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161.
The degradation of azobenzene (AO) by a gaseous plasma is reported. The plasma was generated in a localized zone between an electrolytic solution and a tip of an anode in contact with the surface of solution by means of contact glow discharge electrolysis. There is an optimum pH for the degradation of AO. Iron (II) had a remarkable catalytic action on it. Furthermore, the degradation followed the first‐order kinetic law. Some of the intermediate products of the degradation process were detected by HPLC. 相似文献
162.
163.
曾建尔 《核聚变与等离子体物理》1989,9(2):121-124
D_2辉光放电实验的目的旨在进一步了解辉光放电清除水的机制,弄清辉光放电清洗时,高本底H_2与质谱仪中离子源反应生成H_2影响质谱仪分析的情况。实验是在FY-I装置(异形截面环流器)上进行的,装置结构见文献[2]。实验安排与预试环上进行的实验大致相同。重水(D_2O)在相对净化的氢纯化器内电解后,生成D_2(氘)经压电晶体阀控制输入。 相似文献
164.
165.
Liquid-phase degradation of chlorobenzene (CB), induced by contact glow discharge electrolysis under various reaction conditions,
such as, the initial solution pH, current intensity, volume of solution and iron salts was investigated. Experimental results
indicated that, in the absence of catalysts, the depletion of CB followed first-order kinetics, where the observed value of
the first-order rate constant ‘k’ is directly proportional to the applied current intensity and inversely proportional to the solution volume. Initial solution
pH had little effect on the value of k. HPLC and IC analyses showed that the major intermediate products were chlorophenols, phenol, organic acids and chloride
ions. During the treatment, a lot of hydrogen peroxide was formed. Role of Fenton’s reaction was examined. A reaction pathway
is proposed based on the degradation kinetics and the distribution of intermediate products. 相似文献
166.
V. S. Burakov N. A. Savastenko N. V. Tarasenko E. A. Nevar 《Journal of Applied Spectroscopy》2008,75(3):394-401
Composite copper-containing carbon nanosized structures were synthesized in the plasma of a pulsed electrical discharge, initiated
between two graphite electrodes in an aqueous copper chloride solution. We studied the effect of laser radiation on the morphology
of the nanoparticles formed, whose properties we studied by optical absorption spectroscopy and transmission electron microscopy.
We discuss the mechanisms for nanoparticle formation in a discharge submerged in a liquid, and the possibilities for laser-induced
modification of the nanoparticles. We estimated the temperature of the nanoparticles when exposed to laser radiation pulses.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 3, pp. 372–378, May–June, 2008. 相似文献
167.
Oxidative Degradation of Aqueous Cresols Induced by Gaseous Plasma with Contact Glow Discharge Electrolysis 总被引:2,自引:0,他引:2
The oxidative degradation of cresols smoothly proceeded toward inorganic end products when a gaseous plasma generated by means
of dc glow discharge was sustained in contact with the surface of aqueous solution containing organic compounds. In order
to get mechanistic insight, the monohydroxylation products from each isomeric cresol were closely examined as primary intermediates
to reveal that the aromatic hydroxylation preferentially occurred at the position para to the hydroxyl group of each starting
material. It was also established that the degradation of cresols strictly followed the first-order rate law. On the basis
of the orientational analysis and the kinetical consideration including the effects of Fe ions added on the reaction rate,
it was concluded that hydroxyl radical, which might result from the homolytic cleavage of water molecules by the action of
plasma, was the most likely reagent responsible for the mineralization of cresols. 相似文献
168.
气体绝缘开关设备(GIS)绝缘缺陷引发的放电会导致SF6分解,分解产生的低氟硫化物与设备内的微量H2O和O2反应生成具有腐蚀性的物质,影响设备正常运行,因此,研究SF6分解机理对GIS的安全运行具有重要意义。由于部分分解物在采样过程中发生转化,因此,实现SF6分解物的原位检测对于研究SF6分解机理是十分必要的。采用飞秒激光引导高压放电实现了高压放电空间和时间的精确控制,并利用飞秒激光引导高压放电产生的空间分辨光谱实现了SF6分解物的原位测量。首先研究证明了飞秒激光不会引起SF6的分解;其次,利用飞秒激光产生的等离子体通道实现了放电空间和时间的精确控制;最后,发现分解物中包含由于高能电子碰撞直接或间接产生的大量S和F的离子和原子。研究证明了基于飞秒激光引导高压放电可以实现SF6分解物的原位检测,为开展高压放电下SF6分解机理研究提供了一种新的研究手段。 相似文献
169.
170.
M.Y. Pustylnik A.A. Pikalev A.V. Zobnin I.L. Semenov H.M. Thomas O.F. Petrov 《等离子体物理论文集》2021,61(10):e202100126
Low-pressure gas discharge plasmas are known to be strongly affected by the presence of small dust particles. This issue plays a role in the investigations of dust particle-forming plasmas, where the dust-induced instabilities may affect the properties of synthesized dust particles. Also, gas discharges with large amounts of microparticles are used in microgravity experiments, where strongly coupled subsystems of charged microparticles represent particle-resolved models of liquids and solids. In this field, deep understanding of dust–plasma interactions is required to construct the discharge configurations which would be able to model the desired generic condensed matter physics as well as, in the interpretation of experiments, to distinguish the plasma phenomena from the generic condensed matter physics phenomena. In this review, we address only physical aspects of dust–plasma interactions, that is, we always imply constant chemical composition of the plasma as well as constant size of the dust particles. We also restrict the review to two discharge types: dc discharge and capacitively coupled rf discharge. We describe the experimental methods used in the investigations of dust–plasma interactions and show the approaches to numerical modelling of the gas discharge plasmas with large amounts of dust. Starting from the basic physical principles governing the dust–plasma interactions, we discuss the state-of-the-art understanding of such complicated, discharge-type-specific phenomena as dust-induced stratification and transverse instability in a dc discharge or void formation and heartbeat instability in an rf discharge. 相似文献