The preparation and adsorption properties of electrospun aramid nanofibers

The focus of this work is the preparation of aramid nanofibers via electrospinning technology and the study of their adsorption properties. In this article, aramid nanofibers were prepared by electrospinning aramid fibers solution with the addition of lithium chloride (LiCl). It showed a good adsorption capacity when methylene blue (MB) was used as the model target. There were much larger adsorption amounts and faster kinetics of uptaking target species of electrospun aramid nanofibers to MB than that of electrospun polyethersulfone (PES) nanofibers. Compared with activated carbon, aramid nanofibers also have a much faster adsorption rate to MB. Aramid nanofibers were subsequently used to effectively remove endocrine disruptors such as bisphenol A (BPA), phenol (Phe), and p‐hydroquinone (BPhe) from their aqueous solutions. Additionally, molecule imprinted technology enhances aramid nanofibers with much higher adsorption amounts and special adsorption property for endocrine disruptors. These results showed that aramid nanofibers have the potential to be used in environmental applications. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012     

非线性Schrōdinger方程和非线性Klein-Gordon方程耦合组Cauchy问题整体经典解的存在唯一性

本文讨论非线性Schrōdinger方程和非线性Klein-Gordon方程耦合组的Cauchy问题,对初值和空间维数以及非线性项加以适当限制,在Sobolev空间框架下,得到了整体经典解的存在唯一性。     

考虑处置效果的苯系物泄露应急方案生成方法

针对苯系物泄露次生突发环境事件的应急响应问题,研究了基于案例推理和处置效果的应急方案生成方法。首先,在计算案例相似度时,为避免历史案例不全产生的情景要素遗失,基于随机森林算法,结合专家知识构建了权重求解方法,采用案例检索方法得到相似案例集;然后,构建了应急处置效果评估指标体系,以全面评价相似案例对应的处置效果;进一步,考虑多专家评价可弥补决策者知识、经验等的不足,引入了自适应群共识调整算法,得到群体评价意见,通过集结相似度与处置效果,得到了方案的综合评价值并生成最优方案;最后,用算例说明了方法的可行性和有效性。     

PS_(3000)-b-PAA_(5000)球形胶束温度效应的原位小角X射线散射技术研究

应用小角X射线散射技术(SAXS)对两亲嵌段共聚物聚苯乙烯聚丙烯酸(PS-b-PAA)胶束形貌的温度影响进行了原位表征.SAXS结果表明:随着水含量的增加,粒子尺寸相应增加;对于水含量10%的PS_(3000)-b-PAA_(5000)胶束溶液,发现了明显的SAXS双峰现象;双峰的位置不随着温度的变化而改变,但是peak 1和peak 2的相对强度随着温度发生了减弱和增强的交错变化;相邻的SAXS双峰说明在PS_(3000)-b-PAA_(5000)胶束溶液中最初形成的粒子尺寸并不是均匀的,主要分为尺寸极其相近的两种球形粒子;随着温度的升高,粒径大小不同的两种粒子存在着一种消融和生长的过程,并且保持着一个相同的归一化动态平衡速率.     

锁相检测式二维小角度测量装置

介绍了一种新型的二维小角度检测装置。由于该装置采用了光电自准直结构,以高灵敏度的四象限硅光电探测器作为检测元件,采用交流调制,锁相放大的方法对信号进行了处理,所以有效地消除了直流漂移的影响,提高了稳定性和测试精度。分析了光斑的形状和大小对测试结果的影响,研制了专门的标定装置。首先由高精度的光电自准直仪标定测量角度与输出信号的关系,并将相关数据存入单片机,然后由软件拟合出关系曲线。测量时,既可自动显示角度的大小,同时也可以与计算机相连。该测试系统结构小巧,具有较高的测量精度。     

Oh型分子三重简并态Hamiltonian算符的研究

本文应用群论原理及不可约张量性质，详细推导了Ｏｈ型分子三重简并态Ａｍａｔ－Ｎｉｅｌｓｅｎ方案中精确到四级的Ｈａｍｉｌｔｏｎｉａｎ算符，为Ｏｈ型分子精细结构理论和光谱的进一步研究做了数学上的准备。     

碘分子吸收光谱研究

我们用HRD-1型双光栅单色仪记录了碘分子在可见光区域的吸收光谱。确定了大量的带头,由此得出了碘分子的离解限、离解能、力常数和振动基频。实验结果与理论结果很符合。     

对《对重整热力学第二定律理论体系的不同看法》一文的补正

对笔者在《大学物理》2002年第8期上发表的《对重整热力学第二定律理论体系的不同看法》一文的错误之处进行了补正.     

Hydrogen dissociation on high-temperature tungsten

H₂ dissociation on polycrystalline tungsten is measured from 1700 to 3000 K using the filament temperature (T) change and a normalized H-atom density at the chamber surface. The dissociation probability per H₂ filament collision (P_diss) saturates at 0.40 at high T and has a 2.25 ± 0.05 eV apparent activation energy when P_diss ? 1. This activation energy is consistent with prior data and models, but the H₂ pressure dependence is not. P_diss is independent of the H₂ pressure for this entire T range and the 1-85 mTorr pressure range studied, contradicting the primary model that has been used to explain H₂ dissociation on tungsten and other metals. We show that some apparently contradictory prior measurements are actually consistent with our observations and with each other, once this pressure dependence of P_diss is recognized.     

Characterization of an in‐vacuum PILATUS 1M detector

A dedicated in‐vacuum X‐ray detector based on the hybrid pixel PILATUS 1M detector has been installed at the four‐crystal monochromator beamline of the PTB at the electron storage ring BESSY II in Berlin, Germany. Owing to its windowless operation, the detector can be used in the entire photon energy range of the beamline from 10 keV down to 1.75 keV for small‐angle X‐ray scattering (SAXS) experiments and anomalous SAXS at absorption edges of light elements. The radiometric and geometric properties of the detector such as quantum efficiency, pixel pitch and module alignment have been determined with low uncertainties. The first grazing‐incidence SAXS results demonstrate the superior resolution in momentum transfer achievable at low photon energies.