Hcp-icosahedron structural transformation induced by the change in Ag concentration during the freezing of （CoAg）561 clusters

The synergy effect of alloy elements in bimetallic clusters can be used to tune the chemical and physical properties. Research on the influences of alloy concentration and distribution on the frozen structure of bimetallic clusters plays a key rolc in exploring new structural materials. In this paper, we study the influence of Ag concentration on the frozen structure of the （AgCo）561 cluster by using molecular dynamics simulation with a general embedded atom method. The results indicate that tt~e structure and chemical ordering of the （AgCo）561 cluster are strongly related to Ag concentration. Hcp-icosahedron structural transformation in the frozen （CoAg）561 cluster can be induced by changing Ag concentration. The chemical ordering also transforms to Janus-like Co Ag from core-shell Co-Ag.     

Transformation of macromonomers into ring‐opening polymerization macroinitiators: A detailed initiation efficiency study

In the present study, n‐butyl acrylate macromonomer (BAMM) (M_n = 1900 g mol^?1; PDI = 1.96) has been synthesized via a high‐temperature polymerization process. Subsequently, the olefinic termini of the BAMM have been transformed into a diol via a dihydroxylation process using KMnO₄ as an oxidizing agent. The OH‐terminated macroinitiator pBA(OH)₂ has subsequently been employed for the ring‐opening polymerization (ROP) of ε‐caprolactone via various catalytic systems, that is, organo‐(1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene), metal (tin(II) 2‐ethylhexanoate), and enzymatic catalysis (Novozym® 435). The obtained pBA‐b‐pCL block copolymers and the initiation efficiency of the BAMM macroinitiator have been investigated via size exclusion chromatography (SEC), electrospray ionization–mass spectrometry (ESI‐MS) hyphenated with SEC and liquid chromatography at the critical conditions of both poly(ε‐caprolactone) (pCL) and pBA. The in vitro enzyme catalysis (eROP) approach proved to be the most efficient catalysis system due to minor transesterification side reactions during the polymerization process. However, side reactions such as transesterifications occur in each catalytic system and—while they cannot be suppressed—they can be minimized. The species generated during the eROP process include the desired block copolymer pBA‐b‐pCL as main species as well as pCL homopolymer and residual macroinitiator pBA(OH)₂. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

一种线性模型的精确转换方法

基于广义范德蒙矩阵的逆矩阵的计算方法,导出线性系统的连续时间模型和离散时间模型在含有重极点时的严格的直接换算关系,其结果可以直接表示为两者的分子多项式系数之间的关系,并且,对不同的调制器具有统一的转换形式.     

Auxiliary-field Monte Carlo methods

I discuss Monte Carlo algorithms for quantum many-body systems that employ an auxiliary field to linearize a two-body interaction. These reduce the evaluation of the partition function to sampling many one-body evolutions in a fluctuating field. Fermions and bosons are treated on an equal footing. Applications to potential models and to quantum spin systems are discussed. This work was supported in part by the National Science Foundation, grants PHY82-07332 and PHY85-05682. The potential-model studies were done in collaboration with G. Sugiyama, while A. Khan and T. Troudet were responsible for the work on the quantum spin systems.     

Supersymmetric classical mechanics

The purpose of the paper is to construct a supersymmetric Lagrangian within the framework of classical mechanics which would be regarded as a candidate for passage to supersymmetric quantum mechanics. The authors felicitate Prof. D S Kothari on his eightieth birthday and dedicate this paper to him on this occasion.     

利用X射线衍射研究冲击波合成纤锌矿型氮化硼

 用X射线衍射法，对不同结晶度的石墨型氮化硼（gBN）在冲击波作用下转变成的纤锌矿型氮化硼（wBN）产物进行了研究，对wBN中的杂质含量等进行了分析。结果表明：gBN的石墨化指数G.I值对wBN的产率有明显的影响。     

不共轴光学系统自动优化中的有关问题

描述不共轴光学系统计算机优化中坐标变换与逆变换、“入瞳”与光线坐标、像面基准与质量函数定义的一致性问题。     

A novel optical technique for realizing real-time Logarithmic transformation

We propose a novel optical technique for performing real-time nonlinear transformation and particularly for realizing Logarithmic transformation     

一类三阶非线性分布时滞动力方程的振动结果

研究一类三阶非线性分布时滞动力方程的振动性,通过构造广义Riccati变换得到一类新的广义Riccati不等式,利用积分平均技巧等方法,建立了保证该方程一切解均振动或收敛于0的若干新的振动结果,推广和改进了近期文献的相关结论,并给出了若干例子。     

基于RTD可编程逻辑门的n变量函数实现算法

共振隧穿二极管（RTD）可编程逻辑门是一种由单双稳态转换逻辑单元（MOBILE）及正、负输入分支组成的阈值逻辑电路。基于二进制神经元模型中的三层网络结构,提出了基于RTD可编程逻辑门的n变量函数实现算法。按照汉明距离由大到小的顺序,搜索最优输入向量,用定理1或定理2方法产生隐层函数,通过变换次数,确定输入向量的真假及隐层函数的权重。由于定义了最优输入向量及变换次数,提高了算法的准确性;又由于采用了定理2方法,令设计的电路更简单。