拉曼光谱法检测三甘醇中的水分含量

三甘醇是具有强烈吸湿性的粘稠液体,被用作石油天然气产品的新型干燥剂及脱水剂,在对三甘醇品质进行评价时,水分的含量是非常重要的指标。本文利用拉曼光谱技术,对三甘醇样品的拉曼光谱图进行采集,三甘醇标准品在波数129cm-1、321cm-1、531cm-1、830cm-1、886cm-1有较强的拉曼信号,以特征波数886cm-1的信号强度与对应的水分含量做标准曲线,得回归方程为y=-42.95x+4583.5,相关系数R2=0.9986,说明拉曼信号强度与三甘醇水分含量有良好的线性关系。选择水分含量为10%、15%、85%、95%的三甘醇溶液作为回测,平均回收率在90.1%~115.86%,相对标准偏差在0.43%~10.1%,该方法可准确检测三甘醇中的水分含量,且快速、操作简便、样品用量少,可用于现场检测。     

Asymptotic analysis for multi-objective sequential stochastic assignment problems

ABSTRACT

We provide an asymptotic analysis of multi-objective sequential stochastic assignment problems (MOSSAP). In MOSSAP, a fixed number of tasks arrive sequentially, with an n-dimensional value vector revealed upon arrival. Each task is assigned to one of a group of known workers immediately upon arrival, with the reward given by an n-dimensional product-form vector. The objective is to maximize each component of the expected reward vector. We provide expressions for the asymptotic expected reward per task for each component of the reward vector and compare the convergence rates for three classes of Pareto optimal policies.     

A support for the identification of non-tryptic peptides based on low resolution tandem and sequential mass spectrometry data: The INSPIRE software

A simple software, to be used as an aid in the identification of non-tryptic peptides based on low resolution (3D-ion trap) tandem (MS/MS) and sequential (MS³) mass spectrometry data, is presented.     

ICP OES Simultaneous Determination of Ca,Cu, Fe,Mg, Mn,Na, and P in Biodiesel by Axial and Radial Inductively Coupled Plasma-Optical Emission Spectrometry

Abstract

A simple and rapid method for the simultaneous determination of seven trace elements in biodiesel by axial and radial view Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) is proposed, in which the sample is emulsified with Triton X-100 and water, and in which yttrium is employed as an internal standard. The better obtained quantification limits (10 s) were by axial view, 0.165, 0.099, 0.033, 0.007, 0.016, 0.132, 0.660 µg g^?1 for Ca, Cu, Fe, Mg, Mn, Na, and P, respectively, based on a sample mass of 1.0 g diluted to a final mass of 10 g in the analytical solution. Calibration was carried out with aqueous standards, thus avoiding the use of frequently instable organic standards. Elemental recoveries were in the range of 90 to 109% for all seven analytes studied, and also the precision of the method was satisfactory (RSD < 8%).     

A note on random walks with absorbing barriers and sequential Monte Carlo methods

In this article, we consider importance sampling (IS) and sequential Monte Carlo (SMC) methods in the context of one-dimensional random walks with absorbing barriers. In particular, we develop a very precise variance analysis for several IS and SMC procedures. We take advantage of some explicit spectral formulae available for these models to derive sharp and explicit estimates; this provides stability properties of the associated normalized Feynman–Kac semigroups. Our analysis allows one to compare the variance of SMC and IS techniques for these models. The work in this article is one of the few to consider an in-depth analysis of an SMC method for a particular model-type as well as variance comparison of SMC algorithms.     

Characteristics of the magnetic analysis system for a compact MPR-type spectrometer

The magnetic proton recoil(MPR)spectrometer is a novel diagnostic instrument with high perfor-mance for measurements of neutron spectra in inertial confinement fusion(ICF)experiments and high power fusion devices.A compact MPR-type spectrometer dedicated to the research of pulsed deuterium-tritium(DT)neutron spectroscopy of special experimental conditions is currently under design.Analyses of the main parameters and performance of the magnetic analysis system through 3-D particle transport calculations and MonteCarlo simulations and calibration of the system performance as a test using CR-39 solid track detector and α particle from 239pu and 226Ra radioactive sources are presented in this paper.The results indicate that the magnetic analysis system will achieve a detection efficiency level of 10-5-10-4 at an energy resolution of 1.5%-2.1%,and fulfills the design goals of the spectrometer.     

AFS–3100原子荧光光度计联机异常故障排除

介绍了北京海光仪器公司生产的AFS–3100原子荧光光度计在使用过程中仪器与电脑通讯失败的故障原因及排除方法。     

Thermal oxidative degradation of additive-free polypropylene pellets investigated by multichannel Fourier-transform chemiluminescence spectroscopy

Thermal oxidative degradation of additive-free polypropylene pellets heated isothermally in dry air at 150 and 180 °C (below and above the melting point of 163 °C) was investigated by multichannel Fourier-transform chemiluminescence spectroscopy. The initial peak wavelength of chemiluminescence emission at 490 nm remained constant during the early stages of thermal degradation, but new emissions developed with time in the red spectral region over an extended oxidation period. The time-dependent luminescence spectra were deconvoluted into three emission bands by least-squares fitting using Gaussian curves. We concluded that at least three groups of luminescent species (luminophores), having different conjugation lengths, were generated by thermal oxidation over extended periods and show luminescence around 490, 660, and 740 nm.     

宽离子能量检测范围垂直引入反射式飞行时间质谱仪的研制

本实验室研制了国内首台宽离子能量检测范围飞行时间质谱仪。仪器采用紧凑式电子轰击源设计,配合离子透镜系统有效的调制离子流,飞行时间质量分析器采用了离子垂直引入式,双场加速和双场反射以及大尺寸MCP检测装置设计。仪器单离子信号半峰宽约2 ns,仪器分辨率优于1600FWHM,检测实际样品质量范围为1~127 amu(仪器理论质量检测上限优于800 amu),可检测离子能量范围优于2个数量级(3~140 eV)。若该TOF质量分析器与短瞬高压脉冲放电离子源耦合联用,可广泛应用于高能离子束的快速检测,如真空阴极放电对制备薄膜、离子注入材料的表征,导电材料的离子电荷态分布以及离子扩散速度的测定等。