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61.
Howard Jacobowitz Gerardo Mendoza 《Transactions of the American Mathematical Society》2003,355(10):4201-4222
We study embeddings of complex vector bundles, especially line bundles, in the complexification of the tangent bundle of a manifold. The aim is to understand implications of properties of interest in partial differential equations.
62.
In this work actin is used to illustrate connection of protein fluorescence characteristics with its structure. On one hand, it has been demonstrated what kind of information about the contribution of each tryptophan residues to the bulk fluorescence spectrum can be obtained from the special analysis of protein three-dimensional structure. On the other hand, potentials of intrinsic fluorescence for elucidation of proteins structure, dynamics and processes of folding-unfolding are shown. In particular, using this method a new essentially unfolded kinetic intermediate state of actin was detected and characterized, and the place of inactivated actin and its kinetic predecessor in the process of folding-unfolding was determined. It has been revealed that inactivated actin is not intermediate state between the native and completely unfolded states, as it has been accepted before, but a result of protein misfolding. On the basis of the obtained data a new model of actin folding-unfolding pathway has been proposed. 相似文献
63.
A hierarchical structure (HS) analysis (β-test and γ-test) is applied to a fully developed turbulent pipe flow. Velocity signals are measured at two cross sections in the pipe and at a series of radial locations from the pipe wall. Particular attention is paid to the variation of turbulent statistics at wall units 10<y+<3000. It is shown that at all locations the velocity fluctuations satisfy the She–Leveque hierarchical symmetry (Phys. Rev. Lett. 72 (1994) 336). The measured HS parameters, β and γ, are interpreted in terms of the variation of fluid structures. Intense anisotropic fluid structures generated near the wall appear to be more singular than the most intermittent structures in isotropic turbulence and appear to be more outstanding compared to the background fluctuations; this yields a more intermittent velocity signal with smaller γ and β. As turbulence migrates into the logarithmic region, small-scale motions are generated by an energy cascade and large-scale organized structures emerge which are also less singular than the most intermittent structures of isotropic turbulence. At the center, turbulence is nearly isotropic, and β and γ are close to the 1994 She–Leveque predictions. A transition is observed from the logarithmic region to the center in which γ drops and the large-scale organized structures break down. We speculate that it is due to the growing eddy viscosity effects of widely spread turbulent fluctuations in a similar way as in the breakdown of the Taylor vortices in a turbulent Couette–Taylor flow at high Reynolds numbers. 相似文献
64.
为了使光盘获得优良的记录/读出性能并能够长期稳定地使用,必须优化设计相变光盘的多层膜结构。采用自行设计的模拟分析相变光盘读出过程设计软件,从光学角度出发模拟计算了蓝光(405nm)相变光盘的膜层结构,研究了多层膜系的反射率和反射率对比度等光学参量与各层膜厚度和槽深的关系。研究得出的最佳多层膜结构为:下介电层/记录层/上介电层/反射层的厚度对于台记录为100nm/10nm/25nm,/60nm,而对于槽记录则为140nm/15nm/30nm,/60nm,槽深为50nm。模拟计算结果对于将来高密度蓝光相变光盘的制备具有一定的指导意义。 相似文献
65.
Two structure functions W1(x,Q2) and W2(x,Q2) are determined by using the cross sections measured in the deep inelastic electron-proton scattering experiments at Stanford Linac in the energy range of 5 to 20 GeV. In this paper an alternative mathematical approach have been used in such determination, resulting in a larger number of points in the graphs of the structure functions. 相似文献
66.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献
67.
This paper presents a quantum chemical calculation of native (2–7 fructoside residues) and chemically modified (2–4 fructoside residues) levan molecule models. A levan modification was carried out by oxidation and the following reduction or hyrdazonation of the fructoside rings. The conformational particularity and reaction ability was studied for the native and for the modified levan molecules. 相似文献
68.
ZHOU Ming-Xiua② YANG Chuna DENG Xiao-Yana YU Wei-Feib LI Jin-Shanb a 《结构化学》2006,25(6):647-652
1 INTRODUCTION Silicon and its alloy have been widely applied in such fields as electronic industry, high-temperature structural ceramics, etc. In addition, the researches on silicon and its relevant materials greatly promote the rapid development of modern optics and infor- mation technology. Therefore, more and more at- tention is focused on the structure of silicon, oxide of silicon and the interfaces between silicon and metal or nonmetal. As an ideal passive film on the Si surface, S… 相似文献
69.
Dinesh Topwal U. Manju Sugata Ray S. Raj D. D. Sarma S. R. Krishnakumar M. Bertolo S. La Rosa G. Cautero 《Journal of Chemical Sciences》2006,118(1):87-92
Disordered Sr2FeMoO6 shows a drastic reduction in saturation magnetization compared to highly ordered samples, moreover magnetization as a function
of the temperature for different disordered samples shows qualitatively different behaviours. We investigate the origin of
such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish
that extensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples, is
responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with
composition fluctuations of the type Sr2Fe1+x
Mo1-x
O6 with Fe-rich (x > 0) and Mo-rich (x < 0) regions.
Dedicated to Prof J Gopalakrishnan on his 62nd birthday. 相似文献
70.
Yong‐Jin Kim Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Junoh Kim Ih‐Seop Chang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5627-5635
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004 相似文献