首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   26833篇
  免费   3019篇
  国内免费   1763篇
化学   19200篇
晶体学   230篇
力学   161篇
综合类   47篇
数学   76篇
物理学   11901篇
  2024年   35篇
  2023年   186篇
  2022年   622篇
  2021年   722篇
  2020年   864篇
  2019年   834篇
  2018年   711篇
  2017年   801篇
  2016年   1285篇
  2015年   1262篇
  2014年   1274篇
  2013年   2301篇
  2012年   1616篇
  2011年   1773篇
  2010年   1475篇
  2009年   1881篇
  2008年   1766篇
  2007年   1870篇
  2006年   1722篇
  2005年   1365篇
  2004年   1170篇
  2003年   1001篇
  2002年   781篇
  2001年   629篇
  2000年   555篇
  1999年   518篇
  1998年   423篇
  1997年   388篇
  1996年   313篇
  1995年   270篇
  1994年   201篇
  1993年   181篇
  1992年   151篇
  1991年   114篇
  1990年   70篇
  1989年   63篇
  1988年   112篇
  1987年   50篇
  1986年   30篇
  1985年   32篇
  1984年   36篇
  1983年   8篇
  1982年   27篇
  1981年   28篇
  1980年   27篇
  1979年   10篇
  1978年   12篇
  1976年   10篇
  1973年   11篇
  1971年   7篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
181.
In this work, chemically and topographically nanopatterned surfaces were produced by a top-down processing approach for biosensing devices. The nanopatterning was the result of the combination of plasma polymerisation (pp) of biofunctional materials and colloidal lithography techniques. The morphological and chemical properties induced by the plasma deposition-etching treatment were characterised by optical method combining ellipsometry and Fourier Transform Infrared spectroscopy studies. This method supported by atomic force microscopy measurements, allowed the full optical characterization of each step of the top-down process. The optical characterization of the end-up nanopatterned samples demonstrated that the chosen process is able to produce well-defined nanostructured surfaces with controlled chemical and morphological properties.  相似文献   
182.
The relationships of the structure and electrical properties of anisotropic HCl‐doped polyaniline (PANI) films cast from N,N′‐dimethylpropylene urea (DMPU) solutions and stretched to different draw ratios were studied. The anisotropic structure of the stretched PANI films was examined by X‐ray diffraction, near‐infrared wave‐guide coupling, and polarized infrared measurements. The PANI emeraldine base (EB) films cast from DMPU solutions had a single‐phase noncrystalline structure, and stretching of the films did not cause crystallization to occur. The transition moment angles of two weakly absorbing infrared bands were determined, and the Hermans' orientation functions for the PANI EB films were calculated. The PANI films were then doped with HCl, and the electrical properties were determined by impedance spectroscopy. With a specially designed test fixture, the in‐plane and through‐plane impedance was obtained. The conductivity along the stretch direction increased with orientation. The in‐plane conductivity was significantly higher than the through‐plane conductivity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 823–841, 2003  相似文献   
183.
Taking into account the effects of quantum interference and interface scattering, combining the electron current with hole current contribution to tunnel current,we study the coherent quantum transport in normal-metal/d-wave superconductor/normal-metal (NM/d-wave SC/NM) double tunnel junctions by using extended Blonder-Tinkham-Klapwijk (BTK) approach. It is shown that all quasiparticle transport coefficients and conductance spectrum exhibit oscillating behavior with the energy, in which periodic vanishing of Andreev reflection (AR) above superconducting gap is found.In tunnel limit for the interface scattering strength taken very large, there are a series of bound states of quasiparticles formed in SC.  相似文献   
184.
The behavior of zirconium atoms at the W(100) surface associated with oxygen adsorption at different sample temperatures has been studied by Auger electron spectroscopy (AES), ion scattering spectroscopy (ISS), and the relative change of the work function (Δф) measured by the onset of the secondary electron energy distribution. The results have revealed: (i) adsorption of zirconium onto the W(100) surface followed by the elevation of the sample temperature up to 1710 K in an oxygen partial pressure of 2.7 × 10−4 induces complete diffusion of zirconium atoms into the W(100) substrate; (ii) further exposure of oxygen induces co-existence of oxygen and tungsten on the surface at 1710 K, resulting in a work function of 4.37 eV; (iii) keeping the sample temperature at 1710 K, simple evacuation of the system has resulted in surface segregation of zirconium atoms to the surface to form a zirconium atomic layer on the top-most surface, reducing the work function to 2.7 eV. The results have revealed that this specific behavior of zirconium atoms at high temperature assures, with very good reproducibility, the highly stable performance and long service life of Zr---O/W(100)-emitters in practical use, even in a low vacuum of 10−6 Pa.  相似文献   
185.
转动系统的相对论性分析力学理论   总被引:20,自引:3,他引:17  
本文讨论了转动相对论力学理论,主要是建立转动系统的相对论性分析力学理论·构造转动系统的相对论性广义动能函数Tr=∑ni=1I0iΓi2(1-1-θ·2i/Γi2)和广义加速度能量函数Sr=12∑ni=1Ii(θ·i·θ¨i)2Γi2-θ·2i+θ¨2i,给出其Hamilton原理和三种不同形式的D′Alembert原理;对于完整约束系统,建立了转动系统的相对论性Lagrange方程、Nielsen方程、Appel方程和Hamilton正则方程;对于非完整约束系统,建立了转动系统的相对论性Routh方程、Чаплыгин方程、Nielsen方程和Appel方程;并给出转动系统的相对论性Noether守恒律  相似文献   
186.
Ge segregation during the growth of Si1 − xGex alloys (x = 5, 10, 20, and 40%) was studied using X-ray photoelectron spectroscopy. The alloys were grown in thicknesses up to 20.0 nm at 500°C to measure quantitatively the amount of segregated surface Ge. The length of alloy needed to reach steady-state growth edge was found to decrease with increasing alloy concentration (4.8, 2.8, 2.4, and 2.0 nm, respectively). It was found that each alloy had a complete monolayer of Ge on the surface and an increasing amount of segregated Ge in the second layer (20, 55, 80, and 95%, respectively) during steady-state growth. An increase in the temperature of alloy growth (400–750°C) resulted in an increase in the leading edge of alloy growth but did not change the amount of segregated Ge during steady-state growth. We propose that film stress is responsible for the amount of Ge segregation.  相似文献   
187.
Crystalline LiFePO4 has been synthesized using solid-state, spray pyrolysis, and wet chemical methods. The crystal parameters were obtained from Rietveld’s refinement methods of the X-ray diffraction patterns. A detailed investigation of the Fe valency carried out using Mössbauer spectroscopy at room temperature indicates that Fe is predominantly present in its bivalent state.  相似文献   
188.
We report on experiments that evaluate the potential of terahertz (THz) time-domain spectroscopy (TDS) for quality control of polymeric compounds. We investigate specimens out of a polyethylene compound with silver-coated titanium dioxide nanospheres and a glass-fiber reinforced epoxy composite. We further examine an industrial polymer product produced by injection molding. Our data demonstrates that THz imaging is a powerful tool for contactless quality control in the polymer industry.  相似文献   
189.
We have examined the magnetic properties of the heavy electron compounds YbAgGe and YbPtIn by 170Yb M?ssbauer spectroscopy down to 0.1 K, and the crystal field properties of YbAgGe by Perturbed Angular Correlations (PAC) measurements up to 900 K. In YbAgGe, we show that each of the two magnetically ordered phases below 0.8 K involves a specific incommensurate modulation of the Yb moment. An analysis of existing low temperature specific heat data suggests the persistence of fluctuations of the correlated Yb spins down to 0.1 K. The PAC data allow to discriminate among proposed Yb3+ crystal field level schemes. In YbPtIn, we show that the low temperature magnetic order phase has an antiferro-para structure, where zero moment Yb ions coexist with large moment ones, and that a 90° moment reorientation occurs at 1.4 K.  相似文献   
190.
We have investigated the mechanosynthesis of gadolinium and yttrium iron garnets by high-energy ball-milling of α-Fe2O3 and Gd2O3 or α-Fe2O3 and Y2O3, respectively, followed by short thermal annealings conducted at moderate temperatures. The samples were characterized by X-ray diffraction and Mössbauer spectroscopy, in order to determine the influence of the milling time and annealing conditions on the final products. For as-milled samples of each rare-earth system, the results revealed the formation of perovskite phases, in relative amounts that depend on the milling time. The formation of garnet phases was observed in as-annealed samples treated at 1000°C for 2 h or 1100°C for 3 h, i.e., at very modest annealing requirements when compared with ordinary solid-state-reaction processes performed without previous high-energy milling. Also, the occurrence was verified of a milling time for which the relative amount of garnet phases formed by annealing was maximized. This time depends on the rare-earth composing the garnet phase and on the annealing temperature.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号