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51.
A. F. Isakovic A. Stein J. B. Warren S. Narayanan M. Sprung A. R. Sandy K. Evans‐Lutterodt 《Journal of synchrotron radiation》2009,16(1):8-13
Motivated by the anticipated advantageous performance of diamond kinoform refractive lenses for synchrotron X‐ray radiation studies, this report focuses on progress in designing, nanofabricating and testing of their focusing performance. The method involves using lift‐off and plasma etching to reproduce a planar definition of numerically determined kinoform refractive optics. Tests of the focusing action of a diamond kinoform refractive lens at the APS 8‐ID‐I beamline demonstrate angular control of the focal spot. 相似文献
52.
53.
《Green Chemistry Letters and Reviews》2013,6(3):261-267
Abstract In the present work, metals (cadmium, lead, copper, nickel, tin, selenium, and mercury) have been estimated in the Ebro River (Spain) using the zebra mussel (Dreissena polymorpha) as an environmental bio-indicator. In two sequential studies, in 2006 and 2008, concentrations of metals were calculated in water as well as in the shells and fleshes of the zebra mussels. Samples were collected from assorted locations of the river. Metals were determined successfully at trace levels through voltamperometry, a sensitive technique. It has been noted that analysis of bioaccumulators like zebra mussels can be helpful in evaluating metal pollution in water. 相似文献
54.
Krishna Nand Singh 《合成通讯》2013,43(16):2651-2654
A safe and simple method of preparing organic carbamates has been achieved from amines and carbon dioxide using tetraethylammonium superoxide generated in situ. 相似文献
55.
An efficient and environmentally benign method for the synthesis of organic carbamates was developed. Amines, CO2, and alkyl halides underwent a three-component reaction with the aid of K2CO3 and polyethylene glycol (PEG, MW = 400), affording the organic carbamates under ambient conditions. PEG could presumably act as a solvent and phase-transfer catalyst (PTC). Notably, the presence of PEG could also depress the alkylation of both the amine and the carbamate, thus resulting in enhanced selectivity toward the target carbamate. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file. 相似文献
56.
Oxidation of structurally diverse 2-arylbenzothiazolines to give the corresponding 2-arylbenzothiazoles has been carried out in benzene using dimethyldichlorosilane and trimethylchlorosilane. Short reaction times, mild reaction conditions, easy and quick isolation of the products, and excellent yields are the main advantages of this procedure. 相似文献
57.
Emanuele Aresu Laura CarrocciaStefania Fioravanti Simona GasbarriLucio Pellacani Fabio Sciubba 《Tetrahedron》2013
Chiral racemic α-diimines, tested in aziridination reactions with NsONHCO2Et, for the first time led to the synthesis of (±)-bidiaziridines, stereoselectively derived from the corresponding meso (E-s-trans-E)-α-diimines. Moreover, a minor bidiaziridine isomer, probably a meso form that was lost under classical work-up conditions, can be obtained by adding water to the crude mixtures at the end of amination reactions. The results definitively prove that the imine aziridination by carbamates is a two-step domino process. The structures of the compounds were determined using 2D NMR on purified bidiaziridines. 相似文献
58.
Dr. Jörg Wagler Dr. Erica Brendler Prof. Dr. Thomas Heine Dr. Lyuben Zhechkov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(42):14296-14303
The reaction of 1‐methyl‐3‐trimethylsilylimidazoline‐2‐thione with hexachlorodisilane proceeds toward substitution of four of the disilane Cl atoms during the formation of disilicon complexes with two neighboring hexacoordinate Si atoms. The N,S‐bidentate methimazolide moieties adopt a buttressing role, thus forming paddlewheel‐shaped complexes of the type ClSi(μ‐mt)4SiCl (mt=methimazolyl). Most interestingly, three isomers (i.e., with (ClN4)Si? Si(S4Cl), (ClN3S)Si? Si(S3NCl), and (ClN2S2)Si? Si(S2N2Cl) skeletons as so‐called (4,0), (3,1), and cis‐(2,2) paddlewheels) were detected in solution by using 29Si NMR spectroscopic analysis. Two of these isomers could be isolated as crystalline solids, thus allowing their molecular structures to be analyzed by using X‐ray diffraction studies. In accord with time‐dependent NMR spectroscopy, computational analyses proved the cis‐(2,2) isomer with a (ClN2S2)Si? Si(S2N2Cl) skeleton to be the most stable. The compounds presented herein are the first examples of crystallographically evidenced disilicon complexes with two Si? Si‐bonded octahedrally coordinated Si atoms and representatives of the still scarcely explored class of Si coordination compounds with sulfur donor atoms. 相似文献
59.
A simple, accurate and rapid voltammetric method has been developed for the quantitative determination of coenzyme Q10. Studies with direct current voltammetry were carried out using a glassy carbon electrode (GCE) in a phosphate buffer solution (pH 6.86). A well-defined oxidation peak of CoQ10 was obtained at -0.600 V vs Ag/AgCl. The magnitude of the oxidation peak current has been found to be related to the concentration of the coenzyme over the range of (2.010-5 to 2.010-4 M) (r = 0,991). Antioxidant activity of CoQ10 was investigated. 相似文献
60.
《Arabian Journal of Chemistry》2022,15(7):103876
Knowledge of drug solubility data in supercritical carbon dioxide (SC-CO2) is a fundamental step in producing nano and microparticles through supercritical fluid technology. In this work, for the first time, the solubility of metoclopramide hydrochloride (MCP) in SC-CO2 was measured in pressure and temperature range of 12 to 27 MPa and 308 to 338 K, respectively. The results represented a range mole fractions of 0.15 × 10-5 to 5.56 × 10-5. To expand the application of the obtained data, six semi-empirical models and three models based on the Peng-Robinson equation of state (PR + VDW, PR + WS + Wilson and PR + MHV1 + COSMOSAC) with different mixing rules and various ways to describe intermolecular interactions were investigated. Furthermore, total enthalpy, sublimation enthalpy and solvation enthalpy relevant to MCP solvating in SC-CO2 were estimated. 相似文献