中国银行间拆借利率扩散模型的极大拟似然估计

本文用极大拟似然估计法估计了中国银行间市场七天拆借利率扩散模型的参数。并用自助法对众多不同的模型进行了广义拟似然比检验。结论表明:中国货币市场利率具有均值回复效应:利率敏感系数γ值为1.421265,对利率水平具有较高敏感性。     

孔梯度陶瓷纤维复合膜管的制备及特性

陶瓷过滤管具有孔隙率高、耐腐蚀、耐高温、机械强度高、便于清洗、使用寿命长等优点,是高温烟尘处理用的高效过滤元件.本文研制了一种具有梯度孔结构堇青石陶瓷纤维复合膜过滤元件,该过滤元件是由多孔支撑体、过渡层和分离膜层组成.其中支撑体、过渡层和分离层的气孔率分别为35～40;、50～60;和60～70;.文中主要分析了孔梯度陶瓷纤维复合膜管的材料结构和抗热震性能,同时对复合膜管进行含尘气体过滤的冷态模拟试验.对于烟气中粒径大于或等于0.1μm的颗粒,复合膜管的截留率达到99.8;以上.     

大非球面镜的郎奇检验灵敏度理论研究及仿真分析

为了研究等间距直线条光栅的周期及其他相关参数的变化对大非球面镜朗奇检验法的影响,提出了一种评估郎奇检验灵敏度大小的新方法。其检验灵敏度定义为一个光栅周期所能检测到的镜面偏差大小能力。在朗奇检验的几何原理基础上,利用光线追迹法讨论了镜面偏差与朗奇光栅周期之间的关系,并以此推导出检验灵敏度公式,计算了抛物面镜的朗奇检测灵敏度。分析结果表明,如果给定镜子的规格参数及检验光路,朗奇检验灵敏度分别随着光栅周期间隔和半通光口径的变大而减小。     

标准圆筒试验技术与数据处理方法研究

 对标准圆筒试验技术与数据处理方法进行了深入研究,在狭缝扫描实验中建立了新型、高效的照明技术、底片判读方法以及数据处理方法,得到了精度高、信息丰富的圆筒壁质点上的位移、速度、加速度和比动能结果。同时,通过VISAR技术直接测量了圆筒外表面径向膨胀速度-时间曲线,进而积分得到位移-时间曲线,与狭缝扫描结果相互印证和补充,进一步提高了测试可靠性。     

Chemical Composition and Antibacterial Activity of Lippia multiflora Moldenke Essential Oil from Different Regions of Angola

The purpose of the study was to determine the chemical composition and antibacterial activity of Lippia multiflora Moldenke essential oils (EOs) collected in different regions of Angola. Antibacterial activity was evaluated using the agar wells technique and vapour phase test. Analysis of the oils by GC/MS identified thirty-five components representing 67.5 to 100% of the total oils. Monoterpene hydrocarbons were the most prevalent compounds, followed by oxygenated monoterpenes. The content of the compounds varied according to the samples. The main components were Limonene, Piperitenone, Neral, Citral, Elemol, p-cymene, Transtagetone, and Artemisia ketone. Only one of the eleven samples contained Verbenone as the majority compound. In the vapour phase test, a single oil was the most effective against all the pathogens studied. The principal component analysis (PCA) and hierarchical cluster analysis (HCA) of components of the selected EOs and inhibition zone diameter values of agar wells technique allowed us to identify a variability between the plants from the two provinces, but also intraspecific variability between sub-groups within a population. Each group of essential oils constituted a chemotype responsible for their bacterial inhibition capacity. The results presented here suggest that Angolan Lippia multiflora Moldenke has antibacterial properties and could be a potential source of antimicrobial agents for the pharmaceutical and food industry.     

基于学科能力视角的江苏高考化学试题研究

以化学学科能力模型为依据,确定化学学科能力评价指标,并以此为基础,对2008-2020年江苏高考化学试题学科能力要求进行分析,得出江苏卷对于化学学科能力的考查特点及变化趋势,并提出了相关教学建议.     

P波段微波注入反相器模数转换电路的响应

利用设计的三反相器模数（A/D）转换电路,开展了P波段微波注入实验。采用眼图观测法对电路的线性响应进行了有效测量,推导了实验线路中微波注入效率公式,利用一种实时温度检测电路来验证芯片工作状态的稳定性,并利用统计检验的方法分析了不同芯片及电路板等对实验数据获取的影响,从而保证了实验的有效性和可信度。重点研究了注入微波的幅值、频率、脉宽及重复频率等参数对反相器正常工作的影响。实验结果表明:当注入微波信号脉宽大于70 ns时,电路信号在微波脉冲结束后,相邻脉冲脉宽变化10%的非线性干扰功率阈值,比使电路信号噪声容限降低50%的功率阈值大4~6 dB,电路信号脉宽变化30%的功率阈值比脉宽变化10%的大2~3 dB,在功率小于32 dBm的实验中得到的最大非线性干扰为脉宽变化约40%。非线性干扰阈值随注入微波信号脉宽变化明显,拐点为40~70 ns。注入微波的重复频率对微波干扰阈值影响很小。     

Amperometric biosensor based on reductive H2O2 detection using pentacyanoferrate-bound polymer for creatinine determination

Pentacyanoferrate-bound poly(1-vinylimidazole) (PVI[Fe(CN)₅]) was selected as a mediator for amperometric creatinine determination based on the reductive H₂O₂ detection. Creatinine amidohydrolase (CNH), creatine amidohydrolase (CRH), sarcosine oxidase (SOD), peroxidase (POD), and PVI[Fe(CN)₅] were crosslinked with poly(ethylene glycol) diglycidyl ether (PEGDGE) on a glassy carbon (GC) electrode for a creatinine biosensor fabrication. Reduction current was monitored at −0.1 V in the presence of creatinine and O₂. It is revealed that PVI[Fe(CN)₅] is suitable as a mediator for a bioelectrocatalytic reaction of POD, since PVI[Fe(CN)₅] neither reacts with reactants nor works as an electron acceptor of SOD. The amounts of PVI[Fe(CN)₅], PEGDGE, and enzymes were optimized toward creatinine detection. Nafion as a protecting film successfully prevented the enzyme layer from interferences. The detection limit and linear range in creatinine determination were 12 μM and 12–500 μM (R² = 0.993), respectively, and the sensitivity was 11 mA cm⁻² M⁻¹, which is applicable for urine creatinine tests. The results of the creatinine determination for four urine samples measured with this proposed method were compared with Jaffe method, and a good correlation was obtained between the results.     

A novel turn-on fluorescent probe for Hg2+ detection based on rhodamine B spirolactam derivative

ABSTRACT

In this work, a new turn-on fluorescent probe 1 for Hg²⁺ ions detection based on rhodamine B spirolactam was reported. Among tested metal ions, probe 1 shows high selectivity towards Hg²⁺ in the the mixture solution of methanol and 0.02 M HEPES buffer (V/V = 9:1, pH = 7.2). No absorption and emission band of probe 1 was observed in the range from 450 to 700 nm. While only addition of Hg²⁺ to probe 1 could lead to appearance of a new absorption band centered at 553 nm and a fluorescence emission band around 577 nm upon excitation at 520 nm. Moreover, it exhibits excellent linear relationship (R² = 0.9993) between fluorescence intensity at 577 nm and the concentration of Hg²⁺ from 1.6 to 32 μM. The sensing mechanism was proven to be spirolactam ring open induced by Hg²⁺ through ¹H NMR, MS, absorption and fluorescence spectra. In addition, probe 1 could detect Hg²⁺ in real water samples and on filter paper, which demonstrates its application in environment science.     

涡流发生器污垢特性实验台的设计

为了研究涡流发生器的污垢特性设计了一个能够在线监测温度、流量以及压差进而可以直接得到污垢热阻的实验台。通过验证实验、准确性分析与误差分析,验证了实验台设计精度在允许的误差范围内。示例实验结果表明实验台具有研究涡流发生器的污垢特性、压力特性以及换热特性的功能。