6,8-二甲基-1,2,4-三唑并嘧啶-3-丁二酮基硫醚酮-烯醇互变异构平衡的1HNMR研究

用１ＨＮＭＲ方法研究了不同溶剂和温度对６，８－二甲基－１，２，４－三唑并嘧啶－３－丁二酮基硫醚酮－烯醇互变异构平衡的影响，发现温度升高有利于平衡向酮式转变，而溶剂极性的改变对平衡的影响并不规律，获得了四种溶剂中的ΔＨ和ΔＳ．     

A NEW FIXED POINT THEOREM FOR CONE MAPS AND ITS APPLICATIONS

1IntroductionLetEbearealBanachspace.AnonemptyconvexclosedsetPCEiscalledaconeinEifitsatisfiesthefollowingtwoconditionsf(i)xEP,A20impliesAxEP,(n)xEP,--xEPimpliesx=0.AconePiscalledsolidifitcontainsinteriorpoints,i.e.,P/gi.TheconePinEdefinesapartialorderingx5…     

Correlation integral as a tool for distinguishing between dynamics and statistics in time series data

We propose a new test for time series data for proper choice of processing technique: dynamical or statistical. It is based upon the normalized slope of the correlation integral (, m) = m⁻¹d(ln C()) /d ln , where m is the embedding dimension. It is shown that when does not tend to 0 on the resolved range of scales as m grows, then there will be serious limitations for dynamical methods even if the data are dynamical by nature. In the latter case it means that the length of time series does not allow to resolve small scales, and on large scales the delay reconstruction for any m mixes true and false neighbours of points and therefore restricts the application of dynamical techniques, such as estimating Lyapunov exponents or predicting time series.     

测量液体粘滞系数实验的研究

本文利用液体的绝对速度理论得到液体的粘滞系数随温度变化的关系式，在不同的温度下测得液体的粘滞系数，找出液体的粘滞系数随温度变化的数学表达式。     

On the inversion of the classical second virial coefficient

For a large class of intermolecular potentials, the values of the second virial coefficient at a discrete set of temperature points in an arbitrarily small neighborhood of the origin determine the potential uniquely.     

The excess volumes of tetrahydronaphthalene inn-alkanes at 10 and 25°C

The excess volume of mixing tetrahydronaphthalene with n-pentane, n-hexane, n-heptane, n-octane, n-dodecane and n-hexadecane have been measured over the whole composition range at two temperatures. The results are compared to the excess volume of mixing bicyclohexyl with the same solvents.     

X-ray determination of the mean amplitudes of vibration and debye temperatures of some rare earth monochalcogenides

The x-ray diffraction intensities of Bragg reflections have been measured at room temperature for thulium selenide, samarium sulphide, samarium selenide and samarium telluride. On the basis of a common amplitude approximation, the Debye-Waller factor, the mean amplitude of vibration and the Debye temperature have been evaluated. The values of the Debye temperatures and mean amplitudes of vibration are 176±16°K, 0·185 ± 0·017 Å (TmSe), 155 ± 7°K, 0·244 ± 0·012 Å (SmS), 153 ± 14°K, 0·221 ± 0·020 Å (SmSe) and 151 ± 20°K, 0·204 ± 0·027 Å (SmTe).     

Measuring the efficiency of trigonometric series estimates of a density

Some types of density estimators, particularly those based on trigonometric series, converge reasonably quickly to their limit except in the neighbourhood of one or two singularities. In this situation the mean integrated square error, the traditional measure of the efficiency of a density estimator, is an unsatisfactory measure. The notion of partial mean integrated square error is introduced and used to compare the performance of trigonometric series estimators. The results lead to consideration of some new estimators which have excellent properties from the points of view of both efficiency and ease of computation.     

Triangular lattice Potts models

In this paper we study the 3-state Potts model on the triangular lattice which has two- and three-site interactions. Using a Peierls argument we obtain a rigorous bound on the transition temperature, thereby disproving a conjecture on the location of its critical point. Low-temperature series are generated and analyzed for three particular choices of the coupling constants; a phase diagram is then drawn on the basis of these considerations. Our analysis indicates that the antiferromagnetic transition and the transition along the coexistence line are of first order, implying the existence of a multicritical point in the ferromagnetic region. Relation of the triangularq-state Potts model with other lattice-statistical problems is also discussed. In particular, an Ashkin-Teller model and the hard-hexagon lattice gas solved by Baxter emerge as special cases in appropriate limits.Supported in part by NSF grant No. DMR 78-18808.