Optoelectronic,Aggregation, and Redox Properties of Double-Rotor Boron Difluoride Hydrazone Dyes

We develop the chemistry of boron difluoride hydrazone dyes (BODIHYs) bearing two aryl substituents and explore their properties. The low-energy absorption bands (λ_max=427–464 nm) of these dyes depend on the nature of the N-aryl groups appended to the BODIHY framework. Electron-donating and extended π-conjugated groups cause a redshift, whereas electron-withdrawing groups result in a blueshift. The title compounds were weakly photoluminescent in solution and strongly photoluminescent as thin films (λ_PL=525–578 nm) with quantum yields of up to 18 % and lifetimes of 1.1–1.7 ns, consistent with the dominant radiative decay through fluorescence. Addition of water to THF solutions of the BODIHYs studied causes molecular aggregation which restricts intramolecular motion and thereby enhances photoluminescence. The observed photoluminescence of BODIHY thin films is likely facilitated by a similar molecular packing effect. Finally, cyclic voltammetry studies confirmed that BODIHY derivatives bearing para-substituted N-aryl groups could be reversibly oxidized (E_ox1=0.62–1.02 V vs. Fc/Fc⁺) to their radical cation forms. Chemical oxidation studies confirmed that para-substituents at the N-aryl groups are required to circumvent radical decomposition pathways. Our findings provide new opportunities and guiding principles for the design of sought-after multifunctional boron difluoride complexes that are photoluminescent in the solid state.     

Borane-Catalyzed Chemoselective and Enantioselective Reduction of 2-Vinyl-Substituted Pyridines

Herein, we report that highly chemoselective and enantioselective reduction of 2-vinyl-substituted pyridines has been achieved for the first time. The reaction, which uses chiral spiro-bicyclic bisboranes as catalysts and HBpin and an acidic amide as reducing reagents, proceeds through a cascade process involving 1,4-hydroboration followed by transfer hydrogenation of a dihydropyridine intermediate. The retained double bond in the reduction products permits their conversion to natural products and other useful heterocyclic compounds by simple transformations.     

Diazoacetonitrile (N2CHCN): A Long Forgotten but Valuable Reagent for Organic Synthesis

Diazoacetonitrile (N₂CHCN) is a small reactive diazoalkane. It has been synthesized for the first time already in 1898 by Theodor Curtius, however, did not gain much recognition in organic synthesis until recently. Only in 2015, after introduction of in situ and flow protocols for the safe generation of diazoacetonitrile, it started gaining popularity. In this minireview, the synthetic properties and applications of this valuable reagent are discussed.     

Characterization of the soluble one-generated totally saturated formations of finite groups

We prove that the finite length condition for the lattice of τ-closed totally saturated subformations of a τ-closed totally saturated formation is equivalent to the finite length condition for this lattice, and it is also equivalent for the formation to be soluble and one-generated.     

光强一定时饱和光电流随入射光频率的变化关系辨析

对光电效应实验中饱和光电流随入射光频率变化关系的几种谬误进行了辨析，给出了光强一定时饱和光电流随入射光频率变化的正确规律并作了解释。     

A class of periodic groups

We deal with periodic groups saturated with dihedral groups. In particular, it is proved that periodic groups of bounded period, and also periodic Shunkov groups, saturated with dihedral groups, are locally finite.Supported by RFBR grant No. 03-01-00356 and by the Krasnoyarsk Science Foundation, project 11F0202C.Translated from Algebra i Logika, Vol. 44, No. 1, pp. 114–125, January–February, 2005.     

有限群的Sylow-子群的弱s-可补极大子群(英文)

假设G是一个有限群,H是G的一个子群.称H在G是s-置换的,若对G的任意的Sylow-子群Gp,有HG_p=G_pH:称H在G是弱s-可补的,若存在G的子群T使得G=HT且H∩T≤H_(sG),其中H_(sG)是所有包含在H中的G的s-置换子群生成的子群.本文给出了下列定理:设F是一个包含超可解群系u的饱和群系,有限群G有一个正规子群H使得G/H∈F.若F~*(H)的每个Sylow子群的所有极大子群在G中是弱s-可补的,其中F~*(H)是H的广义Fitting子群,则G∈F.它是J.Algebra,2007,315:192-209一文中的Skiba公开问题在极大子群情形下的肯定回答.     

基于Newmark算法的任意磁化方向铁氧体电磁散射时域有限差分分析

利用坐标系转换矩阵给出实验室坐标系中饱和磁化铁氧体的频域磁导系数张量,再通过频域到时域的转换关系jω→?/?t得到一个二阶微分方程形式的时域本构关系.然后采用Newmark方法求解时域本构关系从而给出一种适用于处理任意磁化方向铁氧体电磁问题的Newmark时域有限差分算法.利用此算法计算了饱和磁化铁氧体层的反(透)射系数和饱和磁化铁氧体球的后向雷达散射截面,所获得的结果验证了此算法的正确有效性.     

飞秒激光等离子体中电子热传导现象的数值模拟

采用相对论电磁粒子模拟程序研究了飞秒激光等离子体相互作用中产生的电流密度、电场和自生磁场的发展演化过程。介绍了电子的非局域热输运的基本特性以及激光加热过程中温度烧蚀前沿稠密等离子体子区的预热效应、临界面附近的限流效应,以及冕区的反扩散与限流效应,得到了经典Spitzer-Harm理论描述的电子热传导随自生磁场的演化情形。数值模拟表明:在线性强激光作用下,由于电子初始时刻的无规则热运动,在等离子体上激发电磁不稳定性,而不稳定性激发的强电磁场使电子束在非常短的距离内沉积能量,同时对在激光有质动力推开电子时形成的超热电子能量输运产生抑制作用。