A novel polyfunctional chiral building block derived from (S)-ethyl lactate. Application to the synthesis of the sex pheromone of the southern corn rootworm (Diabrotica undecimpunctata howardi)

Highly enantiomerically pure (4S, 5E)-4-bromomethylhept-5-enenitrile was prepared from (S)-ethyl lactate by a six-step procedure involving a rearrangement of chiral cyclopropylcarbinol. This product was used for the synthesis of the sex pheromone of the southern corn rootworm (Diabrotica undecimpunctata howardi), (10R)-10-methyltridecan-2-one. For preliminary communication, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 151–155, January, 2000.     

GC–MS法分析茵陈挥发油成分

采用水蒸气蒸馏法提取茵陈中挥发性成分挥发油,用气相色谱–质谱联用技术(GC–MS)对茵陈挥发油成分进行分析鉴定,并采用峰面积归一化法测定其相对含量。共检出52种挥发性成分,鉴定了其中31种主要挥发性成分,含量较高的组分为石竹素(15.27%)、(–)-斯巴醇(6.64%)、石竹烯(4.89%)等。GC–MS法适用于茵陈挥发性成分的定性分析,具有灵敏度高、分析速度快的特点。     

Asymptotic solving method for a sea-air oscillator model of atmospheric physics

In this paper, a class of coupled system for the El Nin o/La Nin a southern oscillation (ENSO) atmospheric physics oscillation model is considered. We propose an ENSO atmospheric physics model using a method from the asymptotic theory. It is indicated from the results that the asymptotic method can be used for analyzing the sea surface temperature anomaly and the thermocline depth anomaly of the atmosphere-ocean oscillation for the ENSO model in the equatorial Pacific.     

一类具时滞的厄尔尼诺-南方涛动充电-放电振子模型的Hopf分岔与周期解问题

研究了一类具时滞的厄尔尼诺-南方涛动充电-放电振子模型. 给出了产生Hopf分岔的临界时滞条件, 利用Mawhin重合度理论,探讨了该模型的周期解问题.关键词：时滞厄尔尼诺-南方涛动模型Hopf分岔周期解     

OPTIMAL AUSTRALIAN AND JAPANESE HARVESTING OF SOUTHERN BLUEFIN TUNA

A 19-cohort bioeconomic model is developed for the southern bluefin tuna fishery. The fish are long-lived and highly migratory. They are harvested as juveniles by Australia and Japan in Australian waters, and as adults by Japan on the high seas. The potential for conflict between Australian and Japanese fleets therefore exists in the exploitation of the fishery. The model is used to compare Japanese and Australian social rents and harvest levels through time under joint maximization, and under duopoly.     

A novel polyfunctional chiral building block derived from (S)-ethyl lactate. Application to the synthesis of the sex pheromone of the southern corn rootworm (Diabrotica undecimpunctata howardi)

Highly enantiomerically pure (4S, 5E)-4-bromomethylhept-5-enenitrile was prepared from (S)-ethyl lactate by a six-step procedure involving a rearrangement of chiral cyclopropylcarbinol. This product was used for the synthesis of the sex pheromone of the southern corn rootworm (Diabrotica undecimpunctata howardi), (10R)-10-methyltridecan-2-one. For preliminary communication, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 151–155, January, 2000.     

高锰酸钾引发丙烯腈与木质纤维素接枝共聚的研究

研究了用高锰酸钾引发羟丙基马尾松磨石磨木浆粕与丙烯腈的接技共聚反应。得出,木质素对接技反应的影响可能主要来源于它的酚型结构单元。用羟丙基醚化木质素的酚羟基后接枝反应可顺利进行。X-射线衍射结果显示,接技共聚反应有可能渗透到纤维素晶区内部,随接技量的提高,反应具有一定的消晶作用。     

Southern galactic plane CO survey

Preliminary results are presented for a survey of J=1–0¹²CO emission being carried out at 3 arc intervals along the southern galactic plane in the range 294°358°, –0°.075b0°.075. The longitude-velocity distribution shows well-defined terminal velocities, and is similar to the distribution at corresponding longitudes north of the galactic centre. However, the radial distribution of CO suggests that the southern CO, while concentrated inside the solar circle as in the north, is on the average located about 500 pc further from the galactic centre. Limited estimates of cloud sizes and masses suggest ranges greater than those deduced in previous surveys.On leave from University of British Columbia Vancouver, B.C.     

1960―2017年秦岭南北地区降雨侵蚀力的时空变化特征研究

基于秦岭南北地区1960―2017年47个气象站点逐日降雨资料,根据章文波提出的日降雨侵蚀力模型估算降雨侵蚀力,并采用气候倾向率、反距离权重插值及Mann-Mendal突变检验等方法分析秦岭南北地区近58 a年均降雨侵蚀力与不同量级降雨侵蚀力的时空变化特征。 结果表明：（1） 1960―2017年秦岭南北地区年均降雨侵蚀力与不同雨量产生的降雨侵蚀力均呈由南向北递减的特征。（2）近58 a,秦岭南北地区年均降雨侵蚀力、大雨与暴雨侵蚀力年际变化呈增长趋势,未通过突变检测;中雨侵蚀力呈减弱趋势,在1972年发生突变且在2007年后达到显著;其中秦岭以北年均降雨侵蚀力、中雨侵蚀力、暴雨侵蚀力均呈下降趋势,且年际波动程度较大,秦岭以南年均降雨侵蚀力及大雨、暴雨侵蚀力均呈上升趋势。（3）秦岭南北地区年均降雨侵蚀力变化趋势空间差异显著,明显增长区集中于汉中盆地与巴巫谷地,减少区集中于西部嘉陵江、秦岭以北汾河入黄河交界、汉水流域两湖平原;且不同量级侵蚀力呈增长趋势的面积大小依次为大雨侵蚀力>暴雨侵蚀力>中雨侵蚀力。