全文获取类型
收费全文 | 12467篇 |
免费 | 575篇 |
国内免费 | 1797篇 |
专业分类
化学 | 14447篇 |
晶体学 | 15篇 |
力学 | 23篇 |
综合类 | 32篇 |
数学 | 5篇 |
物理学 | 317篇 |
出版年
2024年 | 12篇 |
2023年 | 38篇 |
2022年 | 91篇 |
2021年 | 162篇 |
2020年 | 333篇 |
2019年 | 299篇 |
2018年 | 233篇 |
2017年 | 431篇 |
2016年 | 508篇 |
2015年 | 426篇 |
2014年 | 481篇 |
2013年 | 954篇 |
2012年 | 680篇 |
2011年 | 717篇 |
2010年 | 706篇 |
2009年 | 763篇 |
2008年 | 883篇 |
2007年 | 931篇 |
2006年 | 830篇 |
2005年 | 760篇 |
2004年 | 745篇 |
2003年 | 551篇 |
2002年 | 499篇 |
2001年 | 388篇 |
2000年 | 362篇 |
1999年 | 310篇 |
1998年 | 271篇 |
1997年 | 252篇 |
1996年 | 225篇 |
1995年 | 188篇 |
1994年 | 205篇 |
1993年 | 191篇 |
1992年 | 155篇 |
1991年 | 68篇 |
1990年 | 56篇 |
1989年 | 40篇 |
1988年 | 32篇 |
1987年 | 18篇 |
1986年 | 9篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
241.
Reverse iodine transfer polymerisation (RITP) is a living radical polymerisation technique that has shown to be feasible in synthesising segmented styrene-acrylate copolymers. Polymers synthesised via RITP are typically only described regarding their bulk properties using nuclear magnetic resonance spectroscopy and size exclusion chromatography. To fully understand the complex composition of the polymerisation products and the RITP reaction mechanism, however, it is necessary to use a combination of advanced analytical methods. In the present RITP procedure, polystyrene was synthesised first and then used as a macroinitiator to synthesise polystyrene-block-poly(n-butyl acrylate) (PS-b-PBA) block copolymers. For the first time, these PS-b-PBA block copolymers were analysed by a combination of SEC, in situ1H NMR and HPLC. 1H NMR was used to determine the copolymer composition and the end group functionality of the samples, while SEC and HPLC were used to confirm the formation of block copolymers. Detailed information on the living character of the RITP process was obtained. 相似文献
242.
Poly(styrene-co-glycidyl methacrylate) latex microspheres with uniform size and high-density epoxy groups on the surface were prepared by soap-free emulsion polymerization with batch wise operation mode in the presence of 2.2′- azobis(2-methylpropionamidine) dihydrochloride as an initiator.The kinetics of soap-free emulsion polymerization and the effects of polymerization factors were examined.In addition,the optimum polymerization conditions of poly(styrene-co- glycidyl methacrylate) latex microspheres ... 相似文献
243.
High-quality poly(fluorene-9-acetic acid) (PFAA), a new soluble polyfluorene derivative, was synthesized electrochemically by direct anodic oxidation of fluorene-9-acetic acid (FAA) in boron trifluoride diethyl etherate (BFEE) containing a certain amount of trifluoroacetic acid (TFA). This electrolyte enables facile anodic oxidation of FAA monomer at lower potential (1.05 V vs. SCE). PFAA films with conductivity of 0.53 S cm−1 obtained from this medium showed better redox activity and thermal stability in relation to unsoluble poly(fluorene-9-carboxylic acid). Fluorescent spectral studies indicate that PFAA film with high fluorescence quantum yields and photochemical stability is a good blue-light emitter. The structure and morphology of the polymer were studied by UV–vis, FT-IR, 1H NMR spectra and scanning electron microscopy, respectively. 相似文献
244.
Activator generated by electron transfer atom transfer radical polymerization of methyl methacrylate (MMA) in inexpensive, non-toxic poly(ethylene glycol) (PEG), with air-stable Cu(II)X2(X = Br, Cl) as the catalyst and N,N,N′,N′-tetramethylethylenediamine (TMEDA) as both ligand and reducing agent was investigated. The polymerizations in PEG proceeded in a well-controlled manner as evidenced by kinetic studies and chain extension results. The polydispersity of the polymer obtained was quite narrow, with a weight-average molecular weight/number-average molecular weight ratio of less than 1.2. Effects of the TMEDA content and the catalysts on polymerization were also investigated, respectively. 相似文献
245.
246.
247.
新型的承载双金属氰化物络合催化剂 总被引:1,自引:0,他引:1
用双金属氰化物(DMC)络合催化剂可制得相对分子质量高、相对分子质量分布窄和不饱和度低的聚醚多元醇。为提高DMC催化剂的利用率,降低催化剂和聚醚的生产成本,国外开发了承载的DMC催化剂。它不仅可简化聚醚的后处理工艺,而且使聚醚的连续化大规模生产得以实现,因此代表了DMC催化剂的一个重要发展方向。 相似文献
248.
Novel conjugated silole‐containing polyfluorenes, with green‐ and red‐emissive siloles on the backbone of the blue‐emissive polyfluorene are synthesized for white light electroluminescence (EL) from a single polymer with simultaneous red, green, and blue (RGB) emission. The CIE coordinates (0.33, 0.36) of the white light EL spectra are very close to that for pure white light (0.33, 0.33). The EL spectra are also quite stable at different applied voltages or brightness. The relative intensities for the three RGB peaks, at 450, 505, and 574 nm, were 0.94, 1, and 0.97, respectively, which demonstrates a balanced simultaneous RGB emission. A maximum luminous efficiency of 2.03 cd · A−1 for a brightness of 344 cd · m−2, and a luminous efficiency of 1.86 cd · A−1 for a more practical brightness of 2 703 cd · m−2, were achieved.
249.
Katharina Landfester Prof. Dr. 《Angewandte Chemie (International ed. in English)》2009,48(25):4488-4507
The miniemulsion process allows the formation of complex polymer nanoparticles and the encapsulation of widely varying materials into a polymer shell (see examples). Functionalization of the nanoparticles can be easily carried out, and polymerization to form polymer nanoparticles can be performed in environmentally friendly solvents, such as water.
250.
Rui Xu Dr. W. Bernd Schweizer Dr. Holger Frauenrath Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(36):9105-9116
A series of symmetrically and unsymmetrically substituted octa‐2,4,6‐triyne‐1,8‐diol derivatives with benzoyl, 4‐dodecyloxybenzoyl, as well as perfluorobenzoyl substituents were prepared and investigated with respect to their crystal structures and topochemical polymerizability. Single‐crystal structures for several of these triacetylene monomers have been obtained and proved that the perfluorophenyl–phenyl interactions played a decisive role in the molecular packing. As a consequence of the geometric requirements imposed by the perfluorophenyl–phenyl interactions, packing parameters appropriate for a topochemical triacetylene polymerization in the sense of either a 1,6‐ or a 1,4‐polyaddition along different crystallographic axes were observed in two cases, and UV irradiation led to successful polymerization. Raman as well as solid‐state 13C NMR spectra of the obtained polymers revealed that the polymerization had predominantly proceeded in the form of a 1,4‐polyaddition. 相似文献