人工光合作用反应中心的研究进展

本文对几种人工光合作用反应中心系统,做一个简单的综述,其中包括叶绿素和细菌叶绿素二聚体,卟啉二聚体,卟啉-苯醌共价键络合物以及其他合成中心。     

微柱分离中的激光诱导荧光检测

 激光诱导荧光检测 (LIFD)以其高的灵敏度和选择性而被广泛应用于微柱分离技术中。以检测池为轴线 ,概述了激光诱导荧光检测系统新进展及其应用。引用了 5 2篇文献     

化学反应的选择性和金属有机化学

本文是对旨在提高合成效率的化学反应选择性和金属有机化学关系的综述,按金属有机化合物的基元反应进行讨论。     

Biocatalysis and biorecognition in nonaqueous media. Some perspectives in analytical biochemistry

Biocatalysis and, to a lesser extent, biorecognition in non-aqueous media (including organic solvents as well as supercritical fluids and gases) constitute at present an exciting research area which has already demonstrated its biotechnological potential in numerous, varied applications. Less attention, however, has been paid to its analytical possibilities, even though many advantages have been postulated and a wide range of poorly water-soluble analytes are present in samples (or waste materials) from food and drink, petrochemical, pharmaceutical, military and other industries. The main approaches, developed in recent years to exploit the use of enzymes, antibodies or antibody mimics in water-restricted environments for analytical purposes, as well as possible future directions are briefly discussed.     

MnRe(CO)10: A review of the chemical and physical properties of a simple heterobimetallic non-bridged dimer

A review of the chemical and physical properties of MnRe(CO)₁₀ and its derivatives has been undertaken. This heterobimetallic complex is one of the simplest complexes known which contains a bond between two different metals and does not contain bridging groups. The review has revealed that high yield synthetic strategies are known for this complex and the synthetic strategies have bearing for the synthesis of other bimetallic complexes. Kinetic data suggest that information available on monometallic fragments can provide information on the reactivity trends expected for the dimer. However, the second metal is not a neutral spectator and provides a site forsecondary reactions eg for CO substitution. Data on the physical properties of the dimer are sparse and definitive statements ond _Mn-Re·v _Mn-Re, H_Mn-Re etc. cannot be made. This has significant implications for studies on related simple and complex dimer and cluster complexes.     

Love波免疫传感器在免疫分析中的研究

Love波免疫传感器是一种以免疫反应为识别方式的新型声表面波传感器。与其它压电声波免疫传感技术相比,水平剪切型表面波、高的压电晶体基频以及声波导层的存在使Love波免疫传感器在可用于气液两相检测的同时具有更高的灵敏度,从而可以成为免疫分析中的一种重要的工具。本文分别从Love波传感器的构造、原理、发展现状和以抗体作为探针在传感器表面的固定化方法两方面综述了Love波免疫传感器的研究进展。     

ICP-MS for elemental speciation studies

The use of inductively coupled plasma mass spectrometry (ICP-MS) coupled with separation techniques for the purpose of elemental speciation has recently gained a lot of attention. Much of this is due to ever improving separation capabilities of Chromatographic techniques, the high sensitivity of ICP-MS, and the continuing development of better interface techniques. Additionally, there is a growing awareness of the need to monitor various species of an analyte, rather than just total analyte concentrations, due to their often varying natures. For the sake of learning from different elemental speciation approaches, this review brings together some selected types of elemental speciation which have been recently seen in literature. These include separations using various forms of liquid chromatography, such as reversed phase, reversed phase ion pairing, micelle, ion exchange, and size exclusion. Elemental speciation employing gas Chromatographie separations and supercritical fluid separations are discussed as well as elemental speciation using capillary electrophoresis.     

毛细管电泳在手性分离中的应用及进展

本文评述了近年来毛细管电泳在手性分离中的应用及进展，介绍了毛细管电泳分离手性对映射的数学模型、五种不同的分离模式及机理、七种常用的手性选择性类型及其在药学、环境和生命科学中的应用、研究中需优化的操作参数及其发展方向。     

3-(噁唑-5-基)吲哚类天然产物生物活性及其衍生物的合成研究进展

3-(噁唑-5-基)吲哚类天然产物如Pimprinine,Streptochlorin等,广泛存在于海洋微生物中,因其具有多样的生物活性,在医药和农药领域中很有研究潜力.3-(噁唑-5-基)吲哚类天然产物的合成方法有很多研究报道,在吲哚结构上构建噁唑环是合成此类天然产物的关键.总结了已报道的3-(噁唑-5-基)吲哚类天然产物的生物活性,并对构建3-(噁唑-5-基)吲哚骨架的合成方法及部分主要反应机理进行了综述,探讨了3-(噁唑-5-基)吲哚类骨架作为一种优势活性结构在未来的应用前景.     

双偏振干涉测量技术在生物分析方面研究应用进展

双偏振干涉测量(dual-polarization interferometry,DPI)技术是2000年以后出现的一种灵敏、实时、无需标记的新型表面状态分析方法,它能够在亚秒尺度精确测量界面层厚度、密度和质量的绝对值.所以,DPI在固/液界面上蛋白质结构、功能表征,蛋白质之间或与其它分子间的相互作用研究,核酸固定化及杂交检测研究,模拟生物膜研究以及表面超微结构表征等方面都有着广泛的应用.本文介绍了DPI的测量原理和特点,着重评述了近年来DPI在生物分析方面的应用进展.