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91.
Three new N2S2 donor ligands 1,1′-((2-(2-(phenylthio)phenylthio)phenyl)methylene)bis(3,5-R-1H-pyrazole), R = H (LH), R = Me (LMe), R = i-Pr (Li-Pr) have been prepared and characterized. These bifunctional ligands incorporate two distinct chelate donor systems, by virtue of the presence of bispyrazole and bisthioether functions. The preferred conformation of these ligands is such that the N2 and S2 donor moieties may be oriented in opposite directions, thus favoring the formation of molecular chains when treated with AgBF4. The X-ray structures of Ag(I) complexes show that, depending on the steric hindrance present on the pyrazole rings, these ligands behave as κ4-SSNN-μ bridging tetradentate (when R = H), or κ3-SNN-μ bridging tridentate (when R = Me, i-Pr). Interestingly, [Ag(LH)]BF4 crystallizes in the chiral space group P41, with the molecular chain that is folded around the 41 screw axis. 相似文献
92.
Photophysical properties of a series of high luminescent europium complexes with fluorinated ligands
Jiangbo Yu 《Journal of luminescence》2011,131(2):328-335
A series of high luminescent europium complexes have been synthesized, such as Eu(TFNB)3phen (1), Eu(PFNP)3phen (2), Eu(HFNH)3phen (3) and Eu(PFND)3phen (4), which have β-diketone ligands containing fluorinated alkyl chains with different lengths and conjugated naphthyl groups, i.e., 4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dione (TFNB); 4,4,5,5,5-pentafluoro-1-(2-naphthyl)pentane-1,3-dione (PFNP); 4,4,5,5,6,6,6-heptafluoro-1-(2-naphthyl)hexane-1,3-dione (HFNH) and 4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluoro-1-(2-naphthyl)decane-1,3-dione (PFND). And 10-phenanthroline (phen) is coordinated as the neutral second ligand in 1-4. The crystal structures of 1 and 2 have been studied, which are typical and similar to that of 3. The results of TGA-DTA suggest that these Eu complexes have good thermal stabilities. By means of absorption and (time resolved) emission spectroscopy including determination of luminescence quantum yields, energy transfer dynamics and so on, the following results have been obtained: first, these Eu complexes show characteristic pure red color photoluminescence emission with high quantum efficiencies from the central Eu3+ ions through the excitation of the ligands; secondly, photophysical properties of 1, 2, 3 and 4, especially the lifetimes of excited states 5D0 of Eu3+ ions and quantum efficiencies are influenced by the different lengths of fluorinated alkyl chains, though the singlets (S1) and triplets (T1) of the fluorinated ligands are almost the same. 相似文献
93.
In this paper, we explore how firms can manage their raw material sourcing better by developing appropriate sourcing relationships with their raw material suppliers. We detail three empirical case studies of firms explaining their different raw material sourcing strategies: (a) firms can adopt a hands-off approach to raw material management, (b) firms can supply raw material directly to their suppliers, and this may be beneficial for some agents in the supply chain, and (c) firms can bring their component suppliers together, and the resulting cooperation between suppliers can be beneficial for supply chain. We then analytically model the three raw material scenarios encountered in our empirical work, examine the resulting profits along the supply chain, and extend the results to a competitive buyer scenario. Overall, our results show that active management of raw material sourcing can add value to supply chains. 相似文献
94.
Rui M.R. Cardoso 《商业与工业应用随机模型》2014,30(2):172-182
In this paper, we consider the classical risk model modified in two different ways by the inclusion of a dividend barrier. For Model I, we present numerical algorithms, which can be used to approximate or bound the expected discounted value of dividends up to a finite time horizon, t, or ruin if this occurs earlier. We extend this by requiring the shareholders to provide the initial capital and to pay the deficit at ruin each time it occurs so that the process then continues after ruin up to time t. For Model I, we assume the full premium income is paid as dividends whenever the surplus exceeds a set level. In our Model II, we assume dividends are paid at a rate less than the rate of premium income. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
95.
Adam Liwo Jarosław Pillardy Rajmund Kaźmierkiewicz Ryszard J. Wawak Małgorzata Groth Cezary Czaplewski Stanisaw Ołdziej Harold A. Scheraga 《Theoretical chemistry accounts》1999,101(1-3):16-20
A united-residue model of polypeptide chains developed in our laboratories with united side-chains and united peptide groups
as interaction sites is presented. The model is designed to work in continuous space; hence efficient global-optimization
methods can be applied. In this work, we adopted the distance-scaling method that is based on continuous deformation of the original
rugged energy hypersurface to obtain a smoothed surface. The method has been applied successfully to predict the structures
of simple motifs, such as the three-helix bundle structure of the 10-58 fragment of staphylococcal protein A in de novo folding
simulations and more complicated motifs in inverse-folding simulations.
Received: 24 April 1998 / Accepted: 4 August 1998 / Published online: 2 November 1998 相似文献
96.
B. Grenier L. -P. Regnault J. E. Lorenzo J. -P. Renard G. Dhalenne A. Revcolevschi 《Physica B: Condensed Matter》2000,280(1-4):313-314
We have performed magnetic susceptibility measurements on CuGe1−xSixO3 single crystals and obtained a detailed (T,x) phase diagram. In order to fully characterize the nature of the SP and AF phases in this diagram, we studied both order parameters by neutron diffraction as a function of temperature and Si concentration. 相似文献
97.
This paper presents some conditions for the minimal Q-function to be a Feller transition function, for a given q-matrix Q. We derive a sufficient condition that is stated explicitly in terms of the transition rates. Furthermore, some necessary and sufficient conditions are derived of a more implicit nature, namely in terms of properties of a system of equations (or inequalities) and in terms of the operator induced by the q-matrix. The criteria lead to some perturbation results. These results are applied to birth-death processes with killing, yielding some sufficient and some necessary conditions for the Feller property directly in terms of the rates. An essential step in the analysis is the idea of associating the Feller property with individual states. 相似文献
98.
Y. Nagasoe N. Ichiyanagi H. Okabayashi S. Nave J. Eastoe C. J. O'Connor 《Colloid and polymer science》1999,277(10):947-956
A homologous series of sodium dialkylsulfosuccinates (SDAS) has been synthesized with various chain lengths (dibutyl, dihexyl,
diheptyl, dioctyl, dinonyl, didecyl, diundecyl and didodecyl). These compounds are straight-chain analogues for Aerosol-OT.
Raman scattering spectra have been recordered for these SDAS compounds, both in the solid state and in aqueous solutions.
These spectra are analyzed in detail in the CH stretch and CH2 deformation regions, and the results depend specifically on the length of the hydrocarbon chain. In particular, the longitudinal
accordion-like vibrational modes coming from the all-trans n-alkyl chains have been investigated. For the SDAS dihydrates, all hydrocarbon chains take up an extended form, whereas for
the monohydrates the tails tend to become disordered at the CH2-CH2 single bond close to the terminal methyl groups. It has also been confirmed that for the concentrated aqueous SDAS (sodium
dibutylsulfosuccinate – sodium dioctylsulfosuccinate) samples preferential stabilization of the extended conformation of the
hydrocarbon chain may occur.
Received: 23 February 1999 Accepted: 10 May 1999 相似文献
99.
Xueqing Qiu Xiongyi Peng Yonghong Deng 《Journal of Dispersion Science and Technology》2013,34(2):203-212
Polycarboxylate-type superplasticizers (PCs) containing different side chains and sulfonic groups have been synthesized, and the effect of side chains and sulfonic groups on their performance in cementitious systems has been intensively investigated by measuring zeta potential, thickness of absorption layer, paste fluidity, rheological properties as well as the setting time in this paper. Results show that the PC containing both short poly(ethylene oxide) (PEO) side chains and long PEO side chains with the molar ratio of 1:1 has a better dispersibility than the PC containing only short PEO side chains or only long PEO side chains in cement suspensions. The shorter the side chain of the PC, the longer the setting time of cement paste incorporating it. An appropriate increase of sulfonic group content is beneficial for the improvement of dispersibility for the PC and leads to no obvious change for the setting time. It also suggests that there is a geometrical balance between the PEO side chains and sulfonic groups for the performance of PC. This work is not only helpful for understanding the relationship of molecular structure of PCs and their performance, but also further designing optimum molecular structure of PC to meet the requirement in different concrete system. 相似文献
100.
Ying Lin Teng‐Ling Ye Yu Chen Dong‐Ge Ma Zhi‐Kuan Chen Yan‐Feng Dai Yong‐Xi Li 《Journal of polymer science. Part A, Polymer chemistry》2010,48(24):5930-5937
A new bipolar conjugated polyfluorene copolymer with triphenylamine and cyanophenylfluorene as side chains, poly{[9,9‐di(triphenylamine)fluorene]‐[9,9‐dihexyl‐fluorene]‐[2,7‐bis(4′‐cyanophenyl)‐9,9′‐spirobifluorene]} ( PTHCF ), was synthesized for studying the polymer backbone emission. Its absolute weight‐average molecular weight was determined as 4.85 × 104 by using gel permeation chromatography with a multiangle light scattering detector. In contrast to the electronic absorption spectrum in dilute solution, the absorbance of PTHCF in thin film was slightly blue shifted. By comparison of the solution and thin‐film photoluminescence (PL) spectra, a red shift of Δλ = 8–9 nm was observed in the thin‐film PL spectrum. The HOMO and LUMO energy levels of the resulting polymer were electrochemically estimated as ?5.68 and ?2.80 eV, respectively. Under the electric‐field intensity of 4.8 × 105 V cm?1, the obtained hole and electron mobilities were 2.41 × 10?4 and 1.40 × 10?4 cm2 V?1 s?1, respectively. An electroluminescence device with configuration of ITO/PEDOT:PSS/ PTHCF 70%+PBD30%/CsF/Ca/Al exhibited a deep‐blue emission as a result of excitons formed by the charges migrating along the full‐fluorene main chain. The incorporation of the bipolar side chains into the polymer structure prevented the intermolecular interaction of the fluorene moieties, balance charge injection/transport, and thereby improve the polymer backbone emission. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献