which are only connected via hydrogen bonds. Above 40 °C the tetrahydrate decomposes into anhydrous Mg[N(CN)2]2. 相似文献
239.
With a view to study the pre-equilibrium effects in neutron-induced reactions, the activation cross-sections for (n, 2n) reactions at 14.2±0.2 MeV in the heavy mass region have been measured using the versatile mixed powder technique and high
resolution Ge(Li) detection. The experimental cross-sections are found to be consistently smaller than the predictions based
on the statistical theory and this is attributed to the effect of pre-equilibrium decay in these reactions. The cross-sections
due to pre-equilibrium decay were estimated using exciton, hybrid and unified models. When this cross-section was included
in comparing the experimental cross-sections with theory, we obtained better agreement, within the limitations of the present-day
preequilibrium theories.
Preliminary results of this work were reported at the Nuclear Physics and Solid State Physics Symposium, Pune (1978). 相似文献
240.
Yoshitaka Ishii Koichi Hirao Takehiko Terao Tsutomu Terauchi Makoto Oba Kozaburo Nishiyama Masatsune Kainosho 《Solid state nuclear magnetic resonance》1998,11(3-4):169-175
A solid state NMR method is presented for determination of a backbone dihedral angle φ in peptides, being based on the previously reported method, relayed anisotropy correlation (RACO) NMR [Y. Ishii et al., Chem. Phys. Lett. 256 (1996) 133]. In the present method, the
and the
dipolar tensors in the
system are two-dimensionally (2D) correlated via polarization transfer from
to
under magic angle spinning (MAS). This method was applied to N-acetyl
,
-valine, and the H–C–N–H dihedral angle was determined to be 154.0±1.4° or 206.0±1.4°, the former agreeing with the X-ray value of 154±5°. 相似文献