中红外波段二阶非线性光学晶体材料研究进展

新型无机红外波段二阶非线性光学晶体材料在光电子领域有着重要的应用，对它们的探索是当前非线性光学材料研究领域的难点和前沿方向之一。本文将材料按组成分成三大类（即经典的ABC₂型黄铜矿结构化合物，硫属元素其他化合物和AMX₃型卤化物），分别就新材料探索、已知材料的单晶生长等综述了近10余年来中红外波段二阶非线性光学晶体材料的研究进展。     

一种新的光致变色膜：Na2WO4-PAA-Glycerol体系研究

A method for preparing Na₂WO₄-PAA-Glycerol photochromic films was reported. The film was composed of Na₂WO₄, PAA and Glycerol, which were coated on a glass substrate. The film turned blue in the sun, and bleached to transparent in the darkness. The UV-Visible spectra showed strong absorbance at 300～500 nm, and the ABS changed signifanctly at 500～800 nm. The film showed the best photochromic behavior when n_Na2WO4∶n_PAA is 4%～5%. The mechanism was suggested that after irradiation, poly tunstate produced by Na₂WO₄ and PAA formed the tungsten blues. The tungsten blues were bleached due to oxidation back to poly tunstate by oxygen. The film showed not only an excellent photochromism property with rapid response and good reversibility, but also the simple techniques and good stability.     

Secondary succession and its effects on soil moisture and nutrition in abandoned old-fields of hilly region of Loess Plateau, China

Floristic composition, community structure and soil moisture and nutrient contents in abandoned fields of different ages were analyzed to clarify the regenerative aspects of succession as a tool for vegetation restoration. The results indicated that secondary succession in this region can be interpreted as an auto-succession: there are main changes in species-relative abundance and species turnover. Annual or biennial species (e.g. Artemisia scoparia), acted as pioneers and strongly dominated the early stages. Then, they underwent a progressive decline, while forbs (e.g. Artemisia sacrorum) and grasses (e.g. Xanthium sibiricum) had their peak abundance at intermediate stages. Dwarf shrubs (e.g. Lespedeza dahurica) and short rhizome grass (e.g. Bothriochloa ischaemum) appeared at mid-succession stage and gradually increased in abundance during succession, becoming dominant at late stages. The first axis of detrended correspondence canonical analysis arranged the sites according to their fallow time, indicating a successional sere. The second axis, associated with diverging pathways of regeneration, correlated with topographic factors and soil moisture and nutrition. Structural divergence between plots increased as succession went on, attained the highest at the mid-succession stage, decreased at the late stage.

Soil moisture and available phosphorus content decreased steadily with field age after their abandonment, whereas pools of organic matter, total and available nitrogen, potassium and total phosphorus increased with field age. The pace and direction of recovery of native vegetation and natural soil properties in these abandoned fields resembled classic old-field succession, which is a form of secondary succession that often serves as a template for guiding restoration efforts. Interface between the abandoned field soil and plant system was crucial to the above process. Our current study supported the generally accepted hypothesis in the succession literature.     

γ-二氧化锰/K3[Fe(CN)6]溶液界面的电子转移反转区

Marcus电子转移理论的主要成果之一是预言了电子转移反应反转区的存在.从实验上 验证Marcus反转区仍是一个热点问题.通过对γ-MnO2/K3[Fe(CN)6]溶液界面平带电位、极 化曲线的测量,计算了在极化条件下,γ-MnO2导带的电子直接转移到溶液中氧化态物种[F e(CN)6]3-空电子能级上的速率常数ket,logket对外加电位作图,观察到了Marcus反转区. 从理论上也论证了在半导体/溶液界面上的直接电子转移反转区的存在.     

固定接触界面切向静弹性刚度问题研究

根据两球体单峰同时受法向、切向载荷时微滑切向应力的分布以及MB模型,给出了界面的总切向接触静弹性条件刚度、总条件法向载荷的解析解。将切向接触静弹性条件刚度的解析解嵌入到有限元软件中,获得了整机的理论模态。以一款八四七厂华中工学院XHK5140型自动换刀计算机数控立式镗铣床上的结合部为研究对象,通过实验对解析解进行了定量验证。研究结果表明：在理论振型与实验振型一致的条件下,界面模型的相对误差在-19．2％～16．8％之间。     

基于光纤智能夹层传感结构的应力测量研究

制作了一种模块化的光纤传感夹层,对夹层内的光纤传感器的应力特性进行了实验研究。分析了应变对传感系数的影响,对埋入到光纤智能夹层中的两种光纤传感器的输出特性进行了比较。实验结果表明:光纤Bragg光栅传感器的波长漂移与应变之间具有理想的线性关系,但应变灵敏度由1.2pm/με降至1.15pm/με;由于制作工艺的局限,对于非本征F-P光纤传感器,当应变达到350με后,应变与载荷具有较好的线性响应。与非本征F-P光纤传感器相比,光纤Bragg光栅传感器是光纤智能夹层首选的应变传感器。将埋入了Bragg光栅传感器的智能夹层粘贴于某型飞机的翼-身连接构件内部进行监测,实验结果为光纤智能夹层应用于复合材料结构的应变监测提供了参考。     

Fabrication of thermo-responsive polymer nanocomposites for smart window applications

Abstract

Thermo-responsive polymers have attracted much attention in recent years because they can provide a variety of applications for smart devices, but the lack of sufficient mechanical properties and late response rate of the polymers limit their applications. In the current work, we fabricated polymer nanocomposites made from poly(vinyl methyl ether) and nanofillers with photothermal conversion property such as graphene oxide, antimony tin oxide nanoparticles, and silver nanoplates. The prepared nanocomposites showed rapidly reversible and reliable transparent-opaque transitions during the repeated heating and cooling processes, suggesting that they can be applied to smart window applications.     

光纤传感器和压电作动片对薄板振动控制的分析

利用双模模态域光纤传感器的模间干涉感知薄板结构中应变的变化、获得薄板结构振动变化状况，进一步利用压电体作为动元件，减小振幅，实现振动的主动控制，采用振型叠加法和直接积分相结合的方法，从理论上论证薄板分别受到正弦波激振力，脉冲激振力和方波激振力时的振动主动控制，并由脉冲激振下的响应得到控制前后的幅频特性曲线和相频特性曲线．。     

Empirical likelihood for AR-ARCH models based on LAD estimation

By employing the empirical likelihood method,confidence regions for the stationary AR(p)-ARCH(q) models are constructed.A self-weighted LAD estimator is proposed under weak moment conditions.An empirical log-likelihood ratio statistic is derived and its asymptotic distribution is obtained.Simulation studies show that the performance of empirical likelihood method is better than that of normal approximation of the LAD estimator in terms of the coverage accuracy,especially for relative small size of observation.     

An adaptive trust region method and its convergence

In this paper, a new trust region subproblem is proposed. The trust radius in the new subproblem adjusts itself adaptively. As a result, an adaptive trust region method is constructed based on the new trust region subproblem. The local and global convergence results of the adaptive trust region method are proved. Numerical results indicate that the new method is very efficient.