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61.
采用四种杯芳烃超分子化合物为吸附涂层物质, 探讨了涂膜石英晶体微天平(QCM)传感方法对环境大气中微量甲醇气体的识别研究, 发现RCT(Resorcinol cyclic tetramer)是对甲醇气体识别最有效的活性涂层材料. 通过RCT-MeOH单晶体的制备并对其进行X-ray衍射结构解析, 发现其识别机制是基于甲醇分子中的甲基与杯芳烃化合物的苯环之间形成了C-H…π键作用. 当RCT涂层质量为28.16 μg时, 涂膜QCM传感器对甲醇的响应最灵敏, 达到0.01245 Hz/ppm. 该传感器对甲醇气体吸附和解吸附的初速度分别为-0.2110 Hz/s和0.09497 Hz/s. 该方法具有响应快、重现性和稳定性好的优点, 对甲醇测定的回收率在97.83%~103.66%之间, 与气相色谱法测定结果一致, 表明该方法可应用于环境大气中甲醇气体含量的检测. 相似文献
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本文用作者在文[1]引进的S 稳定的概念,给出了下面三个三阶非线性系统x~■+ax″+bx′+integral(t,x)=0;x~■+ax″+integral(t,x′)+cx=0;x~■+integral(t,x″)+bx′+cx=0存在唯一稳定周期解的充分条件,推广和改进了文[2—3]的工作. 相似文献
66.
Analysis of the generation mechanism of the S-shaped J—V curves of MoS2/Si-based solar cells
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Amorphous-microcrystalline MoS$_{2}$ thin films are fabricated using the sol-gel method to produce MoS$_{2}$/Si-based solar cells. The generation mechanisms of the S-shaped current density-voltage ($J$-$V$) curves of the solar cells are analyzed. To improve the performance of the solar cells and address the problem of the S-shaped $J$-$V$ curve, a MoS$_{2}$ film and a p$^+$ layer are introduced into the front and back interfaces of the solar cell, respectively, which leads to the formation of a p-n junction between the p-Si and the MoS$_{2}$ film as well as ohmic contacts between the MoS$_{2}$ film and the ITO, improving the S-shaped $J$-$V$ curve. As a result of the high doping characteristics and the high work function of the p$^+$ layer, a high-low junction is formed between the p$^+$ and p layers along with ohmic contacts between the p$^+$ layer and the Ag electrode. Consequently, the S-shaped $J$-$V$ curve is eliminated, and a significantly higher current density is achieved at a high voltage. The device exhibits ideal p-n junction rectification characteristics and achieves a high power-conversion efficiency (CE) of 7.55%. The findings of this study may improve the application of MoS$_{2}$ thin films in silicon-based solar cells, which are expected to be widely used in various silicon-based electronic and optical devices. 相似文献
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《Physics and Chemistry of Liquids》2012,50(1-2):95-102
Abstract The equations of state (EOS) of four and five dimensional hyperspheres have been calculated using Leutheusser's ansatz. In five dimensions these, and the correlation functions, are compared with the results obtained from the analytic solution of the Percus—Yevick (PY) approximation. It is shown that the ansatz reproduces extremely well the PY results. However, in both approximations neither the virial, Zv , nor the compressibility, Zc , EOS reproduce well the available molecular dynamics (MD) results. Yet a linear combination of Zv and Zc , following the Carnahan—Starling EOS for hard spheres, are in excellent agreement with the MD results in four and five dimensions. 相似文献
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Silica-based hybrid organic-inorganic materials prepared by sol-gel chemistry exhibit chemical and physical properties revealing their anisotropic organization. Besides the opportunities that these phenomena open for the preparation of new materials, they also provide arguments for the chemist looking for better comprehension and control of the solid's organization. 相似文献
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A new way to Prepare ts-2 with Silica sol as Silicon Source 总被引:3,自引:0,他引:3
The addition of suitable amounts of aqueous ammonia into precursor gel with silica sol as silicon source, TS-2 with small particle size and high titanium content has been successfully synthesized. It displays the same excellent performance in hydroxylation of phenol as the sample prepared with TEOS as silicon source. 相似文献