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71.
Fei Qi Yayun Pu Daofu Wu Xiaosheng Tang Qiang Huang 《Chemical record (New York, N.Y.)》2023,23(10):e202300078
It is still challenging to design and develop the state-of-the-art photocatalysts toward CO2 photoreduction. Enormous researchers have focused on the halide perovskites in the photocatalytic field for CO2 photoreduction, due to their excellent optical and physical properties. The toxicity of lead-based halide perovskites prevents their large-scale applications in photocatalytic fields. In consequence, lead-free halide perovskites (LFHPs) without the toxicity become the promising alternatives in the photocatalytic application for CO2 photoreduction. In recent years, the rapid advances of LFHPs have offer new chances for the photocatalytic CO2 reduction of LFHPs. In this review, we summarize not only the structures and properties of A2BX6, A2B(I)B(III)X6, and A3B2X9-type LFHPs but also their recent progresses on the photocatalytic CO2 reduction. Furthermore, we also point out the opportunities and perspectives to research LFHPs photocatalysts for CO2 photoreduction in the future. 相似文献
72.
Tuning the Reactivity of Isocyano Group: Synthesis of Imidazoles and Imidazoliums from Propargylamines and Isonitriles in the Presence of Multiple Catalysts 下载免费PDF全文
Dr. Shuo Tong Dr. Qian Wang Prof. Dr. Mei‐Xiang Wang Prof. Dr. Jieping Zhu 《Angewandte Chemie (International ed. in English)》2015,54(4):1293-1297
The reaction of propargyl amines with tert‐butylisonitrile in the presence of a catalytic amount of both Yb(OTf)3 and AgOTf afforded imidazoles, whereas the same reaction with primary and secondary alkylisonitriles, as well as arylisonitriles, in the presence of three metal salts [Yb(OTf)3/AgOTf/KOTf] resulted in the 1,3,4,5‐tetrasubstituted imidazoliums in excellent yields. Both chiral amines and chiral isonitriles can be used to provide corresponding chiral heterocycles without racemization. In this multiple catalytic system, Yb(OTf)3 catalyzed the insertion of isonitriles to the N? H bond of amines, AgOTf catalyzed the 5‐exo‐dig cyclization of the resulting amidine nitrogen to the tethered triple bond, and KOTf promoted the salt metathesis, thus providing at the same time the counterion to the imidazolium. Against common knowledge, the isocyano group acted in these reactions as a polarized triple bond instead of conventional carbene‐like function. 相似文献
73.
Dr. Martin Schmidt Prof. Albert Masson Prof. Hai‐Ping Cheng Prof. Catherine Bréchignac 《Chemphyschem》2015,16(4):855-865
Adsorption and coadsorption studies on free silver clusters show that nitrogen physisorbs like rare gases, whereas oxygen chemisorbs with similarities and differences to bulk silver surfaces. Silver nanoparticles activate, or even dissociate adsorbed oxygen molecules. The global electron configurations of the adsorbent and adsorbate dominate the stability at small clusters. This is more important than geometry and site effects. Due to electronic shell effects and electron pairing, the activation of oxygen strongly varies with size. At more than 40 free electrons in the complex, such quantum effects start to blur. The size dependence becomes smoother and general trends govern the reactivity, which is driven by the interaction between the charge state of the nanoparticle and the charge transfer of the reaction. 相似文献
74.
恒电流库仑分析法测定青霉素G钠盐含量 总被引:1,自引:0,他引:1
梁述忠 《理化检验(化学分册)》2005,41(12):914-916
将青霉素G钠盐在pH4.6条件下水解成青霉氨基酸;以银电极为阳极,电解产生滴定剂Ag^+,以Ag^+滴定青霉氨基酸,采用电位法确定库仑滴定终点,由电解定律计算青霉素G钠盐含量。此法取代了汞量法,消除了汞污染,相对误差为0.184%,RSD(n=11)为0.030%。 相似文献
75.
76.
Synthetic oligopeptides with a tryptophan residue at the C-terminus have been used for the synthesis of gold and silver nanoparticles at pH 11. The tryptophan residue in the peptides is responsible for the reduction of metal ions to the respective metals, possibly through electron transfer. A mechanistic pathway has been proposed to explain the reductive properties of the tryptophan moiety of the peptide based on some spectroscopic techniques, such as UV-visible and fluorescence spectroscopy. This study reveals that some of the peptide molecules are converted to its corresponding ditryptophan, kynurenine form and some cross-linked products, all of which are highly fluorescent species. The resultant peptide-functionalized metal nanoparticles have also been characterized by UV-visible spectroscopy, transmission electron microscopy, and Fourier transform IR spectroscopy and thermogravimatric analysis. 相似文献
77.
Silver‐Catalyzed Cross‐Coupling of Propargylic Alcohols with Isocyanides: An Atom‐Economical Synthesis of 2,3‐Allenamides 下载免费PDF全文
Jianquan Liu Zhenhua Liu Nannan Wu Dr. Peiqiu Liao Prof. Xihe Bi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(8):2154-2158
Cross‐coupling reactions between propargylic alcohols and isocyanides, by means of silver catalysis, have been described. This new reaction is both atom and step efficient and is applicable to a broad scope of substrates, allowing the synthesis of a range of synthetically valuable 2,3‐allenamides in moderate to excellent yields. 相似文献
78.
Mohammad Reza Kashefi Alasl Mahmoud Reza Sohrabi Mehran Davallo 《Journal of separation science》2019,42(9):1777-1785
In this work, a fast and simple magnetic dispersive solid phase extraction methodology was developed utilizing Ag@magnetite nanoparticles@graphene nanocomposite as an efficient magnetic nanosorbent for preconcentration and determine of five aromatic amines in water samples. The sorbent was characterized by diverse characterization techniques. After the extraction, high‐performance liquid chromatography with UV detection was utilized to analysis the aromatic amines. The effects of different factors on the extraction process were studied thoroughly via design of experiment and desirability function. Detection limits and linear dynamic ranges were obtained in the range of 0.10–0.20 and 0.3–300 μg/L, respectively. The relative standard deviations (n = 5) were in the range of 4.3–6.5%. Eventually, the method was employed for determination of target aromatic amines in various water samples. 相似文献
79.
Kuai L Geng B Wang S Zhao Y Luo Y Jiang H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(12):3482-3489
Much effort has gone into generating polyhedral noble metal nanostructures because of their superior electrocatalytic activities for fuel cells. Herein, we report uniform, high-yield icosahedral silver and gold nanoparticles by using a facile one-pot, seedless, water-based approach that incorporates polyvinyl pyrrolidone and ammonia. Electrocatalysis of the oxygen-reduction reaction was carried out in alkaline media to evaluate the performance of the icosahedral nanoparticles. They showed excellent stability and much higher electrocatalytic activity than the spherelike nanoparticles; they display a positive shift in reduction peak potential for O(2) of 0.14 and 0.05 V, while the reduction peak currents of the silver and gold icosahedra are 1.5- and 1.6-fold, respectively, better than the spherelike nanoparticles. More importantly, the icosahedral nanoparticles display electrocatalytic activities comparable with commercial Pt/C electrocatalysts. The facile preparation of icosahedral silver and gold nanoparticles and their superior performance in the oxygen reduction reaction render them attractive replacements for Pt as cathode electrocatalysts in alkaline fuel cells. 相似文献
80.
Reactivity of Tris(dialkylthiophosphinyl)phosphines – Crystal Structure of [Ag{O[P(S)Me2]2}2][AsF6] In contrast to tris(dialkylphosphoryl)phosphines the reaction of tris(dimethylthiophosphinyl)phosphine with transition metal hexafluoroarsenates of the type [M(SO2)m [AsF6]n (M = Ag, m = 0, n = 1; M = Fe, Cd, m = n = 2) forms no molecular 2 : 1-complexes but polymeric products. The silver polymer is transformed into [Ag{O[P(S)Me2]2}2][AsF6], which is also formed by the reaction of Ag[AsF6] with O[P(S)Me2]2. It crystallizes in the space group P1 with a = 862.5(2), b = 1 241.4(2), c = 1 254.0(3)pm, α = 80.34(1), β = 101.99(6), γ= 73.75(1)° (at 20°C) and Z = 2. The central silver atom is surrounded by four sulphur atoms in a slighly distorted tetrahedron. The average (Ag? S) and (P? S) bond lengthes are 259.4(2) pm and 194.9(2)pm, respectively. 相似文献