全文获取类型
收费全文 | 1646篇 |
免费 | 68篇 |
国内免费 | 218篇 |
专业分类
化学 | 1771篇 |
晶体学 | 4篇 |
力学 | 5篇 |
综合类 | 11篇 |
数学 | 2篇 |
物理学 | 139篇 |
出版年
2024年 | 4篇 |
2023年 | 12篇 |
2022年 | 68篇 |
2021年 | 69篇 |
2020年 | 54篇 |
2019年 | 38篇 |
2018年 | 44篇 |
2017年 | 65篇 |
2016年 | 76篇 |
2015年 | 47篇 |
2014年 | 55篇 |
2013年 | 126篇 |
2012年 | 63篇 |
2011年 | 60篇 |
2010年 | 61篇 |
2009年 | 86篇 |
2008年 | 107篇 |
2007年 | 73篇 |
2006年 | 92篇 |
2005年 | 95篇 |
2004年 | 54篇 |
2003年 | 52篇 |
2002年 | 53篇 |
2001年 | 52篇 |
2000年 | 48篇 |
1999年 | 48篇 |
1998年 | 54篇 |
1997年 | 47篇 |
1996年 | 52篇 |
1995年 | 48篇 |
1994年 | 31篇 |
1993年 | 16篇 |
1992年 | 15篇 |
1991年 | 20篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 11篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有1932条查询结果,搜索用时 15 毫秒
31.
Inverse gas chromatography (IGC) was used to determine the dispersive component of the free energy as well as the acid-base properties of cellulose fibre surfaces, before and after modification by corona treatment. It was found that the corona treatment increases both the dispersive contribution to surface energy and its acidic character, whereas only a slight increase in its basicity was observed. It was also found that some chemical degradation of the surface occurs at high corona currents. The extent of modification of the surface properties, as revealed by IGC, was correlated to the surface chemical composition deduced from XPS analysis as well as with the electrical conductance and the pH of the water suspensions of the cellulose fibres. 相似文献
32.
Krystyna Cieśla H. Rahier Grażyna Zakrzewska-Trznadel 《Journal of Thermal Analysis and Calorimetry》2004,77(1):279-293
One to three endothermal peaks atributted to melting of bulk and interfacial water were observed by DSC in the regenerated
cellulose — water system. The profiles of thermal effects depend on water content, time of conditioning, film pretreatment
and the conditions applied during the preceding freezing-thawing cycles. The occurrence might be deduced of melting-crystallisation
processes. A large amount of non-freezable strongly bounded water was also detected.
Although cellulose absorbs water quickly after immersion, the structural changes consisting on ordering of polymer fraction
occur during further conditioning due to increase in strength of water binding. Using the membranes in the separation module
at 90°C causes weakening of these bonds. Differences between interaction of particular cellulose films with water can be detected
during the first, the second and the third heating.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
33.
34.
J. Lédé 《Journal of Thermal Analysis and Calorimetry》1996,46(1):67-84
This paper deals with models describing the thermal and chemical behaviour of solid particles undergoing fast endothermic reactions under the influence of an external heat flux. The heat source temperature is supposed to be constant, to increase with time, or to deliver a simple thermal flash. It is shown that the pyrolysis conditions (reaction temperature, conversion, etc.) depend on the chemical characteristics of the reaction and also to a large extent on the external heating conditions. Relationships are proposed to take into account these parameters. The results are applied to the thermal decomposition of NaHCO3. The pyrolysis of cellulose is finally chosen in order to show how these operating parameters can also affect the selectivity of a more complex reaction. 相似文献
35.
36.
Inorganic-organic hybrids have been synthesized by incorporation of the inorganic component of Ti(OC2H5)4 into the organic polymer of ethyl cellulose. The inorganic-organic hybrids did not dissolve in toluene used as a solvent for the starting materials. The ethanol was formed as a by-product of the alcoholysis condensation reaction between Ti(OC2H5)4 and ethyl cellulose. These results suggest that ethoxy groups of Ti(OC2H5)4 react with hydroxy groups of ethyl cellulose to form cross-linking bonds of –O–Ti–O–. The reaction of Ti(OC2H5)4 with ethyl cellulose was further investigated by Fourier transform infrared (FT-IR) spectroscopy. The FT-IR spectroscopic experiments revealed that the Ti–O bond state of Ti(OC2H5)4 was changed by refluxing a toluene solution of Ti(OC2H5)4 with ethyl cellulose. The inorganic-organic hybrids have an interesting dielectric property; their dielectric constant is higher than that of ethyl cellulose and that of a simple mixture of TiO2 and ethyl cellulose. 相似文献
37.
消臭抗菌纤维素纤维的制备、结构和性能 总被引:2,自引:0,他引:2
采用一种制备消臭、抗菌纤维素纤维的新方法,即先将纤维素纤维用多元羧酸进行化学修饰,然后在铜溶液中处理,生成铜螯合纤维素纤维,用红外光谱、电子自旋波谱表征了该纤维的配位结构,消臭和抗菌实验结果显示,这种功能性纤维对硫化氢,氢气、三甲胺的消臭率分别达到100%,92.1%和80.4%,对金黄色葡萄球菌,大肠杆菌和白色念珠菌的抑菌率分别为79.14%,93.59%和82.50%,用X射线衍射,电子自旋波谱分析了该纤维吸附硫化氢,氨气、三甲胺的机理。 相似文献
38.
Various types of sodium cellulose sulfate (SCS), dissolved in a 1M LiCl solution, were investigated by alternating current (AC)polarography. The SCS samples differed in the degree of substitution (DS), thedistribution of substituents within the anhydroglucose unit (AGU), and alongthechain, due to the method of synthesis. The goal was to study theelectrosorptionbehavior, characterized by the shape of the desorption wave in the polarogram,as a function of the chemical structure of the SCS samples. The shape of thedesorption wave reflects domains of different substitution. A superimpositionofparameters like DS and pattern of substitution on the electrosorption behaviorwas observed. The AC polarography method described can be used as a tool todistinguish between an even or uneven distribution of substituents along thecellulose chain. 相似文献
39.
40.
Thomas F. Brodasky 《Journal of separation science》1978,1(5):239-244
Two new acyltetramic acids related to streptolydigin have been isolated from fermentations of Streptomyces lydicus. The principal members of this complex were resolved by TLC on silica gel. However, the methods of detection, permanganate spray or bioautography, were not suitable for both crude fermentation broths and purified extracts. Gas chromatography is unsuitable for the detection of either underivatized or silylated streptolydigins. High performance liquid chromatography (HPLC) particularly on triethylaminoethyl cellulose is rapid and sensitive and is the method of choice for the analysis of both crude and purified samples. Using high performance liquid chromatography, two components were detected in the complex, which are not observed using any of the other chromatographic procedures. 相似文献