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排序方式: 共有827条查询结果,搜索用时 15 毫秒
741.
《Analytical letters》2012,45(20):2569-2579
Abstract Adsorptive/extractive accumulation of 1,2,3,4-tetrahydrocarbazole at a carbon paste electrode is used to improve the subsequent voltammetric measurement with respect to sensitivity and selectivity. By simply immersing the electrode in the 1,2,3,4-tetrahydrocarbazole solution for a given period of time, and then transferring it to a blank solution, high degree of selectivity is achieved. After 10 min preconcentration, a detection limit near 1.4×10-8M 1,2,3,4-tetrahydrocarbazole is obtained. Cyclic voltammetry is used to aid understanding the nature of the accumulation process. Applicability to measurements of other indole alkaloids and to analysis of urine samples is illustrated. 相似文献
742.
《Analytical letters》2012,45(6):996-1014
A novel electrochemical sensor for bisphenol A was developed through the combination of a molecular imprinting technique with a multiwalled carbon nanotube paste electrode. A molecularly imprinted polymer and nonimprinted polymer were synthesized in the presence and absence of bisphenol A, and then used to prepare the electrode. The bisphenol A imprinted polymer was applied as a selective recognition element in the electrochemical sensor. Differential pulse voltammetry was used to characterize the electrochemical behavior of bisphenol A at the modified electrodes. The results showed that the imprinted sensor had highest response for bisphenol A. Parameters including the carbon paste composition, pH, and adsorption time for the imprinted sensor were optimized. Under the optimized conditions, the differential pulse voltammetry peak current was linear with the concentration of bisphenol A from 0.08 to 100.0 µM, with a detection limit of 0.022 µM. The imprinted sensor for bisphenol A exhibited good selectivity, stability, and reproducibility. This sensor was successfully used for the determination of bisphenol A in real water samples. 相似文献
743.
《Analytical letters》2012,45(13):2562-2573
Abstract A sensing system for uracil was constituted by using lanthanum hydroxide nanowires (LNW) as a modifier to obtain LNW modified carbon paste electrode (LNW/CPE) and by introducing copper(II) ion into supporting electrolyte to transform electroinactive uracil to electroactive uracil‐Cu(II) complex. The voltammetric behaviors of uracil in the presence of Cu(II) ion at LNW/CPE were investigated. A reduction peak of the uracil‐Cu(II) complex at ?0.18 V was the two‐electron reduction of Cu(II) ion in the uracil‐Cu(II) complex; while a new oxidation peak at 0.22 V was the one‐electron oxidation of the uracil‐Cu(I) complex. Additionally, the voltammetric responses of all the complexes at LNW/CPE were more sensitive than that at carbon and multiwall carbon nanotube paste electrodes, which resulted from both the large surface effect of LNW and the chemical coordination of uracil with La(III) ion in LNW. With the sensitive oxidation peak of the uracil‐Cu(I) complex at LNW/CPE, a linear range of 4.0×10?9?3.0×10?8 mol/l for uracil was obtained along with a detection limit of 2.0×10?10 mol/l. The proposed system was evaluated by the determination of uracil derivatives, anticancer drug 5‐flurouracil, in pharmaceutical preparations. 相似文献
744.
This work offers construction and comparative evaluation the performance characteristics of conventional polymer (I), carbon paste (II) and carbon nanotubes chemically modified carbon paste ion selective electrodes (III) for meclofenoxate hydrochloride are described. These electrodes depend mainly on the incorporation of the ion pair of meclofenoxate hydrochloride with phosphomolybdic acid (PMA) or phosphotungestic acid (PTA). They showed near Nernestian responses over usable concentration range 1.0 × 10−5 to 1.0 × 10−2 M with slopes in the range 55.15–59.74 mV (concentration decade)−1. These developed electrodes were fully characterized in terms of their composition, response time, working concentration range, life span, usable pH and temperature range. The electrodes showed a very good selectivity for Meclo with respect to a large number of inorganic cations, sugars and in the presence of the degradation product of the drug (p-chloro phenoxy acetic acid). The standard additions method was applied to the determination of MecloCl in pure solution, pharmaceutical preparations and biological samples. Dissolution testing was also applied using the proposed sensors. 相似文献
745.
《Analytical letters》2012,45(5):817-853
Abstract Carbon and its derivatives, as the high performance material, occupy a special place in electrochemistry due to its ‐in many ways‐ extreme properties. Recent trends and advances in the electrochemistry of carbon‐based electrodes are reviewed. The varieties of carbon‐based electrodes, their basic physicochemical properties and some characteristics are surveyed. Special attention is paid to the possibilities of carbon‐based electrodes in electroanalytical investigation in pharmaceutical dosage forms and biological samples using modern electrochemical techniques. This review includes a summary of the rules that must be considered for drug analysis from its dosage forms and biological samples using carbon‐based electrodes. The present review is the first comprehensive report on the heterogeneous and homogeneous carbon electrodes, and an addition to many excellent reviews on carbon electrodes in the literature. This review summarizes some of the recent developments and applications of carbon‐based electrodes for drug compounds in their dosage forms and in biological samples in the period from 1996 till 2006. Also some further selected designs (screen‐printed; carbon nanotubes, etc.) and applications have been discussed. 相似文献
746.
《Analytical letters》2012,45(7):1144-1157
Abstract The fabrication and analytical applications of two types of potentiometric sensors for the determination of ketoconazole (KET) are described. The sensors are based on the use of KET-molybdophosphoric acid (MPA) ion pair as electroactive material. The fabricated sensors include both polymer membrane and carbon paste electrodes. Both sensors showed a linear, stable and near Nernstian slope of 57.8 mV/decade and 55.2 mV/decade for PVC membrane and carbon paste sensors respectively over a relatively wide range of KET concentration (1 × 10?2 ? 5 × 10?5and 1 × 10?2 ? 1 × 10?6). The sensors showed a fast response time of < 30 sec and < 45 sec. A useful pH range of 3–6 was obtained for both types of sensors. A detection limit of 2.96 × 10?5M was obtained for PVC membrane sensor and 6.91 × 10?6 M was obtained for carbon paste sensor. The proposed sensors proved to have a good selectivity for KET with respect to a large number of ions. The proposed sensors were successfully applied for the determination of KET in pharmaceutical formulations. The results obtained are in good agreement with the values obtained by the standard method. 相似文献
747.
《Analytical letters》2012,45(11):1735-1746
Abstract Nanoscale Pt/RuO2 colloid with carbon paste support was synthesized and used to prepare a modified electrode for phenol detection. The results showed that the Pt/RuO2 catalyst has high activity for electrooxidation of phenol with reduced intermediate polymerization due to its significantly low potential for phenol oxidation. The detection limit was as low as 10?9 mol L?1 for the polishable Pt/RuO2/C paste electrode with good reproducibility. 相似文献
748.
749.
M. Miranda-Hernández J. Ayala Marina E. Rincón 《Journal of Solid State Electrochemistry》2003,7(5):264-270
In this work, various types of carbon black are electrochemically characterized to study their possible use in the electrochemical
evaluation of fullerene materials as hydrogen storage candidates. The cyclic voltammetry and chronopotentiometry studies were
performed in alkaline media, 6 M KOH, with carbon paste electrodes. Differences in the electrodes' electrochemical response
and their correlation with the various surface chemistries, morphology and doping species of carbon blacks suggest a stronger
dependency on the presence of doping agents (foreign metals) and on the surface structure than on the carbon black surface
area. The study allows the selection of appropriate carbon black materials to be used as matrixes in future fullerene composite
studies.
Electronic Publication 相似文献
750.
For the first time, the analytical application of integrate ionophore-transducer material based on magnetic graphene hybrids and 2,2-dithiodipyridine (DTDP) in solid-contact lanthanum (III) selective electrode is reported. The attachment of Fe3O4 nanoparticles (NPs) to graphene oxide (GO) for magnetic graphene hybrid is achieved by covalent bonding, and the universal problem, Fe3O4 NPs may easily leach out from the graphene during application, is successfully solved by the method above. The proposed electrode exhibits an excellent near-Nernstian response to lanthanum (III) ranging from 1.0 × 10−9 to 1.0 × 10−3 M with a slope of 17.81 mV/dec. Moreover, the excellent performance on fairly good selectivity, wide applicable pH range (3.0_8.0), fast response time (10 s) and long life time (2 months) reveal the superiority of the electrode. Most importantly, we have made a great improvement in the detection limit (2.75 × 10−10 M), which brings new dawn to the real-time detection of lanthanum (III) using ion selective electrode. 相似文献