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173.
Ponnusamy Shanmugam Vadivel Vaithiyanathan Kodirajan Selvakumar 《Tetrahedron letters》2008,49(13):2119-2123
A simple, mild and efficient CAN mediated oxidation of Morita-Baylis-Hillman adducts of 5-methyl-N-alkylisatins 1a-13a to 5-formyl-N-alkylisatins 1b-13b under ambient reaction conditions is reported. Simple and isomerized 5-methyl-N-alkylisatin derivatives 1-4 have also been tested and failed to provide the corresponding formylated products. A plausible reaction mechanism has been proposed. 相似文献
174.
Benefited from the rapid development of MBH reaction, the reaction of MBH adducts have been established as the most synthetically useful transformations. However, compared with the well-established allylic alkylations and (3+2)-annulations, the (1+4)-annulations of MBH adducts have not developed rapidly until recently. As a helpful complement to the (3+2)-annulations of MBH adducts, the (1+4)-annulations of MBH adducts opens a robust access to structurally diverse five-membered carbo- and heterocycles. This paper summarizes recent advances in organocatalytic (1+4)-annulations using MBH adducts as 1 C-synthons for the construction of functionalized five-membered carbo- and heterocycles. 相似文献
175.
Crystals of [Cu(Eddp)·(HgCl2)3]n (monoclinic, a = 9.7547(7) Å, b = 18.3716(12) Å, c = 11.7811(9) Å, β = 94.828(9)°, Z = 4, space group P21/n) are made of infinite sheets involving dimeric complexes [Cu2(Eddp)2] interacting with quasi-molecules of HgCl2 (Hg-Cl 2.29-2.36 Å). In the dimers, copper atoms are squarely surrounded by two N atoms and two O atoms of the ethylendiamine-N,N′-di(3-propionate) anion, and atom from a neighboring Eddp ion in the apical position; the second apical position is occupied by a Cl atom of one of HgCl2 molecules. Weak Hg-Cl interactions (2.98-3.07 Å) join the molecules of HgCl2 in almost planar centrosymmetrical Hg6Cl12 hexamers, and further (Hg-Cl 3.168(3) Å, 3.250(2) Å) in infinite chains of the hexamers. Finally, the dimeric copper complexes are linked to six Hg atoms of four adjacent hexamers by virtue of their oxygen atoms (Hg-O 2.322(8), 2.609(6) Å, 2.730(5) Å). 相似文献
176.
Avradeep Samanta Ishani Mitra Venkata P. Reddy B. Subhajit Mukherjee Sujay Mahata Wolfgang Linert 《Journal of Coordination Chemistry》2017,70(6):1032-1052
Kinetics of interaction between [Pt(pic)(H2O)2](ClO4)2, 2 (where pic = 2-aminomethylpyridine) with the selected ligands DL-methionine (DL-meth) and DL-penicillamine (DL-pen) have been studied spectrophotometrically in aqueous medium separately as a function of [2] as well as [ligand], pH and temperature at constant ionic strength. The association equilibrium constants (KE) for the outer sphere complex formation have been evaluated together with the rate constants for the two subsequent steps. Activation parameters (enthalpy of activation ΔH≠ and entropy of activation ΔS≠) were calculated from the Eyring equation. An associative mechanism of substitution is proposed for both reactions on the basis of the kinetic observations, evaluated activation parameters, and spectroscopic data. Structural optimizations, HOMO-LUMO energy calculation, and Natural Bond Orbital (NBO) analysis of 2–4 were carried out with Density Functional Theory. Bonding mode of thiol and thio-ether is confirmed by spectroscopic analyses and NBO calculation. Cytotoxic properties of 2–4 were explored on A549 carcinoma cell lines; DNA-binding properties of the complexes were also investigated by gel electrophoresis. 相似文献
177.
Formation of Dialkyl 2‐[3‐Alkoxy‐1‐(alkylimino)‐1‐chloro‐3‐oxopropan‐2‐ylidene]hydrazine‐1,1‐dicarboxylates of α‐(Alkoxycarbonyl)imidoyl Chlorides from PhosphineDiazo Ester Zwitterions and Nef‐Isocyanide Adducts 下载免费PDF全文
A novel transformation involving phosphine? diazo ester zwitterions (generated from dialkyl azodicarboxylates with Ph3P) and α‐(alkoxycarbonyl)imidoyl chlorides (prepared from α‐addition of acyl chlorides to alkyl isocyanides) to afford dialkyl 2‐[3‐alkoxy‐1‐(alkylimino)‐1‐chloro‐3‐oxopropan‐2‐ylidene]hydrazine‐1,1‐dicarboxylates in moderate yields, is described. 相似文献
178.
Gaoxiang Liu Nikita Fedik Chalynette Martinez-Martinez Sandra M. Ciborowski Prof. Dr. Xinxing Zhang Prof. Dr. Alexander I. Boldyrev Prof. Dr. Kit H. Bowen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(23):8840-8844
We reply to the comment by S. Pan and G. Frenking who challenged our interpretation of the Na−:→BH3 dative bond in the recently synthesized NaBH3− cluster. Our conclusion remains the same as that in our original paper ( https://doi.org/10.1002/anie.201907089 and https://doi.org/10.1002/ange.201907089 ). This conclusion is additionally supported by the energetic pathways and NBO charges calculated at UCCSD and CASMP2(4,4) levels of theory. We also discussed the suitability of the Laplacian of electron density (QTAIM) and Adaptive Natural Density Partitioning (AdNDP) method for bond type assignment. It seems that AdNDP yields more sensible results. This discussion reveals that the complex realm of bonding is full of semantic inconsistencies, and we invite experimentalists and theoreticians to elaborate this topic and find solutions incorporating different views on the dative bond. 相似文献
179.
The data of 1H nuclear magnetic resonance and molar conductivity prove that there is a molecule‐ion interaction between α‐cyclodextrin (α‐CD) and sodium arsenite (SA), and the interaction site is different from that between β‐CD and SA. The packing mode of α‐CD molecules after adduct with SA is changed from cage to channel type. Several experimental phenomena from thermogravimetric analyses and gas chromatography coupled to time‐of‐flight mass spectrometry measurements reveal that the presence of SA has led to a large change of thermal decomposition behavior of α‐CD, and vice versa. The current work reveals the particularity of the interaction between SA and α‐CD, which would provide new insight into the understanding of molecule‐ion interactions. 相似文献
180.
利用水热技术合成了2个新型钴支撑的磷钼多金属氧酸盐超分子化合物:(C2N2H10)5[(P4Mo6O25(OH)6)2Co](1)和(Co(H2O)6)2(C5NH6)6[(P4Mo6O25(OH)6)2Co]·10H2O(2).并通过元素分析、红外光谱、热重分析和X射线单晶衍射对2个化合物进行了表征.结果表明:化合物1属于三斜晶系,P-1空间群;晶胞参数a=1.179 9(2)nm,b=1.337 7(2)nm,c=1.479 7(3)nm,α=73.435(2)°,β=74.383(2)°,γ=66.499(2)°,V=2.020 5(6)nm3,F(000)=1 327,Z=1;化合物2属于属于三斜晶系,P-1空间群;晶胞参数a=1.220 68(11)nm,b=1.381 08(13)nm,c=1.687 18(15)nm,α=92.275(1)°,β=104.774(1)°,γ=114.475(1)°,V=2.468 8(4)nm3,F(000)=1 649,Z=1. 相似文献