STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE

A series of new water-soluble bifunctional comonomers having both carboxyl and alkylpolyoxyethylene groups, such as sodium mono(ethyl polyoxyethylene) maleate (ZE series) with variousmolecular weights of polyoxyethylene ethyl ether, were synthesized and characterized. The effects of thestructural factor, the amount and feeding mode of the comonomers, the initiator concentration andpolymerization temperature on the stability of emulsifier-free emulsion copolymerization of methylmethacrylate (MMA) and butyl acrylate (BA) in the presence of a small amount of ZE with potassiumpersulfate as initiator were investigated. Stable, almost monodispersed MMA/BA/ZE emulsifier-free latexparticles were prepared.     

超细颗粒卤化银的制备与稳定性

卤化银微晶体是一种典型的与成像材料相关的无机微粒子。一个多世纪以来,它所特有的光敏性能使之在成像科学领域中一直占据着重要的地位。近二十年来,纳米粒子化学和物理的迅速发展对于推动成像科学技术前进产生了不可低估的影响。纳米级超细颗粒卤化银的制备与性能研究十分活跃,它不仅对于深入认识卤化银成像机理具有重要意义,而且在形成新的特殊照相材料如超高解像力照相材料等方面起着关键性作用。超细颗粒卤化银的制备方法基本上可概括为两种,即直接反应法与间接反应法。前者是在某种保护性介质中同时注入银盐与卤盐,使之直接反应…     

环氧氯丙烷法制备超细β-FeOOH粒子

FeCl₃水溶液和环氧氯丙烷作用,可生成β-FeOOH溶胶,粒子外形呈纺锤状,粒径分布均匀。溶胶经表面处理,可制得油溶性β-FeOOH超细粒子。采用多步反应法,还可控制粒子的大小,并保持粒子外形的各向异性不变。     

折板及多面板非线性弯曲分析的样条核质点法

提出了一种研究折板及多面板类结构非线性弯曲行为的样条核质点法.方法包括以下步骤:(1)将折板及多面板结构模拟成不同平面上平板的集合体;(2)基于冯.卡门的大挠度理论,使用一阶剪切变形理论和样条核质点法先分析各平板的几何非线性行为;(3)将经过修正的各板的非线性刚度矩阵叠加得到整个折板结构的非线性刚度矩阵;(4)研究整个结构的几何非线性行为.由于摆脱了网格的束缚,本文方法可以避免网格扭曲引起的网格重构问题.文末通过几个算例将本文方法解与使用壳单元的ANSYS有限元解或已有文献解进行对比,验证了本文方法的收敛性和准确性.     

测度值分枝过程与移民过程

本文介绍了测度值分枝过程和由斜卷积半群定义的伴随移民过程的基本理论和研究现状,主要内容包括：分枝粒子系统的收敛;超过程的基本正则性和极限定理;非线性微分方程;广义分枝模型;斜卷积半群和进入律;用Ｋｕｚｎｅｔｓｏｖ过程构造移民过程等。     

射流撞击粉碎法制备超细炸药颗粒原理分析

分析了射流撞击粉碎法制备超细炸药颗粒的原理。得出在射流撞击过程中,颗粒之间冲击压力是引起颗粒粉碎的主要原因,冲击波的作用加强了颗粒的粉碎。利用此方法制备出了亚微米级超细ＨＭＸ和ＲＤＸ高能炸药颗粒。     

Research on the algorithm of binary image cross-correlation for unsteady flow field measurement

In the present paper, the algorithm of Binary Image Cross-Correlation (BICC) was developed to measure the unsteady flow field. A vortex flow field was used to test the algorithm by numerical simulation. The results show that BICC is an effective algorithm for particle identification from consecutive images, the accurate velocity vector field can be obtained. The real velocity field in a valve chamber was measured by BICC in this study. From the full-field velocity information, the pressure and vorticity fields were also extracted by post-processing. The project supported by the National Natural Science Foundation of China     

毛细管电泳法测定市售饮料中糖类物质的研究

毛细管电泳－电化学检测技术（ＣＥ－ＥＣ）,对具有电化学活性的物质的分离检测具有极大的优越性。本文采用ＣＥ－ＥＣ技术,以铜电极为工作电极,在０．１０ｍｏｌ／Ｌ ＮａＯＨ溶液中对１０种市售饮料中的糖类物质的分离检测进行了研究。讨论了ｐＨ值,电泳操作液,分离电压,电极,工作电位等对分离检测的影响,并对１０种饮料中的糖类物质的热量进行了计算。     

Particle Deposition in Porous Media: Analysis of Hydrodynamic and Weak Inertial Effects

We have studied the transport and capture of non-Brownian particles in porous media, when the particles are mainly submitted to hydrodynamic and weak inertial effects. Visualization experiments have been performed using several models of porous media which consist of transparent etched networks of interconnected channels. Typical particle deposits have been observed at the corners of the grains of the porous medium. Their shape and their orientation were dependent on flow rate and on the anisotropy of the flow field. A trajectory analysis model has been applied to a porous medium made of a doubly periodic array of rectangular grains very close to the experimental model. This numerical model has been used to localize particle deposits and to determine particle capture efficiency on the grains over a range of low Stokes numbers, grain aspect ratios and flow-field anisotropy ratios. The results have been interpreted in terms of shape of particle deposits and compared successfully to experimental observations.     

Research on the particle dispersion in the particulate two-phase round jet

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