全文获取类型
收费全文 | 16911篇 |
免费 | 2550篇 |
国内免费 | 1416篇 |
专业分类
化学 | 6955篇 |
晶体学 | 193篇 |
力学 | 1021篇 |
综合类 | 69篇 |
数学 | 1098篇 |
物理学 | 11541篇 |
出版年
2024年 | 14篇 |
2023年 | 125篇 |
2022年 | 340篇 |
2021年 | 325篇 |
2020年 | 380篇 |
2019年 | 397篇 |
2018年 | 402篇 |
2017年 | 478篇 |
2016年 | 611篇 |
2015年 | 551篇 |
2014年 | 810篇 |
2013年 | 1429篇 |
2012年 | 973篇 |
2011年 | 1211篇 |
2010年 | 870篇 |
2009年 | 1161篇 |
2008年 | 1145篇 |
2007年 | 1292篇 |
2006年 | 1086篇 |
2005年 | 896篇 |
2004年 | 786篇 |
2003年 | 676篇 |
2002年 | 693篇 |
2001年 | 533篇 |
2000年 | 553篇 |
1999年 | 431篇 |
1998年 | 393篇 |
1997年 | 285篇 |
1996年 | 283篇 |
1995年 | 266篇 |
1994年 | 211篇 |
1993年 | 203篇 |
1992年 | 175篇 |
1991年 | 132篇 |
1990年 | 94篇 |
1989年 | 78篇 |
1988年 | 93篇 |
1987年 | 64篇 |
1986年 | 55篇 |
1985年 | 72篇 |
1984年 | 67篇 |
1983年 | 27篇 |
1982年 | 48篇 |
1981年 | 38篇 |
1980年 | 21篇 |
1979年 | 17篇 |
1978年 | 19篇 |
1977年 | 11篇 |
1976年 | 17篇 |
1973年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 250 毫秒
81.
Mark E. Filipkowski Edwin E. Hach III Michael Offenbacker 《Journal of magnetism and magnetic materials》2006
We show, via a straightforward calculation, that it is feasible to detect nuclear spin echoes in a ferromagnetic thin film by electrical means. The detection scheme is based on the deflection of the electronic magnetization when the nuclear magnetization reforms during an echo. This deflection is observed as a time-dependent magnetoresistive signal. 相似文献
82.
Rare earths exhibit complex magnetic phase diagrams resulting from the competition between various contributions to the magnetic
energy: exchange, anisotropy and magnetostriction. The epitaxy of a rare-earth film on a substrate induces (i) a clamping
to the substrate and (ii) pseudomorphic strains. Both these effects are shown to lead to modifications of the magnetic properties
in (0 0 1)Dy, (0 0 1)Tb and (1 1 0)Eu films. In Dy and Tb films, spectacular variations of the Curie temperature have been
evidenced. Additionally, Tb films exhibit a new large wavelength magnetic modulation. In Eu films, one of the helical magnetic
domains disappears at low temperature whereas the propagation vectors of the other helices are tilted. The link between structural
and magnetic properties is underlined via magnetoelastic models. Moreover, molecular beam epitaxy permits the growth of Sm
in a metastable dhcp phase. The magnetic structure of dhcp Sm has been elucidated for the first time. In this review, neutron
scattering is shown to be a powerful technique to reveal the magnetic structures of rare-earth films. 相似文献
83.
Francois NICOLEAU 《数学学报(英文版)》2006,22(5):1485-1492
We consider a pair of Hamiltonians (H, H0) on L2(R^n), where H0=p^2 -x^2 is a SchrSdinger operator with a repulsive potential, and H = H0+V(x). We show that, under suitable assumptions on the decay of the electric potential, V is uniquely determined by the high energy limit of the scattering operator. 相似文献
84.
We demonstrate the potential of femtosecond two-color pulse interferometry for in vitro optical glucose monitoring, by dispersion of the group refractive index in a glucose solution sample with respect to a red-color
light and a blue-color light. By comparison with femtosecond one-color pulse interferometry, the basic performance of the
present system with regard to sensitivity, quantitativeness, and tolerance to surrounding disturbances, is evaluated. The
resulting accuracy and precision of glucose determination are 77 and 118mg/dl for 10-mm-sample-thickness, respectively. This
near-common-path configuration of the two-color pulse light provides good stability to fluctuations of sample temperature,
which is important in clinical applications. Considering the performance of femtosecond two-color pulse interferometry as
an optical glucose sensor, a suitable measurement site for in vivo optical glucose monitoring is discussed. 相似文献
85.
用硼氢化钠作还原剂,制备出两种相对稳定的含银纳米颗粒的水溶胶,用透射电镜(TEM)和光学吸收谱对这些颗粒进行了表征.当被还原的银离子较少时,所形成的银纳米颗粒较小,吸收峰呈现二极等离子体共振吸收峰.当被还原的银离子较多时,银纳米颗粒尺寸变大,并出现二极和四极共振吸收峰.在Ag纳米颗粒形成后,对其溶液稀释,发现其峰形保持不变,而峰位会出现红移,最大红移量可达到10 nm.透射电镜研究表明,低浓度溶胶中的Ag纳米颗粒尺寸较为均匀,平均直径12 nm.高浓度溶胶中的纳米颗粒尺寸呈双尺寸分布特点,少量颗粒直径小于14 nm,大部分颗粒直径大于20 nm. 相似文献
86.
I. Antoniou M. Gadella J. Mateo G.P. Pronko 《International Journal of Theoretical Physics》2003,42(10):2389-2402
Through two examples: the Friedrichs model and a particular case of central potential scattering, we illustrate the way of constructing Gamow vectors. 相似文献
87.
Influence of annealing and chain defects on the melting behaviour of poly(vinylidene fluoride) 总被引:2,自引:0,他引:2
C. Marega 《European Polymer Journal》2003,39(8):1713-1720
The melting behaviour of poly(vinylidene fluoride) (PVDF) was investigated by differential scanning calorimetry (DSC) and small- and wide-angle X-ray scattering in order to study the influence of the chain defects content and of the temperature of annealing on the crystallization and melting behaviour.All the DSC scans show a double endotherm and the analysis of the data suggests that the low temperature endotherm is due to the melting of a population of thin lamellae, whose thickness increases during the annealing, but a high content of chain defects prevents the lamellar thickening and the main effect in this case is the crystallization of thin lamellae from a portion of polymer which did not crystallize during the quenching from the melt. Furthermore, the two melting endotherms, which are observed, can be partially ascribed to a melting-recrystallization process.Furthermore, stepwise isothermal cooling was performed in a differential scanning calorimeter followed by melting scans of fractionated PVDF samples to point out the possible presence of a series of endothermic peaks. 相似文献
88.
《Magnetic resonance in chemistry : MRC》2003,41(8):585-588
A novel, radical responsive MRI contrast agent based on a gadolinium chelate conjugated to a liposome through a disulfide linker was synthesized, with the aim of pursuing the in vivo mapping of radicals. The liposome was prepared by incorporating a thiol‐activated phospholipid, which was subsequently reacted with a gadolinium chelate containing a free thiol group. The long reorientational motion of the supramolecular adduct endows the paramagnetic agent with a relaxivity significantly higher than that of the free complex. The disulfide bond represents a radical‐sensitive moiety and a large decrease in contrast efficacy (T1 relaxivity) is shown upon its cleavage. A preliminary assessment of the system was made by means of in vitro gamma‐irradiation and thiol–disulfide bond exchange with dithiothreitol. Both methods showed a clear dose‐dependent decrease in T1‐relaxivity. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
89.
We consider some types of packet discretization for continuous spectra in quantum scattering problems. As we previously showed, this discretization leads to a convenient finite-dimensional (i.e., matrix) approximation for integral operators in the scattering theory and allows reducing the solution of singular integral equations connected with the scattering theory to some suitable purely algebraic equations on an analytic basis. All singularities are explicitly singled out. Our primary emphasis is on realizing the method practically. 相似文献
90.
Electron paramagnetic resonance (EPR) investigations has been carried out on the new family of molybdenum doped vanadium sesquioxides (V1−xMox)2−δO3. The oxidation effects were monitored from the rate of paramagnetic V4+ created when the sample is exposed to the air. The effects of the oxidation time, sample temperature, and annealing at 1000 °C under a diluted hydrogen atmosphere on the EPR signal features are analyzed. The V4+ concentration in the oxidized samples is determined and the relaxation effects driven by the conduction electrons are pointed out from the thermal behaviour of the EPR line features. EPR spectra of all the oxidized samples also reveal a small ferromagnetic contribution strongly correlated with the V4+ content. 相似文献