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91.
We construct diffusions in random velocity fields which present anomalous superdiffusive behavior. The mean square displacement can be made to have any power lawt
for 1<2. Higher moments and characteristic functions are also investigated. 相似文献
92.
Zhihua Zhou 《Journal of Macromolecular Science: Physics》2013,52(6):1247-1254
The influences of thermal treatment on cold crystallization and the thermal behavior of poly‐L‐lactide (PLLA) were investigated by DSC and polarizing microscopy. Both the cooling and heating rates had effects on cold crystallization. Double peaks were observed for the samples on subsequently heating at 10°C min?1 after cooling between 5 and 20°C min?1. The degrees of crystallinity dramatically increased with decreasing cooling rate, and the size of PLLA spherulites increased with a decrease in the cooling rate. Double cold crystallization peaks were also observed during heating traces at higher rates for this material after fast cooling (20°C min?1) from the melt. The competition between the crystallization from the nuclei formed during cooling, and that from spontaneous nucleation might be responsible for the appearance of double peaks. 相似文献
93.
Hui-Juan Huang Bang-Hu Xie Wei Yang Yue-Xin Shen Ming-Bo Yang 《Journal of Macromolecular Science: Physics》2013,52(2):231-241
The influence of polyolefin elastomer (POE) content on the fracture behavior of injection-molded polypropylene (PP)/POE blends was evaluated by means of the essential work of fracture (EWF) method. The results indicated that the EWF approach worked well for the PP/POE blends when POE content was 0~7.5 wt% of the blends. The specific essential work of fracture (w e) increased with increasing POE content, and the dominant factor that affected w e was the necking and subsequent fracture process. The specific nonessential work of fracture (βw p) slightly decreased with increasing POE content, while the specific plastic work (w p) showed an increasing trend with the decrease of the shape factor (β) of the specimen. Finally, it was shown that w e could be predicted reasonably well via the COD values. 相似文献
94.
C. V. Chaudhari K. A. Dubey Y. K. Bhardwaj S. Sabharwal 《Journal of Macromolecular Science: Physics》2013,52(5):839-859
Different compositions of SBR/EPDM 50:50 blends containing multiple-walled carbon nanotubes (MWNT) as nanoparticulate fillers (0.5%–10%) were evaluated for radiation sensitivity and solvent permeability. The efficiency of radiation ***cross-linking was analyzed by gel-content and Charlesby–Pinner parameter measurements. ***Gamma-radiation-induced cross-linking extent was found to increase with radiation dose and MWNT concentration, which was reflected in different extents of swelling. Rigorous analysis of swelling and diffusion data, on the basis of the transport exponent (n) values and diffusion/relaxation rate indicated anomalous diffusion behavior for most of the nanocomposites. The swelling extent in different solvents was found to be a function of polymer-solvent interaction as well as stearic hindrance due to the structure/size of the solvent molecules. Polymer-filler interaction investigated by a Kraus plot indicated high reinforcement of the SBR/EPDM matrix on MWNT addition. There was no significant change in surface energy or hydrophilicity of the SBR/EPDM matrix on introduction of MWNT into it. 相似文献
95.
Kawaljeet Singh Samra Ravinder Singh Lakhwant Singh 《Journal of Macromolecular Science: Physics》2013,52(10):691-698
Polyethylene terephthalate (PET) films of 50?μm thickness were exposed to swift-heavy 50?MeV copper and 84?MeV oxygen ions, with fluence varying from 1?×?1011 to 1?×?1013 ions cm?2. Differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) and UV-visible spectroscopic techniques were used to characterize the irradiated samples. The XRD and DSC analysis indicated the loss of crystallinity during/after the irradiation. The FTIR spectra revealed the formation of alkyne end groups, C═C groups and structural deformation with increase of ion fluence. Considerable reduction in the value of the optical bandgap was inferred from the study of the UV-visible absorption curves. 相似文献
96.
In this paper,the supersymmetric Camassa-Holm equation and Degasperis-Procesi equation are derived from a general superfield equations by choosing different parameters.Their peakon-type solutions are shown in weak sense.At the same time,the dynamic behaviors are analyzed particularly when the two peakons collide elastically,and some results are compared with each other between the two equations. 相似文献
97.
The magnetocaloric effect(MCE) in EuCu1.75P2 compound is studied by the magnetization and heat capacity measurements.Magnetization and modified Arrott plots indicate that the compound undergoes a second-order phase transition at TC ~ 51 K.A large reversible MCE is observed around TC.The values of maximum magnetic entropy change(-△SxMma) reach 5.6 J·kg-1·K-1 and 13.3 J·kg-1·K-1 for the field change of 2 T and 7 T,respectively,with no obvious hysteresis loss in the vicinity of Curie temperature.The corresponding maximum adiabatic temperature changes(△Tadmax) are evaluated to be 2.1 K and 5.0 K.The magnetic transition and the origin of large MCE in EuCu1.75P2 are also discussed. 相似文献
98.
基于改进的Newman和Ziff算法以及有限尺寸标度理论, 通过对表征渗流相变特征物理量的序参量、平均集团尺寸、二阶矩、标准偏差及尺寸不均匀性的数值模拟, 分析研究了Erdös Rényi随机网络上Achlioptas爆炸渗流模型的相变性质.研究表明: 尽管序参量表现出了不连续相变的特征, 但序参量以及其他特征物理量仍具有连续相变的幂律标度行为.因此严格地说, Erdös Rényi随机网络中的爆炸渗流相变是一种奇异相变, 它既不是标准的不连续相变, 又与常规随机渗流表现出的连续相变处于不同的普适类.
关键词:
Erdös Rényi随机网络
爆炸渗流模型
相变
幂律标度行为 相似文献
99.
We investigate the temporal behavior of low-amplitude dark spatial solitons in biased centrosymmetric crystals with two-photon photorefractive effects. The expressions of time-dependent space-charge field and dynamical evolution equation are derived. The temporal behaviors of the intensity profiles and the intensity full width at half maximum (FWHM) of dark solitons are investigated by numerical method. The results indicate that a broad soliton is generated at the beginning, and as time evolves, the intensity width of solitons decrease monotonously to a minimum value toward steady state. Within the same propagation time, the higher the ratio of soliton peak intensity to the dark irradiation intensity is, the shorter the FWHM of dark solitons is. 相似文献
100.
本文采用静电自组装的方法制备了二维纳米银膜。UV-vis吸收光谱显示其等离子体共振吸收带位于400+900nm的光谱范围,延伸到了近红外区,可以较好的匹配785nm的近红外激发光源。以该纳米银膜为基底,对2-氨基苯硫酚(2-ATP)分子进行了近红外表面增强拉曼散射(NIR-SERS)检测,获得了重复性良好的NIR-SERS光谱图。实验表明:以2-ATP为探针分子时,该纳米银膜的NIR-SERS增强因子达到2.19×109。同时,本文采用密度泛函理论(DFT),以B3LYP/6-31G为基函数,对2-ATP分子进行结构优化和普通拉曼光谱(NR)计算,发现理论值和实验值吻合较好。此外,对2-ATP的NIR-SERS谱带进行了归属分析,发现当2-ATP分子在纳米银表面吸附时,是以-SH基团吸附到银表面,且同时-SH基团会被纳米银氧化。 相似文献