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11.
12.
Jun Hua YU Xue Song WANG Bao Wen ZHANG* Yi CAO Technical Institute of Physics Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2002,13(10)
Porphyrin derivatives attract much more interest in photodynamic therapy (PDT). Their importance as therapeutic drugs and targeting agents has been widely recognized1, and many of the efforts have been put towards crafting new porphyrin-based molecular entities to achieve enhanced tumor localization, better tissue penetration and increased singlet oxygen quantum yield2. The states of porphyrins in tissue models such as micelles, lipid bilayers are extensively investigated focusing more or l… 相似文献
13.
T. Hayashita T. Kurosawa T. Miyata K. Tanaka M. Igawa 《Colloid and polymer science》1994,272(12):1611-1619
The cationic azo-surfactants possessing different spacers and tail alkyl chain lengths have been synthesized by azocoupling ofp-alkylaniline orop-ethoxyaniline with phenol, followed by alkylation and quaternalization with dibromoalkane and trimethylamine, respectively. These surfactants showed a good solubility in water. A reversibletrans-cis isomerization of the azosurfactants by photoirradiation was assessed by UV-Vis absorption spectra. Due to a difference in HLB between thetrans- andcis-surfactants, the observed critical micelle concentration (CMC) values and the electric conductivity of the surfactant solution at above the CMC were significantly affected by the photoinducedtrans-cis isomerization. The azo-surfactants bearing moderate alkyl chain lengths such as surfactants 6 (R2=C2H4, R3=C4H9) and 9 (R2=C4H8, R3=C2H5) were found to be effective to achieve large CMC changes (3.6 mmol/L for 6 and 5.9 mmol/L for 9) by UV-light irradiation. The replacement of the tail chain species also affected the photoresponsive function. The surfactant 12, possessingp-ethoxy group as the tail chain, was found to form a stable micelle aggregation as compared with the structurally related surfactant 10 having ethyl unit as its tail group, but it exhibited a large CMC change (5.3 mmol/L) by UV-light irradiation. 相似文献
14.
For the purpose of testing the spherical uniformity based on i.i.d. directional data (unit vectors) zi, i=1,…,n, Anderson and Stephens (Biometrika 59 (1972) 613–621) proposed testing procedures based on the statistics Smax=maxu S(u) and Smin=minu S(u), where u is a unit vector and nS(u) is the sum of squares of u′zi's. In this paper, we also consider another test statistic Srange=Smax−Smin. We provide formulas for the P-values of Smax, Smin, Srange by approximating tail probabilities of the limiting null distributions by means of the tube method, an integral-geometric approach for evaluating tail probability of the maximum of a Gaussian random field. Monte Carlo simulations for examining the accuracy of the approximation and for the power comparison of the statistics are given. 相似文献
15.
Huricha Baigude Kaname Katsuraya Kohsaku Okuyama Kenichi Hatanaka Emi Ikeda Naokazu Shibata Toshiyuki Uryu 《Journal of polymer science. Part A, Polymer chemistry》2004,42(6):1400-1414
A novel sugar‐containing poly(ornithine) dendrimer is synthesized for possible antigen delivery and related applications. The dendrimer contains an ornithine dendron as interior scaffolding and oligosaccharides on the periphery, which provide an attachment site for a peptide antigen. Maltose or lactose is bound to both hemispherical and spherical poly(ornithine) dendrimer generation 3 (G3) by reductive amination between its reducing end and the peripheral amino group of the dendrimer using a borane‐pyridine complex in a buffer solution at 50 °C. The degree of substitution of sugar is changed by varying the molar ratio of sugar to dendrimer. When the surface of spherical poly(ornithine) dendrimer G3 is modified by binding β‐alanine to the 16 amino groups, highly substituted maltose‐ or lactose‐β‐alanine‐poly(ornithine) dendrimer G3 is obtained in high yield after 7 days of reaction. The structures of these sugar‐containing dendrimers are characterized by NMR and matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry analyses. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1400–1414, 2004 相似文献
16.
V. N. Lopatin A. D. Aponasenko N. V. Shepelevich 《Journal of Applied Spectroscopy》1997,64(6):825-831
We investigate the possibilities of creating a method for estimating the optical constants, dimensions, and concentrations
of “soft” absorbing particles by applying a theoretical analysis of the angular dependence of the intergrated indicatrix,
overall characteristics of light scattering, and absorption on the phase shift and diffraction parameter of particles in the
brightening band region. We show that using the investigated optical characteristics, it is possible to determine the unknown
parameters of a suspension from experimental data.
Institute of Biophysics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russia. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 6, pp. 807–812, November–December, 1997. 相似文献
17.
离子表面活性剂胶团对阿斯匹林碱水解反应的影响 总被引:3,自引:0,他引:3
离子表面活性剂胶团对阿斯匹林碱水解反应的影响史振民*刘生昆张祝莲巩育军(延安大学化学系延安716000)关键词表面活性剂,阿斯匹林,碱水解反应,胶团,抑制作用1996-05-04收稿,1996-08-12修回阿斯匹林(ASP),学名为乙酰水杨酸,有较... 相似文献
18.
19.
The mean spherical model with an arbitrary interaction potential, the Fourier transform of which has a long-wavelength exponent , 0<2, is considered under periodic boundary conditions and fully finite geometry ind dimensions, when <d<2. A new form of the finite-size scaling equation for the spherical field in the critical region is derived, which relates the temperature shift to Madelung-type lattice constants. The method of derivation makes use of the Poisson summation formula and a Laplace transformation of the momentumspace correlation function.On leave of absence from Institute of Mechanics and Biomechanics, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria. 相似文献
20.
We developed a new method to measure the average aggregation number of large rod-like micelles using static fluorescence self-quenching of a solubilized fluorophore. The method is based on the increase of self-quenching of micelle-solubilized pyrene through excimer formation. We consider the effect of random distribution of pyrene in micelles and the micellar size distribution. The measured average aggregation <n> M is based on a new M-weighted raging similar to our exponential-weighted averaging in the transient decay method. We apply this method to study the effect of a large concentration of salt on the average aggregation behavior of sodium dodecyl sulfate (SDS) and cetyle tetraammonium bromide (CTAB). The sizes increase with increasing ionic concentrations. For SDS, we used the thermodynamic model developed by Missel et al. to calculate < n > M which we compare with experimental results. 相似文献