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11.
Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007 相似文献
12.
We perform an analysis of the pattern formation for a moving sheet of inviscid fluid. The sheet, which is assumed to have an infinite horizontal extent, moves at some prescribed velocity into a passive surrounding gas. The sheet’s thickness is assumed much smaller than the horizontal scale of the fluid motion. By considering a system that is symmetric with respect to the horizontal planes, long scale asymptotics are used to reduce the full governing equations in three dimensions to a set of three coupled nonlinear partial differential equations for the horizontal components of the velocity field and the height of the interface profile. The interfacial conditions consisting of the kinematic and normal stress balance are incorporated into these evolution equations. Investigations are carried out as function of the sole dimensionless parameter, namely the Weber number. A small amplitude stability analysis around the planar gas–liquid interface reveals that wave patterns in the form of traveling plane waves occur subcritically, and are therefore unstable. The reduced evolution equations are solved numerically for fixed values of the Weber number. Since the reduced system of equations is homogeneous, the wave motion is generated by initial conditions. Five initial conditions have been imposed: one-dimensional rolls, two-dimensional squares, two-dimensional hexagons, two-dimensional ridges, and smooth peaks. The ensuing evolution of the liquid sheet’s shape and corresponding flow fields are described by illustrations of the changes in the sheet’s morphology with time. 相似文献
13.
Sun Shufen 《Acta Mechanica Sinica》1987,3(1):44-51
The coupled model has been developed in this study for moisture transport and beat exchange in soil. The model is driven by
atmospheric conditions measured in a field. The concept that soil has a surface resistance to evaporation is introduced in
order to relate the evaporation from surface with the vapour flux in air. With the use of this concept, the simulation results
agree quite well with the measured data. 相似文献
14.
通过实验分析确立了把光纤电阻作为衡量气密性碳涂覆光纤通过2%应变筛选的过渡标准。要拉制2%应变筛选的碳涂覆光纤,其电阻值应小于30kΩ/cm。 相似文献
15.
Optimization of plate buckling resistance is very complicated, because the in-plane stress resultants in the prebuckled state of a plate are functions of thickness distribution. This paper discusses the problem of finding the optimum thickness distribution of isotropic plate structures, with a given volume and layout, that would maximise the buckling load. A simple numerical method using the finite-element analysis is presented to obtain the optimum thickness distribution. Optimum designs of compression-loaded rectangular plates with different boundary conditions and plate aspect ratios are obtained by using the proposed method. Optimum designs from earlier studies and the methods of buckling analysis used to attain these results are discussed and compared with the designs from the proposed method. This paper also examines the reliability of the optimality criterion generally used for plate buckling optimization, which is based on the uniform strain energy density. 相似文献
16.
Zhengping Hao Lidun An Junling Zhou Hongli Wang 《Reaction Kinetics and Catalysis Letters》1996,59(2):295-300
Supported gold catalyst for eliminating hydrogen from CO2 feed gas in the production of urea is found to be superior to other industrial catalysts (e.g. Pt/Al2O3 and PdPt/Al2O3) in catalytic activity and resistance to sulfur poisoning. 相似文献
17.
A series of acrylic ester copolymers with viologen group as pendant were synthesizedthrough the reaction of MMA-EBA (Ethenyl bromoacetate) copolymer with 4-(4'-pyridyl)-N-alkyl (or arylalkyl) pyridiniums. These viologen copolymers can exchange their anionwith NH_4PF_6 in methanol to improve their solubility in organic solvents such as DMFand acetone. Compared with the corresponding low molecular viologens, these viologencopolymers have relatively lower color development rate under UV light and fade fasterin air due to less affinity to photo-reductant and deficiency of association between theircation radicals. Their photofatigue resistant ability is also slightly better than that of lowmolecular vinlogens. 相似文献
18.
A scratch-resistant single-layer antireflective coating by a low temperature sol-gel route 总被引:1,自引:0,他引:1
A novel quarterwave-thick narrow-bandwidth antireflective coating has been developed for both plastic and vitreous substrates by a sol-gel route. This coating has revealed pronounced scratch- and climatic-resistance under adverse conditions. The single-layer coating consists basically of a composite material made of silica as the discontinuous phase and of a polytetrafluoroethylene-derived (Teflon1) organic polymer as the continuous phase. This leads to fluorine-containing colloidal silica product, or a so-called Flucosil coating. The coating is applied by spinning or dipping from specific solutions at room temperature followed by a mild and short heat treatment. In addition to remarkable abrasion and environmental resistance properties, such coatings have displayed excellent laser-induced damage threshold levels, surpassing uncoated substrates.We hope such a product might open new perspectives concerning household articles, architectural optical thin-films, ophthalmic uses, and so on. 相似文献
19.
In this study, we report the design and synthesis of a series of new simplified fumitremorgin C analogues. The preliminary biological study indicated some of these simplified fumitremorgin C might be developed into breast cancer resistance inhibitors. 相似文献
20.
We study the limit theorem related to the interface of the three-dimensional Ising model. Dobrushin proved that the interface does not fluctuate and becomes rigid for sufficiently large. We define the random fieldX
L
(t, s), 0t, s1, on the interface, and prove that XL(t, s) converges to the Brownian sheet as L for sufficiently large, whereL denotes the size of the system. This result does not mean that the interface itself converges to the Brownian sheet. 相似文献