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61.
Summary Coupling reactions of the diazoniumbetaines2, 4, 6a, 6b, 6c with derivatives of 1,6-methano[10]annulene1a–c and/or -naphthol7 yield the dyes3a–c, 5a, 5c, 8a–c, 9, 11. The syntheses of different triazine derivatives12a–c, 13a–c, 15, 16, and17a, 17c are described.
Herrn Kollegen Gerhard Schwenker mit den besten Wünschen zum 65. Geburtstag gewidmet 相似文献
62.
Interference-free determination of Sudan dyes in chilli foods using second-order calibration algorithms coupled with HPLC-DAD 总被引:1,自引:0,他引:1
This paper presents a new method for the determination of Sudan dyes contained in hot chilli samples. The method employs second-order calibration algorithms to handle the recorded data. The second-order calibration algorithms are based on the popular parallel factor analysis (PARAFAC), alternating trilinear decomposition (ATLD) and self-weighted alternating trilinear decomposition (SWATLD), respectively. These chemometric methodologies have the second-order advantage, which is the ability to get accurate concentration estimates of interested analytes even in the presence of uncalibrated interfering components. The results on a set of spiked chilli test shows that low contents of Sudan I and Sudan II in complex chilli mixtures can be accurately determined using the new method. The sample preparation was based on solvent extraction, and internal standard was not required. Quantification was carried out with simple mobile phase. 相似文献
63.
Li Qiu WANG Xiao Jun PENG* Rong ZHANG Guo Quan XU Jing Nan CUI State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian 《中国化学快报》2003,(1)
Indocyanine dyes as fluorescent labeling reagents have been used in bioanalysis1,2. Arylsulfonate indocyanine dyes 1d and 1e developed by Waggoner A. S. et al.3,4 have excellent fluorescent properties combined with good aqueous solubility, are a new generation of fluorescent label compounds for proteins, oligonucleotides and other compounds containing hydroxyl, mercaptol or primary amine groups5. However, photostability of these dyes has been a problem. Z. G. YAO et al.6 reported that p… 相似文献
64.
Empirical solvent parameters of silica surfaces are determined by means of solvatochromic dyes, e.g., Cu(tmen) (acac)+ ClO
4
–
/B(C6H5)
4
–
, Fe(phen)2(CN)2, and Michlers Ketone dissolved in 1,2-dichloroethane or cyclohexane. The values obtained by UV/VIS-measurements are compared with both the polarity scales of Kamlet and Taft and with Gutmann's donor and acceptor numbers. Kamlet and Taft's -parameter (the hydrogen-bond donation capacity of a solvent) is determined independently by means of salicylideneaniline. The * of silica is determined using 5-N,N-dimethylamino-5-nitro-2,2-bithiophene and the complex of tetracyanoethylene with Michlers Ketone, respectively. Further on the reliabilities of the obtained Kamlet-Taft parameters , , and * are checked by comparism with experimental and calculated values of theE
T(30)-parameter of silica by means of multi-parameter regression analysis. The surface properties of silica are influenced mainly by HBD-properties (75%) and dipolarity/polarizability * (20%), but hardly by the HBA-properties (<5%). UV/VIS-measurements were carried out in a special equipment with glass fiber optics, A drawing of the apparatus is given. 相似文献
65.
A series of novel monoazo disperse dyes derived from the coupling of diazotized 2-aminobenzo[b]thiophene derivatives with N-arylmaleimides is described. The monoazo disperse dyes applied to nylon fabric and their dyeing performance has been assessed. These dyes have been found to give light yellow to reddish pink color shades with very good depth and levelness on nylon fabric. The dyed fabric shows moderate light fastness and excellent washing, rubbing, perspiration, and sublimation fastness. The percentage dyebath exhaustion on nylon fabric has been found to be good and acceptable. 相似文献
66.
We present results from a computational study of 4-[4-(dimethylamino)-phenylazo] benzene boronic acid (DABBA) (the 4'-boronic acid isomer of the aminoazobenzene dye N,N-dimethylaminoazobenzene) and its associated anion, as well as, several cyclic esters formed from these azoborates and various conformers of D-glucose. Azo dyes that also contain one or more boronic acid functional groups are of practical importance in the development of chemical sensors for saccharide recognition because of their ability to induce a visible color change upon binding. The lowest-energy DABBA:D-glucose esters found in this investigation consistently involved at least one of the exocyclic hydroxymethyl groups on the D-glucose moiety rather than vicinal cis or trans diol arrangements of hydroxyl groups on the ring. 相似文献
67.
The one-electron oxidation of toluidine blue by specific oxidising radicals such as Cl
2
−
, Tl(II), N3, Br
2
−
etc. has been studied by employing the pulse radiolysis technique. The Br
2
−
radical was found to be less efficient in oxidising toluidine blue as compared to Cl
2
−
., Tl+2 and N3. The semioxidised species exhibited only onepK
a indicating the presence of two conjugate acid-base forms whose spectral and kinetic features were evaluated. Reaction of
OH radicals with the dye gave rise to a transient species which exhibited spectral and kinetic features different from that
of the semioxidised species indicating that the mode of reaction of OH is different. 相似文献
68.
Low‐Symmetry Ω‐Shaped Zinc Phthalocyanine Sensitizers with Panchromatic Light‐Harvesting Properties for Dye‐Sensitized Solar Cells
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Satoshi Yamamoto Angel Zhang Prof. Dr. Martin J. Stillman Prof. Dr. Nagao Kobayashi Prof. Dr. Mutsumi Kimura 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18760-18768
Two low‐symmetry phthalocyanines (Pcs) substituted with thiophene units at the non‐peripheral (α) and peripheral (β) positions were synthesized and their optical, electronic‐structure, and electrochemical properties were investigated. The substitution of thiophene units at the α positions of the phthalocyanine skeleton resulted in a red shift of the Q band and significantly modified the molecular‐orbital electronic distributions just below the HOMO and just above the LUMO, with distortion of the typical Gouterman four‐orbital arrangement of MOs. Two amphiphilic Ω‐shaped ZnPcs ( αPcS1 and αPcS2 ) bearing a π‐conjugated side chain with an adsorption site at an α position of the Pc macrocycle were synthesized as sensitizers for dye‐sensitized solar cells (DSSCs). The absorption spectra of αPcS1 and αPcS2 showed red shifted Q bands and a broad band from 350 to 550 nm assignable to the intramolecular charge‐transfer transition from the ZnPc core to the side chains. Time‐dependent DFT calculations provided a clear interpretation of the effect of the thiophene conjugation on the typical phthalocyanine core π MOs. Compound αPcS1 was used as a light‐harvesting dye on a TiO2 electrode for a DSSC, which showed a panchromatic response in the range 400–800 nm with a power conversion efficiency of 5.5 % under one‐sun conditions. 相似文献
69.
Frontispiece: Glycoluril‐Derived Molecular Clips are Potent and Selective Receptors for Cationic Dyes in Water
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70.
Vincent Martinez Prof. Dr. Maged Henary 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(39):13764-13782
Nile red and Nile blue are highly fluorescent and photostable organic dyes from the benzo[a]phenoxazine family. They have been used as histological stains for imaging lysosomes and lipids in vitro. The dyes’ high quantum yields and solvent‐dependent optical properties make them ideal scaffolds for the development of pH probes and local polarity indicators. Reviews of the literature in this area are scarce with only one review ever published in 2006. It has been 10 years since and the field has evolved. This review aims to expand upon topics covered by the previous reviewers and to report on recent advances in the literature. As authors, we hope to convey a sense of scope and to spark renewed interest in this useful niche of dye chemistry. 相似文献