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51.
The 11 800-14 380 cm−1 frequency range has been scanned for rotationally resolved rovibronic transitions in the A2B2-X2A1 electronic band system of the symmetric (C2v) 16O14N16O and 18O14N18O isotopologues and in the corresponding electronic band system of the asymmetric (Cs) 18O14N16O isotopologue. The rotational analysis—reflecting minor differences in mass—in combination with symmetry induced spectral differences allows an identification of 68 16O14N16O vibronic levels, 26 18O14N18O vibronic levels and 51 18O14N16O vibronic levels. The bands are recorded using near infrared fluorescence spectroscopy and a piezo valve based pulsed molecular beam expansion of premixed 18O2 and 14N16O in Ar. The majority of the observed bands is rotationally assigned and can be identified as transitions starting from the vibrational ground state of one of the isotopologues. Numerous hot bands have also been identified. A comparison of the overall spectroscopic features of C2v vs. Cs symmetric species provides qualitative information on symmetry dependence of vibronic couplings. 相似文献
52.
Applied Biochemistry and Biotechnology - 相似文献
53.
Remco van der Hofstad Gerard Hooghiemstra Piet Van Mieghem 《Random Structures and Algorithms》2002,20(4):519-539
In this paper we study the covariance structure of the number of nodes k and l steps away from the root in random recursive trees. We give an analytic expression valid for all k, l and tree sizes N. The fraction of nodes k steps away from the root is a random probability distribution in k. The expression for the covariances allows us to show that the total variation distance between this (random) probability distribution and its mean converges in probability to zero. © 2002 Wiley Periodicals, Inc. Random Struct. Alg., 20: 519–539, 2002 相似文献
54.
The objective of this paper is to investigate the role of the set of irrational numbers as the codomain of order-preserving
functions defined on topological totally preordered sets. We will show that although the set of irrational numbers does not
satisfy the Debreu property it is still nonetheless true that any lower (respectively, upper) semicontinuous total preorder
representable by a real-valued strictly isotone function (semicontinuous or not) also admits a representation by means of
a lower (respectively, upper) semicontinuous strictly isotone function that takes values in the set of irrational numbers.
These results are obtained by means of a direct construction. Moreover, they can be related to Cantor’s characterization of the real line to obtain much more general results on the semicontinuous
Debreu properties of a wide family of subsets of the real line.
相似文献
55.
On a nonlinear multigrid algorithm with primal relaxation for the image total variation minimisation
Digital image restoration has drawn much attention in the recent years and a lot of research has been done on effective variational partial differential equation models and their theoretical studies. However there remains an urgent need to develop fast and robust iterative solvers, as the underlying problem sizes are large. This paper proposes a fast multigrid method using primal relaxations. The basic primal relaxation is known to get stuck at a ‘local’ non-stationary minimum of the solution, which is usually believed to be ‘non-smooth’. Our idea is to utilize coarse level corrections, overcoming the deadlock of a basic primal relaxation scheme. A further refinement is to allow non-regular coarse levels to correct the solution, which helps to improve the multilevel method. Numerical experiments on both 1D and 2D images are presented. 相似文献
56.
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58.
给定一组工件的加工时间与工期,要求确定这些工件在一台机器上的加.工排列,使相应的总延误达到最小,这就是总延误问题.该问题在近年已被证明是NP困难的.由Wilkermn和Irwin(1971),林勋(1983)等所研究的顺时安排法能得到相邻交换意义下的局部解.在本文中,我们进一步证明该算法能得到前移邻域意义下的局部解,并确定了该算法的性能比. 相似文献
59.
60.
Fernando M. Lanas Janete H. Y. Vilegas Srgio Martins Elaine A. F. Gobato 《Journal of separation science》1994,17(4):237-244
An overview is presented of the analytical approaches developed by our research group over the last ten years for analysis of alternative fuel, both biomass and fossil. The alternative fuels are analyzed successively by PLC-8 (preparative liquid chromatography–group-type) fractionation and high resolution gas chromatography. Some of the possibilities for fractionation and characterization of alternative fuels are herein exemplified with sugar cane bagasse pyrolysis products. 相似文献