全文获取类型
收费全文 | 11283篇 |
免费 | 1828篇 |
国内免费 | 3548篇 |
专业分类
化学 | 6950篇 |
晶体学 | 419篇 |
力学 | 759篇 |
综合类 | 159篇 |
数学 | 4073篇 |
物理学 | 4299篇 |
出版年
2024年 | 41篇 |
2023年 | 124篇 |
2022年 | 293篇 |
2021年 | 335篇 |
2020年 | 386篇 |
2019年 | 376篇 |
2018年 | 380篇 |
2017年 | 546篇 |
2016年 | 692篇 |
2015年 | 474篇 |
2014年 | 717篇 |
2013年 | 1281篇 |
2012年 | 994篇 |
2011年 | 945篇 |
2010年 | 834篇 |
2009年 | 835篇 |
2008年 | 868篇 |
2007年 | 848篇 |
2006年 | 724篇 |
2005年 | 670篇 |
2004年 | 562篇 |
2003年 | 482篇 |
2002年 | 479篇 |
2001年 | 409篇 |
2000年 | 348篇 |
1999年 | 328篇 |
1998年 | 278篇 |
1997年 | 225篇 |
1996年 | 222篇 |
1995年 | 185篇 |
1994年 | 165篇 |
1993年 | 107篇 |
1992年 | 96篇 |
1991年 | 59篇 |
1990年 | 65篇 |
1989年 | 51篇 |
1988年 | 47篇 |
1987年 | 25篇 |
1986年 | 20篇 |
1985年 | 19篇 |
1984年 | 19篇 |
1983年 | 14篇 |
1982年 | 22篇 |
1981年 | 16篇 |
1980年 | 11篇 |
1979年 | 9篇 |
1978年 | 8篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 796 毫秒
51.
q变形对相干态的相位概率分布特性 总被引:2,自引:0,他引:2
通过推广Pegg和Barnett的相位算符和相位态到q变形的双模情况, 应用数值计算
研究了q变形对相干态的相位概率分布特性. 结果表明, q变形对相干态的相位概率分布受到相位参数、q参数和参数│ξ│的调节, 从而反映出不同的量子相干特性. 相似文献
52.
R. Jayakumar Y.‐S. Lee S. Nanjundan 《Journal of polymer science. Part A, Polymer chemistry》2003,41(18):2865-2878
The calcium salt of mono(hydroxyethoxyethyl)phthalate [Ca(HEEP)2] was synthesized by the reaction of diethylene glycol, phthalic anhydride, and calcium acetate. Calcium‐containing poly(urethane ether)s (PUEs) were synthesized by the reaction of hexamethylene diisocyanate (HMDI) or tolylene 2,4‐diisocyanate (TDI) with a mixture of Ca(HEEP)2 and poly(ethylene glycol) (PEG300 or PEG400) with di‐n‐butyltin dilaurate as a catalyst. A series of calcium‐containing PUEs of different compositions were synthesized with Ca(HEEP)2/PEG300 (or PEG400)/diisocyanate (HMDI or TDI) molar ratios of 2:2:4, 3:1:4, and 1:3:4 so that the coating properties of the PUEs could be studied. Blank PUEs without calcium‐containing ionic diols were also prepared by the reaction of PEG300 or PEG400 with HMDI or TDI. The PUEs were well characterized by Fourier transform infrared, 1H and 13C NMR, solid‐state cross‐polarity/magic‐angle‐spinning 13C NMR, viscosity, solubility, and X‐ray diffraction studies. The thermal properties of the polymers were also studied with thermogravimetric analysis and differential scanning calorimetry. The PUEs were applied as top coats on acrylic‐coated leather, and their physicomechanical properties were also studied. The coating properties of PUEs, such as the tensile strength, elongation at break, tear strength, water vapor permeability, flexing endurance, cold crack resistance, abrasion resistance, color fastness, and adhesive strength, were better than the standard values. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2865–2878, 2003 相似文献
53.
功能性丙烯酸/MBAM体系共聚产物的研制 总被引:2,自引:0,他引:2
以丙烯酸和MBAM为主要原料,经聚合,合成了一种高性能的具有良好保水性能的聚合产物,其保水量达到750~1000倍.50℃以下有良好的保水性能,28℃以下有极好的保水性能,并研究了工艺条件对该产品性能的影响因素. 相似文献
54.
Monodisperse polyaniline nanoparticles (PAPSSA) were synthesized from an oxidative dispersion polymerization using poly(sodium 4-styrenesulfonate) (PSSA) as both a polymeric stabilizer and a dopant agent due to its acidity. The nanoparticles were being stabilized with two different molecular weight of PSSA. Size effect of PAPSSA particles were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and dynamic light scattering (DLS). The d.c. electrical conductivity of composite films on the glass substrate was measured by a four-probe method. It was found that the electrical properties of the composite films are affected by the content of nano-sized polyaniline and different molecular weights of stabilizer in the poly(vinyl alcohol) (PVA) matrix. 相似文献
55.
We propose a new approach towards proving that the fixed point property for ordered sets is preserved by products. This approach uses a characterization of fixed points in products via isotone relations. First explorations of classes of isotone relations are presented. These first explorations give us hope that this approach could lead to advances on the Product Problem. 相似文献
56.
C. Vaca‐Garcia G. Gozzelino W. G. Glasser M. E. Borredon 《Journal of Polymer Science.Polymer Physics》2003,41(3):281-288
The main transitions of cellulose fatty esters with different degrees of substitution (DSs) were investigated with dynamic mechanical thermal analysis. Two distinct main relaxations were observed in partially substituted cellulose esters (PSCEs). They were attributed to the glass‐transition temperature and to the chain local motion of the aliphatic substituents. The temperatures of both transitions decreased when DS or the number of carbon atoms (n) of the acyl substituent increased. Conversely, all the transitions of fully substituted cellulose esters occurred within a narrow temperature range, and they did not vary significantly with n. This phenomenon was explained by the formation of a crystalline phase of the fatty substituents. The presence of few residual OH groups in PSCEs was responsible for a large increase in the storage bending modulus, and it eliminated the effect of n on damping. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 281–288, 2003 相似文献
57.
Letters in Mathematical Physics - 相似文献
58.
59.
选用新方法合成了2-碘—N-甲基苯磺酰胺,通过^1H NMR,^13C NMR,^13C DEPT NMR(Distortionless Enhancement by Polarization Transfer NMR)和MS确证的其结构。 相似文献
60.
M. I. Gil' 《Proceedings of the American Mathematical Society》2003,131(12):3737-3746
A linear operator in a separable Hilbert space is called a quasinormal one if it is a sum of a normal operator and a compact one. In the paper, bounds for the spectrum of quasinormal operators are established. In addition, the lower estimate for the spectral radius is derived. Under some restrictions, that estimate improves the well-known results. Applications to integral operators and matrices are discussed. Our results are new even in the finite-dimensional case.