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71.
The E' block of the mean-square amplitude matrix (Σ) for the planar symmetrical XY3 molecular model is treated theoretically in terms of the Keating coordinates. A numerical example for 11BF3 is given. Also the mean amplitudes of vibration (ι) and Bastiansen-Morino shrinkage effect (Δ) are considered. New relations which connect the mean-square amplitudes and force constants are given. Previous works on mean amplitudes and related quantities for boron trihalides from vibrational spectroscopy and gas electron diffraction are reviewed, and some new calculations are reported. 相似文献
72.
A simple and efficient one‐pot synthesis of 6‐bromocoumarins was achieved in good yields via the three‐component reaction of phenols, 4‐substituted acetoacetate and tetrabutylammonium tribromide (TBATB) in CH2Cl2‐MeOH. 相似文献
73.
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75.
新型高选择性芳环溴化剂 总被引:1,自引:0,他引:1
苄基三甲基三溴化铵是新型高选择性的芳环溴化剂。在CH2Cl2-CH3OH或CH3COOOH-ZnCl2中,它与酚,芳胺,酰胺,芳醚,芳烃及芳杂环化合物等反应,选择性得到对应的单,双或三溴化产物。 相似文献
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77.
Kjell-Gunnar Martinsen Natalja Vogt Hans Vidar Volden Vasilii S. Lyutsarev Jürgen Vogt 《Journal of Molecular Structure》1996,385(3):704-165
The thermal-average parameters of BBr3 at 21(1) °C were obtained from a conventional analysis of gas electron diffraction (GED) data (rg(B---Br) = 190.0(4) pm). The equilibrium structure and the force constants were refined from a joint analysis of the GED intensities and vibrational frequencies using different approximations. The simplest approximation (quadratic potential function in rectilinear coordinates) is suitable for the refinements of the equilibrium bond length (rhe(B---Br) = 189.6(4) pm) and the force constants of BBr3. The molecule is planar within the error limits. Quantum-chemical density-functional calculations supported planarity of the molecule. 相似文献
78.
KInBr3, the first ternary indium bromide containing divalent indium, is synthesized from InBr3, KBr, and elemental In at 450 °C. Its trigonal crystal structure (a = b = 853.24(1) pm, c = 1077.76(2) pm; P3¯; Z = 4) has been solved and refined from X-ray powder data. Indium atoms of oxidation state two are found in an [In2Br6]2– unit with ecliptic ethane structure while potassium ions are located in two different polyhedra. There is an octahedral coordination by bromine anions for half of the K+ whereas the other K+ cations are located in trigonal Br– prisms, tricapped by three additional Br– anions. 相似文献
79.
研究了四元体系CsBr-LaBr3-HBr(12%)-H2O(25℃)的相化学关系,绘制了相应的溶度图。在该体系中发现一种新型化合物5CsBr·2LaBr3·22H2O;对该化合物进行了偏光、X射线粉末衍射、TG及DTA等方面的测定。将本体系与四元系CsCl-LaCl3-HCl(13%)-H2O(25℃)相比较,发现两者在生成化合物的数量、种类和相化学行为方面均有较大的差异。 相似文献
80.
In this study, the synthesis and applications of a new supported tribromide reagent based on poly(diallyldimethylammonium chloride) is reported. This supported tribromide is used in α‐bromoacetalization of ketones, bromination of alkenes and regioselective bromination of activated aromatic compounds. This method is mild and no Br2 and HBr were used. Other advantages of this reagent are stability, high efficiency, simple filtera‐ bility and reusability. 相似文献