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991.
V. P. Korolev 《Journal of Structural Chemistry》2007,48(4):673-679
Relations are suggested for calculating the heat characteristics of alcohols, benzene, and toluene in aqueous solutions of urea and ethylene glycol. The solution heat of an alcohol shows greater dependence on the glycol concentration, while the heat capacity of solution, on the urea concentration. For n-butanol in aqueous glycol, the characteristic temperature at which the solution heat of the alcohol is zero decreases as the glycol concentration increases. The dependence of the characteristic temperature of 1-butanol on the urea concentration has a maximum. 相似文献
992.
993.
Ralph E. Taylor-Smith Richard A. Register 《Journal of Polymer Science.Polymer Physics》1994,32(12):2105-2114
The nature and extent of phase mixing in blends of hydroxyl-functionalized polystyrene and poly(ethyl acrylate) (PS/PEA), where the driving force for mixing is hydrogen bonding, are characterized by several techniques. Small-angle x-ray scattering (SAXS) shows a reduction in average domain size with increasing functionalization level, a result also evident from scanning electron microscopy (SEM). Together, the two techniques reveal a very broad distribution of domain sizes. At high functionalization levels, both SAXS and SEM indicate a high degree of “in-domain” mixing, with little or no pure PS or PEA remaining in the blends. Mathematical modeling of dynamic mechanical thermal analysis (DMTA) data is employed to quantify this progression. Initially, mixing is primarily interfacial, but as the functionalization level increases, the mixed interphase rapidly grows to occupy the entire material. In agreement with the SAXS and SEM results, DMTA modeling shows that further increases in the functionalization level suppress the amplitude of composition variations in the sample. The onset of extensive in-domain mixing coincides with the marked changes in stress-strain behavior observed previously in these materials. © 1994 John Wiley & Sons, Inc. 相似文献
994.
Ti扩散铌酸锂光波导特性的热固定技术 总被引:1,自引:1,他引:0
在Ti扩散铌酸锂光波导中,因光致折变效应而导致光波导特性漂移.在光波相干性的导波光学器件中,光致折变效应的影响尤为严重.本文报道了稳定光致折变效应的热固定技术实验结果;并提出在光波导特性的热固定过程中,不是H~+离子起主导作用这一看法. 相似文献
995.
Visible photoluminescence (PL) of nanocrystalline silicon (nc-Si) embedded in single crystal CaF2 formed on Si(1 1 1) has been studied and the influence of ex situ rapid thermal annealing (RTA) on the surface morphology and PL spectra has been studied. It has been found that the PL intensity and uniformity was improved by RTA with appropriate temperature and short annealing time. 相似文献
996.
In this article we discuss the finite element discretization of the two-dimensional, incompressible, and turbulent boundary layers. The formulation of the momentum equation is essentially due to Baker and Soliman [1] with some modifications.The versatility and the accuracy of the method is established by considering several test cases. The predictions are satisfactory and compare favorably with alternative numerical techniques. 相似文献
997.
分析了制作高功率连续激光反射镜材料的热性能、缺陷及其加工工艺, 提出了制作高功率激光反射镜应考虑的几个关键问题: 反射镜材料的综合热性能比值S, 材料的微观结构、缺陷的大小和晶向的选择, 以及加工工艺的设计。并介绍了实验结果。 相似文献
998.
999.
Joshi Shrikant V. Park Jin Y. Taylor P. R. Richardson L. S. 《Plasma Chemistry and Plasma Processing》1985,5(2):143-161
Plasma Chemistry and Plasma Processing - A new integral mean diffusivity is proposed for the calculation of the mass transfer rate around a small particle immersed in a thermal plasma gas.... 相似文献
1000.
Van Roie B Denolf K Pitsi G Thoen J 《The European physical journal. E, Soft matter》2005,16(4):361-364
We investigated the smectic-A-hexatic-B (SmA-HexB) transition in the liquid-crystal n-hexyl-4-n-pentyloxybiphenyl-4-carboxilate (65OBC) with adiabatic scanning calorimetry. We were able to prove in a direct way that this transition is indeed very weakly first order, as was already suggested in the literature. The latent heat at the transition was determined to be HL = 0.04±0.02 J/g. Our experiments confirm the high value for the heat capacity critical exponent earlier reported, yielding = 0.64±0.05. 相似文献