Synthesis and Structure Investigation of a Novel 3-Dimensional Potassium Supermolecular Compound Based on 2,4-Dinitro Resorcinol

A novel 3‐dimensional potassium supermolecular compound [K(HDNR)(H₂DNR)(H₂O)]_n (H₂DNR?2,4‐dinitro resorcinol) was synthesized and characterized by elemental analysis and FT‐IR spectroscopy. The crystal structure investigated by X‐ray single crystal diffraction shows that [K(HDNR)(H₂DNR)(H₂O)]_n crystallizes with a monoclinic unit cell in the space group P2(1)/c with unit cell dimensions of a=17.648(5) Å, b=12.527(3) Å, c=7.735(2) Å, β=94.33(2)°, V=1705.00(73) ų, Z=4. The structure was refined to the final R=0.0670 and wR=0.0722 for 2022 observed reflections with I>2σ(I). In the compound, potassium cation is assembled into one‐dimensional chains along c‐axis through oxygen atoms from water molecules, and the chains were connected by the bridged HDNR^? anions to form a two‐dimensional net structure. The two‐dimensional nets constructed a three‐dimensional supramolecular architecture via intermolecular hydrogen bonds and N–O···π interaction. Density functional theory (DFT) B3LYP was employed to optimize the structure and calculate energies for three tautomers of HDNR^? univalent anion. Three stable tautomers were located. It was found that the structure (I) with O(1) losing hydrogen atom is more stable than the structure (II) also with O(1) losing hydrogen atom and the structure (III) with O(4) losing hydrogen atom.     

MB-GNG: Addressing drawbacks in multi-objective optimization estimation of distribution algorithms

We examine the model-building issue related to multi-objective estimation of distribution algorithms (MOEDAs) and show that some of their, as yet overlooked, characteristics render most current MOEDAs unviable when addressing optimization problems with many objectives. We propose a novel model-building growing neural gas (MB-GNG) network that is specially devised for properly dealing with that issue and therefore yields a better performance. Experiments are conducted in order to show from an empirical point of view the advantages of the new algorithm.     

Interference effects of two and three super-tall buildings under wind action

Most previous investigations on interference effects of tall buildings under wind actions focused on the wind induced interference effects between two buildings,and the interference effects of three or more buildings have seldom been studied so far due to the huge workload involved in experiments and data processing.In this paper,mean and dynamic force/response interference effects and peak wind pressure interference effects of two and three tall buildings,especially the three-building configuration,are investigated through a series of wind tunnel tests on typical tall building models using high frequency force balance technique and wind pressure measurements.Furthermore,the present paper focuses on the effects of parameters,including breadth ratio and height ratio of the buildings and terrain category,on the interference factors and derives relevant regression results for the interference factors.     

浅论建筑结构分析中计算简图的建立

建筑结构的力学分析都是通过建立计算简图及计算模型进行的, 探讨了 建筑结构计算简图及计算模型的概念、建立计算简图的原则、对实际建筑结构进行简化的内 容, 并介绍了5种实际建筑结构简化的结果, 期望能帮助学生做好结构分析.     

Controlled blocks of the finite quasisimple groups for odd primes

We classify controlled blocks, introduced by Alperin and Broué in 1979 for all quasisimple groups G for odd primes. The results imply that every nilpotent block of G has abelian defect groups, which in turn is one of the main results proved in An and Eaton (2011) [6]. We also give an explicit characterization of non-controlled blocks of all quasisimple groups G for odd primes. This implies the block theoretic analogue of Glauberman?s ZJ-theorem for G proved by Kessar, Linckelmann and Robinson (2002) [18].     

THE EXISTENCE OF CONNECTING ORBITS

In this paper,using the notion of an isolating block and Conley's attractor theory,an existence criterion of trajectories connecting a pair of invariant sets of ordinary differential equations is given.     

随机Bregman ADMM及其在训练具有离散结构的支持向量机中的应用

针对具有多块可分结构的非凸优化问题提出了一类新的随机Bregman交替方向乘子法,在周期更新规则下, 证明了该算法的渐进收敛性; 在随机更新的规则下, 几乎确定的渐进收敛性得以证明。数值实验结果表明, 该算法可有效训练具有离散结构的支持向量机。     

关于一类BS的几个结果

本文在自共轭的条件下,找到了群G2×Gp(p为奇素数)中相对于2阶子群的(2a-1pb,2a c-1/2 pb/2,2c)-BS的一种下降构造法和一种嵌套构造法,同时给出了Gp的一个指数界,特别地当G2(?) Z2a×Z2a2时,有a2=a1且c=1或2,或者a2=a1-1且c=1.     

广义线性模型(一)

本讲座是广义线性模型这个题目的一个比较系统的介绍。主要分 3部分 :建模、统计分析与模型选择和诊断。写作时依据的主要参考资料是L .Fahrmeir等人的《MultivariateStatisticalModelingBasedonGeneralizedLinearModels》。     

钛宝石再生放大器实验研究

分析了啁啾脉冲在钛宝石再生放大器中的能量增益与泵浦光及信号光光束口径的关系。并用不同能量的调Ｑ倍频ＮｄＹＡＧ激光器的５３２ｎｍ光为泵浦光，测量了２ＴＷ钛宝石激光系统中钛宝石再生放大器在无注入信号脉冲时和有注入信号脉冲时的脉冲建立时间及相应的输出能量大小。再生放大器的增益为２×１０７。