左删失右截断数据的分位数的固定宽度序贯置信区间估计

基于左截断右删失数据下的乘积限估计构造了分位数固定宽度序贯置信区间及其估计，研究了序贯置信区间估计的渐近性质。作为副产品，获得了分位数估计近邻点的Bahadur表示定理。这个表示定理是推导分位数固定宽度序贯置信区间估计渐近性质的重要基础。同时，在文中，进行了一些计算机模拟试验，证明了左截断右删失数据下分位数估计的序贯方法是效的和精确的。     

面向生物过程的在线式傅里叶变换红外光谱仪

针对生物过程反应底物含量的实时测量,设计了一种在线式傅里叶变换红外光谱仪及衰减全反射(attenuated total reflectance,ATR)探头。(1) 光谱仪采用双立体角镜和平面镜相组合的方法,设计了一种高性能干涉仪系统;采用了光路折叠方式,使干涉仪结构紧凑;采用了双立体角镜,大大减少了动镜运动过程中存在的旋转、倾斜等因素影响;采用平行四边形摆动柔性支撑装置来支撑动镜,使动镜移动时无摩擦,无抖动,运行平稳;采用ZnSe分束器,使仪器抗潮湿性能大大增强;采用分束器60°光入射方式,提高了光通量。(2) 该工作设计的一种结构简单、光通量大、经济实用的ATR原位测量探头,入射光和出射光的传输均利用了大口径内镀中红外高反膜光导管作为ATR探头的红外光传输介质,从而大大降低红外光在光导管内壁多次反射后的能量损失,使得ATR探头具有高光通量,提高了信号强度,使信号的检出更加容易。最后采用灵敏度高的MCT(碲镉汞)检测器实现红外干涉信号的收集,使得检测效果更好。实验结果表明,系统具有防潮性能出色,光通量大,在线测量等优点。所设计在线式傅里叶红外光谱仪,能够较好的完成生物反应器内甘油等常见反应物底物的实时测量,在生物在线分析、化学物质检测、材料分析学等诸多领域具有较好的应用前景。     

Effects of optical axis direction on optical path difference and lateral displacement of Savart polariscope

A simple method is applied to calculating the optical path difference (OPD) of a plane parallel uniaxial plate with an arbitrary optical axis direction. Then, the theoretical expressions of the OPD and lateral displacement (LD) of Savart polariscope under non-ideal conditions are obtained exactly. The variations of OPD and LD are simulated, and some important conclusions are obtained when the optical axis directions have an identical tolerance of \pm 1^{{\circ}}. An application example is given that the tolerances of optical axis directions are gained according to the spectral resolution tolerances of the stationary polarization interference imaging spectrometer (SPIIS). Several approximate formulae are obtained for explaining some conclusions above. The work provides a theoretical guidance for the optic design, crystal processing, installation and debugging, data analysis and spectral reconstruction of the SPIIS.     

稀土矿区茶叶中稀土元素ICP-AES测定

本文用ＩＣＰ－ＡＥＳ测定稀土矿区茶叶中稀土元素，并用干扰系数法校正茶叶中的无机元素及其他稀土元素对待测稀土元素的光谱干扰。在最佳工作条件下，测定了茶叶样品中的稀土元素含量。     

稀土元素原子发射光谱及其谱线干扰的高分辨率ICP-AES研究Ⅱ.钐基体对其他稀土元素的光谱干扰

稀土元素在当今生产、生活中具有极重要的地位，由于稀土元素的原子发射光谱极为复杂，因此光谱干扰给稀土元素的原子发射光谱分析带来极大的困难。本工作利用高分辨率ＩＣＰ－ＡＥＳ仪器详细研究了Ｓｍ基体对其他稀土元素重要分析线的光谱干扰，获得了大量的光谱及光谱干扰信息，为以稀土为基体的痕量稀土分析线的选择及光谱分析提供了依据     

电感耦合等离子体原子发射光谱法测定高纯铼酸铵中Ca、Cd、Mn、Fe、Mg、Al、Cu、Co、Mo、Pb、Sn和Ni

本文介绍了电感耦合等离子体发射光谱法（ICP－AES）测定高纯铼酸铵中12个杂质元素的方法。采用挥发健康基体，探讨了高铼酸铵基体的干扰及其消除办法。ICP－AES测定结果的准确度和精密度均能满足分析要求。     

分子筛和担体中主含量元素和杂质元素的同时测定

本文研究了用微波消化试样，ICP－AES法同时测定分子筛及担体中的主含量元素Si、Al和杂质元素Fe、Na、Ca、Mg的方法。相对标准偏差：Si、Al＜2％，Fe、Na、Ca、Mg≤4％，杂质元素回收率为97％－107％。方法快速，简便、准确，可靠。     

等离子体发射光谱法测定地质样品中的硼

用HF－HNO3－HCl－H3PO4混合酸分解样品，在氨性条件下，以元素的磷酸盐沉淀分离样品中大量的Fe、Al、Ca、Mg 等基体元素，然后用ICP－AES法测定，可用于地质样品中硼的分析。     

Characteristics of the magnetic analysis system for a compact MPR-type spectrometer

The magnetic proton recoil（MPR）spectrometer is a novel diagnostic instrument with high perfor-mance for measurements of neutron spectra in inertial confinement fusion（ICF）experiments and high power fusion devices.A compact MPR-type spectrometer dedicated to the research of pulsed deuterium-tritium（DT）neutron spectroscopy of special experimental conditions is currently under design.Analyses of the main parameters and performance of the magnetic analysis system through 3-D particle transport calculations and MonteCarlo simulations and calibration of the system performance as a test using CR-39 solid track detector and α particle from 239pu and 226Ra radioactive sources are presented in this paper.The results indicate that the magnetic analysis system will achieve a detection efficiency level of 10-5-10-4 at an energy resolution of 1.5%-2.1%,and fulfills the design goals of the spectrometer.     

Analysis of a moderate resolution Fourier transform imaging spectrometer

A moderate resolution Fourier transform imaging spectrometer based on a modified Michelson interferometer is presented. The moving part of the interferometer is a moving wedged prism (MWP) instead of a moving mirror. The principle of the interferometer is described and the optical path difference as a function of the displacement of the MWP is calculated. Theoretical calculation and analysis are presented for the two moveable directions (hypotenuse and right angle side) of the MWP. The modified Michelson interferometer is not so sensitive to the non-uniform variation of moving speed and the environmental vibrations compared with the conventional Michelson interferometer. It is compact and has a large numerical aperture. The interferometer facilitated by CCD camera and the accompanying digital hardware and software are becoming the imaging spectrometer with moderate resolution is applicable in ultraviolet-infrared region.