非匹配负载对宽带脉冲产生器谐振特性的影响

 宽带脉冲产生器的谐振特性决定了产生电磁脉冲的频谱,分析了带耦合器的同轴1/4波长谐振器在负载为非完全匹配天线时,天线反射对谐振特性的影响。通过建立级联二端口微波网络分析模型,将非匹配负载的反射系数计入等效耦合器反射系数中,得到了输出脉冲及辐射场频谱与负载反射系数的关系式。数值模拟了包括谐振器、耦合器和天线在内的整个宽带脉冲辐射系统,得到的辐射场频谱与理论预期相符。由于负载反射的影响,在中心频率两侧产生了两个副峰,在高功率实验中也观察到了该现象。     

紧凑型P波段相对论返波振荡器的粒子模拟

 设计了一种紧凑型P波段相对论返波振荡器,其电动力学结构是由同轴慢波结构和同轴引出结构组成的。同轴慢波结构缩小了器件的径向尺寸;同轴引出结构缩短了器件的轴向长度,且提高了束波作用效率。通过粒子模拟研究了器件内束波作用的物理过程,模拟结果表明：器件具有结构紧凑、束波作用效率高的特点。在二极管电压700 kV,电流7 kA,导引磁场1.5 T时,器件在频率833 MHz处获得较高的微波输出,饱和后输出微波的平均功率达1.58 GW,效率约为32%,器件电磁结构尺寸仅为108 mm×856 mm。     

低电感大电流长寿命同轴型电容器

 介绍了一种应用于高功率脉冲源的低电感、高通流能力、长寿命的同轴型电容器。通过理论计算,综合考虑电容器的工作电压、电感、通流能力、与开关的连接方式等,确定了电容器的芯子结构、绝缘子结构及电极结构。通过设计实验线路,测试了电容器的电压、电感、通流能力、寿命等参数。实验结果表明：电容器电容量1.5 μF,工作电压100 kV,工作电流250 kA,峰值电流大于300 kA,电容器电感小于20 nH,储能密度205 J/L,工作寿命大于6 000次。     

中等能量P波段相对论返波振荡器的理论设计与粒子模拟

提出了一种新型的中等能量P波段相对论返波振荡器,该器件将慢波结构由低波段普遍采用的同轴外波纹结构变为同轴双波纹结构,使得径向束-波作用空间扩大了2倍,一定程度上增加了器件的功率容量;另外同轴双波纹结构还较大提高了器件的时间增长率,从而有效地减小了微波输出饱和时间.经优化设计,该结构在二极管电压300 kV、电流3 kA...     

Toluene sensing properties of SnO2-ZnO hollow nanofibers fabricated from single capillary electrospinning

SnO₂-ZnO hollow nanofibers were fabricated through a facile single capillary electrospinning technology. The structure and toluene sensing properties of the hollow fibers were investigated. The results indicated that the fibers possess a hollow structure, a rough porous surface after being annealed at 600 °C and the diameters are in the range of 80-160 nm. A sensor fabricated from these fibers exhibits considerable sensitivity and good stability against toluene at 190 °C, which can be attributed to the special 1D hollow structure and the promoting effect of the SnO₂/ZnO heterojunction. The formation mechanism and toluene sensing mechanism of SnO₂-ZnO hollow nanofibers were also discussed.     

高效同轴脉冲管制冷机性能的实验研究

同轴式脉冲管制冷机具有结构紧凑、与器件耦合简单的优点,在实际应用中得到了越来越广泛的采用.本文对一台经理论优化设计的高频同轴脉冲管制冷机进行了实验研究,采用自制的直线压缩机驱动,惯性管/气库作为调相机构,在输入电功150 W、冷端温度为77 K时得到了9.86 W的制冷量,相对卡诺效率达到18.4%,这是目前同轴脉冲管...     

Aligned and molecularly oriented semihollow ultrafine polymer fiber yarns by a facile method

In this work, aligned and molecularly oriented bone‐like PLLA semihollow fiber yarns were manufactured continuously from an optimized homogeneous polymer‐solvent‐nonsolvent system [PLLA, CH₂Cl₂, and dimethyl formamide (DMF)] by a single capillary electrospinning via self‐bundling technique. Here, it should be emphasized that the self‐bundling electrospinning technique, a very facile electrospinning technique with a grounded needle (which is to induce the self‐bundling of polymer nanofibers at the beginning of electrospinning process), is used for the alignment and molecular orientation of the polymer fiber, and the take‐up speed of the rotating drum for the electrospun fiber yarn collection is very low (0.5 m/s). PLLA can be dissolved in DMF and CH₂Cl₂ mixed solvent with different ratios. By varying the ratios of mixed solvent system, PLLA electrospun semihollow fiber with the porous inner structure and compact shell wall could be formed, the thickness of the shell and the size of inner pores could be adjusted. The results of polarized FTIR and wide angle X‐ray diffraction investigations verified that as‐prepared PLLA semihollow fiber yarns were well‐aligned and molecularly oriented. Both the formation mechanism of semihollow fibers with core‐shell structure and the orientation mechanism of polymer chains within the polymer fibers were all discussed. The as‐prepared self‐bundling electrospun PLLA fiber yarns possessed enhanced mechanical performance compared with the corresponding conventional electrospun PLLA fibrous nonwoven membranes. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1118–1125, 2010     

Carbendazim‐loaded electrospun poly(vinyl alcohol) fiber mats and release characteristics of carbendazim therefrom

Ultra‐fine poly(vinyl alcohol) (PVA) electrospun fiber mats containing carbendazim were successfully fabricated by electrospinning from the neat PVA solution containing carbendazim in various amounts based on the weight of PVA. The morphological appearance of both the neat and the carbendazim‐loaded electrospun PVA fibers were smooth and the incorporation of carbendazim in the neat PVA solution did not affect the morphology of the resulting fibers. The average diameters of the neat and the carbendazim‐loaded electrospun PVA fibers ranged between 155 and 160 nm. The chemical integrity of the as‐loaded carbendazim in the carbendazim‐loaded electrospun PVA fiber mats was intact as verified by the ¹H‐nuclear magnetic resonance spectroscopy. Thermal properties of the carbendazim‐loaded electrospun PVA fiber mats were analyzed by differential scanning calorimetry and thermogravimetric analysis. The release characteristics of the carbendazim‐loaded electrospun PVA mats were investigated by the total immersion method in distilled water at 30°C. The carbendazim‐loaded electrospun PVA mats exhibited greater amount of carbendazim released than the carbendazim‐loaded as‐cast films. Copyright © 2010 John Wiley & Sons, Ltd.     

Electrospun composite nanofibers for functional applications

In this article an outline of studies conducted to date utilizing the process of electrospinning is presented. This overview for the first time focuses on research of composite nanofiber synthesis and their applications. The phenomenon of bringing materials to the nanometer scale not only improves their properties, but also creates entirely new ones. The electrospinning technique is a simple and versatile method that offers a time and cost effective production of strategic combinations of polymer and composites nanofibers useful for numerous applications highlighted in this review. The future prospects of the field are also examined.     

Preparation and characterization of a nanoscale poly(vinyl alcohol) fiber aggregate produced by an electrospinning method

Nanoscale poly(vinyl alcohol) (PVA) fiber (100–500 nm) aggregates were prepared with an electrospinning technique. Additionally, a chemical crosslinking method was used to crosslink the nanoscale PVA fiber aggregates. Differential scanning calorimetry, wide‐angle X‐ray diffraction, and scanning electron microscopy techniques were employed to characterize the PVA fiber aggregates. The different crosslinking densities of the PVA fiber aggregates were obtained through the control of the weight percentage of glyoxal to PVA. The crosslinking densities due to heat treatment and chemical crosslinking were studied. The influence of heat treatment could be neglected in contrast to chemical crosslinking when the curing temperature was 120 °C. The primary factor that affected the crosslinking density was the volume of the chemical crosslinking agent. The results showed that the properly crosslinked PVA fiber aggregates had better antiwater solubility and mechanical properties than the noncrosslinked PVA fiber aggregates. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1261–1268, 2002