全文获取类型
收费全文 | 4565篇 |
免费 | 232篇 |
国内免费 | 856篇 |
专业分类
化学 | 5097篇 |
晶体学 | 68篇 |
力学 | 22篇 |
综合类 | 50篇 |
数学 | 6篇 |
物理学 | 410篇 |
出版年
2024年 | 7篇 |
2023年 | 47篇 |
2022年 | 90篇 |
2021年 | 101篇 |
2020年 | 129篇 |
2019年 | 119篇 |
2018年 | 109篇 |
2017年 | 151篇 |
2016年 | 160篇 |
2015年 | 143篇 |
2014年 | 170篇 |
2013年 | 435篇 |
2012年 | 220篇 |
2011年 | 198篇 |
2010年 | 168篇 |
2009年 | 187篇 |
2008年 | 222篇 |
2007年 | 221篇 |
2006年 | 216篇 |
2005年 | 231篇 |
2004年 | 217篇 |
2003年 | 186篇 |
2002年 | 688篇 |
2001年 | 158篇 |
2000年 | 114篇 |
1999年 | 141篇 |
1998年 | 104篇 |
1997年 | 101篇 |
1996年 | 87篇 |
1995年 | 84篇 |
1994年 | 74篇 |
1993年 | 50篇 |
1992年 | 63篇 |
1991年 | 30篇 |
1990年 | 26篇 |
1989年 | 33篇 |
1988年 | 29篇 |
1987年 | 15篇 |
1986年 | 18篇 |
1985年 | 21篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 15篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1975年 | 4篇 |
1973年 | 6篇 |
排序方式: 共有5653条查询结果,搜索用时 15 毫秒
941.
942.
Xin Dong Juan Yang Xiao-Ting Zheng Yan Chen Li-Hong Ye Bin Wang Hui Zheng Jun Cao Qiu-Yan Wang Yu-Han Hu 《Electrophoresis》2020,41(1-2):123-130
A novel micro matrix solid phase dispersion method was successfully used for the extraction of quaternary alkaloids in Phellodendri chinensis cortex. The elution of target compounds was accomplished with sodium hexanesulfonate as the eluent solvent. A neutral ion pair was formed between ion-pairing reagent and positively charged alkaloids in this process, which was beneficial for selectively extraction of polar alkaloids. Several parameters were optimized and the optimal conditions were listed as follows: silica gel as the sorbent, silica to sample mass ratio of 1:1, the grinding time of 1 min. The exhaustive elution of targets was achieved by 200 µL methanol/water (9:1) containing 150 mM sodium hexane sulfonate at pH 4.5. The method validation covered linearity, recovery, precision of intraday and interday, limits of detection, limits of quantitation, and repeatability. This established method was rapid, simple, environmentally friendly, and highly sensitive. 相似文献
943.
建立了电感耦合等离子体质谱仪(ICP-MS)测定口含烟中钠的方法,并对影响测定结果的主要因素进行了优化. 结果表明,方法检出限和定量限分别为0. 553 4 和1. 845 μg / Kg,平均回收率为92. 00% ~ 97. 63%,RSD 低于5. 535% (n = 6). 应用方法对不同品牌的口含烟样品进行了检测,结果显示,不同品牌口含烟中钠含量水平差异明显. 相似文献
944.
György Schultz Tamás Nagy Gustavo Portalone Fabio Ramondo István Hargittai Aldo Domenicano 《Structural chemistry》1993,4(3):183-190
The molecular structure and benzene ring distortions of ethynylbenzene have been investigated by gas-phase electron diffraction and ab initio MO calculations at the HF/6-31G* and 6-3G** levels. Least-squares refinement of a model withC
2v, symmetry, with constraints from the MO calculations, yielded the following important bond distances and angles:r
g(C
i
-C
o
)=1.407±0.003 Å,r
g(C
o
-C
m
)=1.397±0.003 Å,r
g(C
m
-C
p
)=1.400±0.003 Å,r
g(Cr
i
-CCH)=1.436 ±0.004 Å,r
g(C=C)=1.205±0.005 Å, C
o
-C
i
-C
o
=119.8±0.4°. The deformation of the benzene ring of ethynylbenzene given by the MO calculations, including o-Ci-Co=119.4°, is insensitive to the basis set used and agrees with that obtained by low-temperature X-ray crystallography for the phenylethynyl fragment, C6H5-CC-, in two different crystal environments. The partial substitution structure of ethynylbenzene from microwave spectroscopy is shown to be inaccurate in the ipso region of the benzene ring. 相似文献
945.
946.
947.
This study describes an ultrathin-layer sodium dodecyl sulfate (SDS) disc electrophoresis in polyacrylamide gels of a thickness of only 150 microm. By use of 2-amino-2-methyl-1,3-propanediol/glycine instead of traditional Tris/HCl buffer in the resolving phase of the gel, proteins with a wide range of molecular sizes (10 kDa to over 220 kDa) are separated in unusually low-concentrated gels (4%T, 3.3%C). 2-Amino-2-methyl-1,3-propanediol in the resolving part of the gel contributes to stabilization of the pH value at 8.8, while glycine improves destacking as well as separation of small proteins from the bulk of stacked SDS. This method combines both the advantages of conventional slab-gel electrophoresis and capillary gel electrophoresis. It is easy to apply and well suited for all further miniaturization attempts. 相似文献
948.
The adsorption properties of the new carbon materials, sibunites, which are mesoporous samples with a developed surface of pores, were studied. The isotherms of the adsorption of benzene vapor were determined to estimate the porous structure of these materials. The principal methods for calculating the parameters of the porous structure of sibunites were analyzed. The application of the BET equation even in the presence of a small number of micropores can distort the results, therefore the most suitable method for estimating the surface of mesopores is one that is based on the Dubinin—Zaverina equation. The estimation of the surface of sibunites using water vapor adsorption is demonstrated.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1377–1380, August, 1993. 相似文献
949.
催化裂化干气与苯烷基化催化蒸馏制乙苯反应网络热力学研究 总被引:2,自引:0,他引:2
高温气相反应条件下的催化裂化干气制乙苯过程中,容易生成甲苯和二甲苯等副产物;在该过程中采用催化蒸馏技术,使苯与乙烯在低温条件下进行反应,可大幅度降低产品中二甲苯的含量.通过对催化裂化干气与苯烷基化催化精馏过程中的各反应步骤进行分析与热力学计算,结合反应的实际产物组成,提出了苯与乙烯烷基化的反应网络,探讨了苯与乙烯烷基化反应过程中甲苯和二甲苯的形成机理及影响因素.结果表明,增大苯/乙烯比对提高乙烯平衡转化率及乙苯收率有利;在较低温度下进行烷基化反应,可大大减缓C-C键裂解速度,抑制甲苯和二甲苯生成,提高乙苯产品质量. 相似文献
950.
Beitz T Kötz J Wolf G Kleinpeter E Friberg SE 《Journal of colloid and interface science》2001,240(2):581-589
The influence of the nonionic polymer poly(N-vinyl-2-pyrrolidone) (PVP) in comparison to the surfactant 1-octyl-2-pyrrolidinone (OP) on the phase behavior of the system SDS/pentanol/xylene/water was studied. In both modified systems a strong increase in the water solubilization capacity was found, accompanied by a change in the spontaneous curvature toward zero. In the polymer-modified system an isotropic phase channel is formed with increasing polymer content that connects the L1 and the L2 phase. The lamellar liquid crystalline phase is destabilized in both cases. In the L1 phase the adsorption of PVP at the surface of the microemulsion droplets and the formation of a cluster-like structure is proven by several methods like 13C NMR T1 relaxation time measurments, zeta potential measurements, and rheology. In the L2 phase a modification of the interface of the inverse droplets is detected by a shift in the percolation boundary (conductivity) and 13C NMR T1 relaxation measurements. The formation of a cluster-like structure can be assumed on the basis of our rheological measurements. 相似文献