颗粒有序堆积多孔介质对流换热实验研究

本文采用"瞬态单吹反问题研究方法"对颗粒有序堆积多孔介质内的强制对流换热进行了实验研究。详细研究了颗粒堆积方式变化对多孔介质内对流换热的影响,并对均匀与非均匀颗粒堆积多孔介质内的对流换热特性进行了对比分析。研究表明:通过对颗粒进行合理有序堆积,可以使相应多孔介质内的压降显著降低,其综合换热效率明显提高;通过拟合获得了颗粒有序堆积多孔介质内的宏观流动换热实验关联式,其形式与传统经验公式(Ergun公式和Wakao公式)一致,但部分模型参数值远低于传统经验公式。     

直接供液与重力供液制冷系统的对比研究

重力再循环供液是指蒸发器依靠制冷剂自身的重力送入蒸发器,在供液高度大于蒸发器对制冷剂的阻力情况下,部分制冷剂液体在蒸发器和气液分离器所形成的回路中再循环。由于再循环作用不需要外加动力,并强化管内制冷剂的沸腾换热,蒸发器的效率得以明显提高。文中介绍了重力再循环供液制冷系统和蒸发器的结构,提出采用J.Chawla关系式和Shah关联式相结合的方法预测再循环蒸发器制冷剂侧的换热系数。采用空气侧热平衡法,对直接膨胀供液和重力再循环供液制冷系统分别进行了多蒸发温度下的性能测试。表明重力再循环供液制冷系统比直接膨胀供液制冷系统的制冷量平均增加26%,COP平均增加18%,蒸发温度平均升高1.1℃,传热系数是直接供液的1.57倍。J.Chawla关系式和Shah关联式相结合预测再循环蒸发器制冷剂侧的换热系数,其曲线结构与实验值近似,平均误差不大于20.6%。文章还对各热工参数的变化原因进行了分析。     

土壤源热泵系统冷凝热回收的优化研究

文中提出了一种土壤源热泵冷凝热回收系统,能够减少冬夏两季土壤源热泵系统从土壤冷热源排放吸收热量不均对土壤温度场所造成的影响,并结合火用平衡方程建立了土壤源热泵系统冷凝热回收的优化模型。基于此模型,探讨了系统冷凝器和地下埋管的优化配置,通过模拟计算对该系统在制冷工况下改进前后的运行情况进行了分析对比,结果显示土壤源冷凝热回收系统应用于实际工程能够提高整个系统的COP以及火用效率。     

热声热机声场的格子气分析

从格子气自动机演化方程恢复了宏观热声方程,采用D2Q9热格子气模型模拟热声热机系统的压力场、温度场和速度场,获得压力驻波的传播和反射过程。模拟结果显示,在所给模拟条件下压力波具有非线性的特征,变截面附近的流场区域会产生引起非线性耗散的涡流。本文也分析了谐振管几何尺寸及格子气粒子密度对系统频率和压力的影响,验证了热声热机格子气模型的有效性。     

Boson peak in Sm-Al-Co ternary metallic glasses and its possible structural origin

The low temperature specific heat of Sm-Al-Co ternary metallic glasses is investigated and a clear anomaly associated with the Boson peak is identified. While this anomaly depends slightly on the chemical composition, it has no dependence on external magnetic field. To figure out the mechanism of the Boson peak, we interpret the data within various model frameworks. Unlike earlier work, our study shows that this Boson peak is mainly ascribed to an additional T² term of the specific heat, which may originate from the quasi-two-dimensional and short-range ordered structure units possibly existing in the metallic glasses.     

双壳程连续螺旋折流板换热器的数值模拟

本文提出了一种新型的双壳程连续螺旋折流板换热器。采用数值模拟方法对双壳程、单壳程连续螺折流板换热器,以及弓形折流板换热器壳侧流动与传热持性进行了对比研究。结果表明,同质量流量和对流换热系数近似相等的情况下,双壳程连续螺旋折流板换热器壳程压降比弓形折流板换热器低17.7%～23.5%,同质量流量和壳程压降近似相等的情况下,其对流换热系数比单壳程连续螺旋折流板换热器高7.1%～12.6%。     

基于Goose LDW-PSO的管壳式换热器优化设计

管壳式换热器在工业中的应用越来越广泛,对于设计者和使用者来说使其费用最小化是一个很重要的目标。本文以最小化管壳式换热器的总费用为优化目标,提出了运用基于雁群启示的惯性权重线性下降粒子群优化算法(Goose LDW-PSO)对其进行优化设计。为了验证这种方法的有效性,用Goose LDW-PSO对管壳式换热器进行了优化设计,并与原始设计结果进行了比较。比较结果表明,虽然管子数目增加,但是换热器的总费用比传统方法少了很多。     

Near-field radiative heat transfer between two plane surfaces with one having a dielectric coating

The effect of a dielectric coating on the near-field radiative heat transfer between two plane surfaces is numerically studied in the framework of the fluctuational electrodynamics. The dielectric coating is assumed to be a SiC or SiO₂ film, which is on top of the emitter. The results show that the near-field radiative flux between the plane surfaces can be either diminished or enhanced by the dielectric coating, depending on the thermal radiative properties of the emitter and the receiver. Furthermore, the dielectric coating effect on the near-field radiative flux can be very different from that on the far-field radiative flux. Detailed analysis on the variations of the TE- and TM-wave components of the radiative flux by adding the dielectric coating is provided, along with the physical mechanisms that account for these changes. Dielectric coatings such as SiC and SiO₂ films are widely seen in microelectronic structures and nanofabrication devices. The results obtained in this work should be valuable for further study and nanotechnological applications of near-field radiative heat transfer.     

The role of Pb ions doping in the mechanism of chromate adsorption by goethite

Pure and 0.384% Pb²⁺ ions doped goethite samples were prepared in the laboratory by the coprecipitation method. The laboratory-prepared goethite samples were characterized for pH of point of zero charge (pH_pzc), surface area, XRD, TG-DTA, TEM, SEM and FTIR analysis, which suggest that the Pb²⁺ ions are incorporated into the crystals of goethite and are also present on the surface in the hydroxylated form. Chromate adsorption studies were carried out in the concentration range 0.25-2.01 mmol L⁻¹ at pH 3, 5 and 7, which show that maximum chromate is adsorbed at the lowest pH of 3 by both the samples of goethite. Effect of temperature on the adsorption of chromate, in the range 303-323 K, shows that the process of adsorption is endothermic in case of pure goethite and exothermic in case of Pb-doped goethite. The values of isosteric heat of adsorption were positive for pure goethite and negative for Pb-doped goethite, which are consistent with the effect of temperature on the process of adsorption. Langmuir isotherm was found applicable to the experimental data. FTIR analysis and equilibrium pH changes reveal that at pH 3 outersphere while at pH 5 and 7 innersphere complexation is the dominant mechanism for chromate adsorption by both the samples of goethite.     

Crystal electric field excitations in ferromagnetic CeTX compounds

A ferromagnetic ground state was identified for the compounds CeCuGe (T_C=10 K), CeCuSi (T_C=15 K) [F. Yang, et al., J. Appl. Phys. 69 (1991) 4705] and CeAuGe (T_C=10 K) [R. Pottgen, J. Magn. Magn. Mater. 152 (1996) 196]. The observed saturation magnetic moment values at low temperatures for all three compounds are considerably less than the theoretically expected value g_JJ=2.14μ_B for the free Ce³⁺ ion involving the entire six-fold J=5/2 multiplet, and thus provide a first indication of partial lifting of the f-electron level degeneracy in these compounds. Specific heat data yield crystal electric field (CEF) excitation energies (Δ_Sch) equivalent to 140 K for CeCuGe, 110 K for CeCuSi and 280 K for CeAuGe. To confirm the presence of CEF excitations directly, we have carried out inelastic neutron scattering (INS) measurements on all three compounds, using the HET spectrometer at ISIS Facility. Here, we present a detailed analysis of the INS spectra of CeCuSi on the basis of a CEF model and the detailed analysis of the INS of the other two compounds will be reported elsewhere.