全文获取类型
收费全文 | 865篇 |
免费 | 59篇 |
国内免费 | 143篇 |
专业分类
化学 | 929篇 |
晶体学 | 5篇 |
力学 | 1篇 |
综合类 | 16篇 |
数学 | 10篇 |
物理学 | 106篇 |
出版年
2024年 | 1篇 |
2023年 | 15篇 |
2022年 | 50篇 |
2021年 | 63篇 |
2020年 | 46篇 |
2019年 | 39篇 |
2018年 | 24篇 |
2017年 | 33篇 |
2016年 | 54篇 |
2015年 | 37篇 |
2014年 | 39篇 |
2013年 | 57篇 |
2012年 | 87篇 |
2011年 | 40篇 |
2010年 | 30篇 |
2009年 | 35篇 |
2008年 | 49篇 |
2007年 | 32篇 |
2006年 | 34篇 |
2005年 | 39篇 |
2004年 | 43篇 |
2003年 | 24篇 |
2002年 | 32篇 |
2001年 | 26篇 |
2000年 | 14篇 |
1999年 | 9篇 |
1998年 | 21篇 |
1997年 | 12篇 |
1996年 | 12篇 |
1995年 | 10篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 6篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1978年 | 2篇 |
1976年 | 2篇 |
排序方式: 共有1067条查询结果,搜索用时 0 毫秒
981.
利用傅立叶变换红外光谱( FTlR)和衰减全反射( ATR)技术,建立了人血清葡萄糖的快速定量分析方法。根据葡萄糖水溶液与纯净水差谱得到葡萄糖的指纹吸收波段(1200~900 cm-1),分别在全谱(4000~600 cm-1)和指纹波段建立偏最小二乘法( PLS)模型,指纹波段的预测效果明显好于全谱。选择指纹波段后,提出一种根据浓度分段分别建模然后进行组合的建模方法。按照全部样品、低浓度样品、高浓度样品分别建立模型后,根据3个模型进行综合决策。应用独立的检验集对样品进行测试表明,按葡萄糖浓度范围分段建立组合模型的预测效果优于基于全部样品建模的预测效果。对于分段阈值附近的样本,低浓度和高浓度模型的预测效果差别不大。浓度分段组合模型的预测均方根偏差( RMSEP)和预测相关系数( Rp )分别为0.732 mmol/L和0.948。 相似文献
982.
Fuyan Liu Peng Wang Qianqian Zhang Zeyan Wang Yuanyuan Liu Zhaoke Zheng Xiaoyan Qin Xiaoyang Zhang Ying Dai Baibiao Huang 《Electroanalysis》2019,31(9):1809-1814
A non‐enzyme photoelectrochemical (PEC) glucose sensor based on α‐Fe2O3 film is investigated. The α‐Fe2O3 film was fabricated via a simple spin coating method. The proposed glucose sensor exhibits good selectivity, a fast response time of <5 s, a linear range of 0.05 to 6.0 mM, sensitivity of 17.23 μA mM?1 cm?2 and a detection limit of 0.05 μM. Meanwhile, the excellent performances of the α‐Fe2O3 sensor were obtained in reproducibility and the long‐term stability under ambient condition. The linear amperometric response of the sensor covers the glucose levels in physiological and clinical for diabetic patients. Therefore, this non‐enzyme PEC sensor based on α‐Fe2O3 film has a great potential application in the development of glucose sensors. 相似文献
983.
Jia Liu Qianyi Song Wenqing Zheng Wenhui Jia Haijiao Jia Yaqin Nan Fangfang Ren James Jianmin Bao Youxin Li 《Journal of separation science》2022,45(13):2415-2428
A novel boronic acid and carboxyl-modified glucose molecularly imprinted polymer were prepared through suspension polymerization, which is based on 1.0 mmol glucose as a template, 1.2 mmol methacrylamidophenylboronic acid, and 6.8 mmol methacrylic acids as monomers, 19 mmol ethyleneglycol dimethacrylate, and 1 mmol methylene-bis-acrylamide as crosslinkers. The prepared glucose-molecularly imprinted polymer had a particle size of 25–70 μm, and was thermally stable below 215°C, with a specific surface area of 174.82 m2/g and average pore size of 9.48 nm. The best selectivity between glucose and fructose was 2.71 and the maximum adsorption capacity of glucose- molecularly imprinted polymer was up to 236.32 mg/g which was consistent with the Langmuir adsorption model. The similar adsorption abilities in six successive runs and the good desorption rate (99.4%) verified glucose-molecularly imprinted polymer could be reused. It was successfully used for extracting glucose from cellulose hydrolysis. The adsorption amount of glucose was 2.61 mg/mL and selectivity between glucose and xylose reached 4.12. A newly established chromatography (glucose-molecularly imprinted polymer) mediated hollow fiber membrane method in time separated pure glucose from cellulose hydrolysates on a large scale, and purified glucose solution with a concentration of 3.84 mg/mL was obtained, which offered a feasible way for the industrial production of glucose from cellulose hydrolysates. 相似文献
984.
985.
In order to evaluate the effect of blood glucose concentration on the reliability of AZ31 magnesium alloy medical implant, the corrosion of AZ31 alloy was studied in a simulated physiological saline solution. It is found that when the glucose concentration is in the normal range of ca. 1 g/L, the corrosion of AZ31 alloy can be inhibited. However, when the glucose concentration becomes higher like that of diabetic patients, the degradation of AZ31 alloy is significantly accelerated. Therefore, for diabetic patients, the change in glucose concentration must be taken into consideration in order to ensure the reliability of AZ31 medical implants. 相似文献
986.
987.
以L-酒石酸和一水柠檬酸为混合碳源,以乙二胺为氮源和聚合试剂,并添加六水三氯化铁,通过一锅溶剂热法合成了氮、铁共掺杂碳纳米粒子(N/Fe-CNPs),采用制备的N/Fe-CNPs模拟过氧化物酶催化过氧化氢(H2O2)氧化3,3',5,5'-四甲基 产生可溶性的蓝色产物,联合葡萄糖氧化酶建立了测定H2O2和葡萄糖含量的新方法。 结果显示:H2O2及葡萄糖的浓度与反应体系的吸光度呈良好的线性关系,H2O2的线性范围为0.2~20 μmol/L,葡萄糖的线性范围为0.1~1.0及1.0~80 μmol/L,最低检出限分别可达42.5和76.1 nmol/L。 相似文献
988.
通过溶胶-凝胶法制备的Imm-Fe3+-IL纳米材料具有类过氧化物酶的活性,能够催化过氧化氢(H2O2)快速氧化3,3′,5,5′-四甲基联苯胺(TMB)产生相应的颜色变化。 稳态动力学分析表明,Imm-Fe3+-IL纳米材料遵循典型的Michaelis-Menten模型和乒乓机理。 辣根过氧化物酶(HRP)相比,Imm-Fe3+-IL纳米材料纳米材料具有更强的亲和性。 联合葡萄糖氧化酶建立了H2O2和葡萄糖的比色检测方法。 结果显示:H2O2和葡萄糖的浓度与反应体系的吸光度呈良好的线性关系,H2O2的线性范围为1~200 μmol/L,葡萄糖的线性范围为10~200 μmol/L,最低检出限(LOD)分别为0.35和3.31 μmol/L。 相似文献
989.
Binghui Li Man Wang Kui Chen Zhifeng Cheng Gaojian Chen Zexin Zhang 《Macromolecular rapid communications》2015,36(12):1200-1204
Janus particles with anisotropic biofunctionalities are perfect models to mimic anisotropic architectures and directional interactions that occur in nature. It is therefore highly desirable to develop reliable and efficient methods to synthesize biofunctional Janus particles. Herein, a facile method combining seeded‐emulsion polymerization and thiol‐click chemistry has been developed to synthesize Janus particles with glucose moieties on one side. These biofunctional Janus particles show region‐selective binding of protein, which represents a big step toward biomimicry, and demonstrates the potential of the bioJanus particles for targeted drug delivery and binding.
990.
Thin, phenylboronic acid‐containing polymer coatings are potentially attractive sensory layers for a range of glucose monitoring systems. This contribution presents the synthesis and properties of glucose‐sensitive polymer brushes obtained via surface RAFT polymerization of 3‐methacrylamido phenylboronic acid (MAPBA). This synthetic strategy is attractive since it allows the controlled growth of PMAPBA brushes with film thicknesses of up to 20 nm via direct polymerization of MAPBA without the need for additional post‐polymerization modification or deprotection steps. QCM‐D sensor chips modified with a PMAPBA layer respond with a linear change in the shift of the fundamental resonance frequency over a range of physiologically relevant glucose concentrations and are insensitive toward the presence of fructose, thus validating the potential of these polymer brush films as glucose sensory thin coatings.