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131.
G. Graham Allan Angel P. Stoyanov Masahiro Ueda Amar Yahiaoui 《Cellulose (London, England)》2001,8(2):127-138
The incorporation of sucrose or some other disaccharides (cellobiose, -lactose or trehalose) into the cell wall of pulp fibers increases the tearing resistance of the resultant sugar-containing paper relative to that of its sugar-free counterpart, but only when the fiber is well-refined. Maltose and -lactose do not exhibit this effect. By the use of a high cellulose pulp the increase is shown not to be due to the presence of hemicelluloses. Differential scanning calorimetry indicates that the interaction between the sucrose molecules and the cellulosic fibers changes and becomes more uniform as the fibers are refined. Although the azo dye Congo red bonds strongly with cellulose the analogous reaction with disaccharides and cyclodextrins, established spectrophotometrically, could not be used to predict the physical outcome of the interactions with added disaccharides or cyclodextrins. From a consideration of the stereochemistry of the impregnant disaccharides the augmentation of the fiber strength is attributed to the interlamellar hydrogen bonding of impregnant molecules having hydroxy endgroups in the cis conformation and separated by about 10Å. The incorporation of cyclodextrins further demonstrates that the conformation and the separation distance between the OH groups located in the interlamellar sugar molecule play an important role in strengthening the sugar-impregnated fiber and in augmenting the tearing resistance of sugar-containing papers. 相似文献
132.
Hossein Iloukhani Saied Azizian Narges Samadani 《Reaction Kinetics and Catalysis Letters》2001,72(2):239-244
A kinetic study of the hydrolysis of sucrose by solid catalysts has been carried out using a polarimetric technique. V2O5/-Al2O3 was selected as appropriate catalyst. At the optimum conditions the activation parameters have been evaluated using the Arrhenius and Eyring plots. 相似文献
133.
The preparation of alumina with large surface area, certain phase and porosimetry has always been one of important researches. A new method using much less sucrose (the molar ratio of sucrose to Al^3 =0.5) was developed to prepare γ-Al2O3 with large surface area and high thermal stability. Firstly, ammonium hydroxide was dropped to aqueous solution of aluminum nitrate and sucrose. The resulted precipitate in suspension washeated until a homogeneous gel was ohtained. Then the gel was dehydrated at 110℃ to get a fluffy black precursor. Finally, γ-Al2O3 with A=345m^2/g was prepared by calcining the preeursor at 600℃ for 24h. The precursor and the obtained γ-Al2O3 were characterized by DTA-TG, N2 adsorption-desorption isotherms, XRD and TEM, According to the dispersion behaviors of organic compounds on supports, the related mechanism was discussed. 相似文献
134.
对蔗糖转化反应动力学实验的实验思路、内容设计进行了重新设计,简化了实验过程,提高了实验可操作性,实际测定结果满意。 相似文献
135.
建立了毛细管区带电泳-间接紫外检测快速测定食品中乳糖、蔗糖、葡萄糖和果糖的方法。以水或5 mmol/L醋酸为样品提取液,未涂层熔融石英毛细管(30.2 cm(有效长度20 cm)×50 μm)为分离柱,4 mmol/L山梨酸钾+10 mmol/L磷酸钠+30 mmol/L NaOH(pH 12.56)+0.5 mmol/L十六烷基三甲基溴化铵(CTAB)为分离缓冲液,在-8 kV下分离,于254 nm波长下检测,10 min内实现了食品中上述4种糖的同时分离与测定。乳糖、蔗糖、葡萄糖和果糖的检出限(S/N=3)分别为50、75、25和25 mg/L,定量限(S/N=10)分别为150、225、75和75 mg/L,回收率在87.0%~107.0%之间,相对标准偏差在1.2%~4.7%之间。整个实验过程未使用有机溶剂。用该法测定了9种食品样品及1个质控样品,结果表明该法简单、快速、准确,适用于食品中乳糖、蔗糖、葡萄糖和果糖的日常测定。 相似文献
136.
137.
Two new sucrose esters, β-D-(1-O-acetyl-3,6-O-trans-diferuloyl)fructofuranosyl-α-D-2′-O-acetylglucopyranoside (1) and β-D-(1-O-acetyl-3-O-cis-feruloyl-6-O-trans-feruloyl)fructofuranosyl-α-D-2′,4′,6′-O-triacetylglucopyranoside (2), together with four known sucrose esters (3–6) have been isolated from the rhizome of Sparganium stoloniferum Buch.-Ham. Their structures were elucidated by physical and chemical evidence and spectral analysis. 相似文献
138.
139.
《Arabian Journal of Chemistry》2023,16(3):104525
Fructus Corni (FC), as a promising Chinese medicinal herb, has aroused considerable interest. Generally, FC needs to be processed according to the limited standard policy in China before clinical application, while the investigations on the specific processing methods (such as wine steaming or high-pressure wine steaming) are unclear. A comprehensive metabolomics strategy based on integrated non-targeted metabolomics and targeted glycomics in this paper was implemented to investigate the influences of the different processing technologies such as steaming, wine steaming, high-pressure steaming, high-pressure wine steaming, wine immersion, and wine stir-frying on FC, respectively. UHPLC-Q-TOF-MS/MS was employed for identifying and distinguishing the secondary metabolites. A total of 85 components were identified in all groups. The results of PCA score plots showed that the crude and processed samples had a complete separation, and wine steamed and high-pressure wine steamed samples could be a category, indicating that the two processed products had a similar quality. Multiple chromatography including HPLC (C18)-PDA, HPLC (NH2)-ELSD, and HPGPC-ELSD was used for determining the molecular weight distributions, the monosaccharide compositions of polysaccharides, and the contents of free monosaccharides and oligosaccharides. The results indicated that the content and composition of saccharides were different in crude and different processed FC. The polysaccharides were composed of fucose, arabinose, galactose, glucose, galacturonic acid, mannose and rhamnose, and the free monosaccharides were composed of fucose, arabinose, galactose, glucose, mannose, rhamnose and fructose in all FC samples. The PCA score plots of the glycomics indicated that the crude and high-pressure wine steamed FC could be a category, showing that the two groups had similar chemical compositions. Ultimately, the simulation processing experiments indicated that the transformation of morroniside, polysaccharides, oligosaccharides, fructose, and glucose to 5-HMF through the reactions of dehydration and deglycosylation was the potential mechanism of enhancing the effects by processing. Conclusionly, the saccharides should be investigated as thoroughly as the secondary metabolites, and the high-pressure wine steamed FC could be an alternative to wine steamed FC. 相似文献