The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches

Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom.     

氯代5-氟脲嘧啶卟啉的红外光谱特性的研究

本文对新合成的对位及间位两类氯代苯基 5 氟脲嘧啶卟啉的红外光谱吸收峰进行了归属和总结 ,讨论了其红外吸收频率随取代基位置变化的规律。指出了苯环上的取代基为电负性强的基团时 ,由于场效应的存在 ,使被测化合物的羰基伸缩振动吸收峰的相对强度发生改变。同时 ,表明了嘧啶环上N原子发生了取代 ,形成单、双取代 5 氟脲嘧啶卟啉化合物的红外光谱特性。     

Micellar effect in hydroformylation of high olefin catalysed by water-soluble rhodium complexes associated with sulfonated diphosphines

High linear alkenes (1-octene and 1-decene) have been hydroformylated using water-soluble rhodium complexes associated with sulfonated diphosphines in the presence of ionic surfactants or methanol. In all cases, the hydroformylation activities were higher than in experiments without additives. The selectivity in aldehydes was higher when we used cetyltrimethylammonium hydrogensulfate (CTAHSO₄) as the surfactant or methanol as the co-solvent.     

Lattice Boltzmann方法模拟多孔介质Klinkenberg效应

格子Boltzmann数值模拟方法是研究复杂的多孔介质结构特别是Klinkenberg效应的有效方法之一，对处理复杂边值问题尤其有效，用格子Boltzmann方法研究了气流穿越多孔介质问题，并将数值计算结果与实验结果进行了比较，结果表明格子Boltzmann方法是数值模拟气流穿越多孔介质问题的有效方法之一。     

激光介质的多次吸收不均匀内热源模型

针对激光介质的内热源,以多次吸收作用为基础提出了适用于侧面双向泵浦板状激光介质的不均匀内热源模型,即多次吸收不均匀内热源模型,并与均匀内热源和一次吸收内热源模型进行了对比分析。研究表明,介质厚度及光吸收系数组成的无量纲参数不同时,三种内热源模型得到的内热源分布也有所不同。最后给出了内热源不均匀度及多次吸收模型与一次吸收模型之间的差异在不同目标值下的内热源模型适用准则。     

多气隙电阻板室抗辐照性能研究

给出了为RHIC-STAR飞行时间探测器设计的多气隙电阻板室(MRPC)的辐照实验结果. 实验采用100mCi⁶⁰Co γ源, 采用不同的剂量率对MRPC进行辐照. 一个室在大剂量率2.87×10^－2Gy/h下辐照了24h后, 其性能如噪声计数率, 暗电流等均大大退化. 另一个室在相对低剂量率5.31×10^－4Gy/h下辐照了530h, 其性能没有见到任何变坏. 实验的目的是为了了解这种探测器在几年的运行中经过大剂量的辐照后的性能变化情况.     

Scientific legacy of Stanley Ruby

Stanley L. Ruby (1924–2004) made major contributions to Mössbauer spectroscopy and was the first to suggest the feasibility of observing the Mössbauer effect using synchrotron radiation. In this article we recall his scientific legacy that have inspired his scientific colleagues.     

The driving torque of a rotating levitated cylindrical permanent magnet above a superconductor

Due to the Meissner effect, a permanent magnet is levitated, when released above a high temperature superconductor. When there is an inhomogeneous temperature field around the magnet, the magnet might start to oscillate with increasing amplitude until it remains in a continuous rotation. A mathematical model for the described effect is presented which couples heat transfer and electromagnetic forces with the equation of motion, yielding to a multiphysics task. In a detailed analysis it is found, that the torque which drives the rotation of the magnet, is explicitly given in terms of Bessel functions and the Fourier coefficients of order zero and one of the temperature field of the surrounding air.     

高功率双包层光纤激光器受激拉曼散射和热效应的理论研究

 受激拉曼散射和热效应会限制光纤激光器功率的提高。利用高功率光纤激光器的速率方程和热传导方程，理论研究了双端泵浦和分布泵浦下双包层光纤激光器的受激拉曼散射和热效应，得到了光纤中的泵浦光、激光和斯托克斯光的功率分布，光纤激光器的输出特性以及光纤中的温度分布。分析表明，当泵浦功率增大到一定值时，光纤激光器中出现SRS，一部分激光功率会转移给斯托克斯光，影响激光功率进一步提高;与双端泵浦方式相比，分布泵浦下光纤激光器的斜率效率和最大输出功率相差不大，但是，光纤中的温度分布被有效地降低，因此，分布泵浦方式更为有效。     

Ⅰ类超晶格势阱中能级分布及电子跃迁规律研究

在研究大量实验曲线的基础上,指出势阱所有能级均有一定的宽度,电子或空穴在各能级中出现的概率符合正态分布,从理论上分析了I类超晶格和双势垒单势阱的发光光谱与吸收光谱·解释了GaAs/Ga1-xAlxAs多量子阱和超晶格吸收光谱吸收边及量子阱变窄时各吸收峰的“蓝移现象”及GaAs/Ga1-xAlxAs双势垒单量子阱样品的电流—电压特性曲线及电导—电压特性曲线的特征和出现的“负阻效应”·