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991.
José Angel Brito Helena Teruel Stéphane Massou Montserrat Gómez 《Magnetic resonance in chemistry : MRC》2009,47(7):573-577
Oxomolybdenum(VI) complexes containing diverse ligands from an electronic and topological point of view have been analysed by means of 95Mo NMR in solution with the purpose of using this technique as a tool to study their coordination chemistry and reactivity. The relationship between the electronic density on the metal tuned by the electron‐donor ability of the coordinated ligands and the 95Mo chemical shift has been proved for mono‐ and bimetallic complexes showing a hexa‐ or hepta‐coordination around the metal centre. The different origins of the signal broadening (associated either to the symmetry of the metallic polyhedron or to the presence of isomers or to the ligand de‐coordination) have been also considered to rationalise the obtained data. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
992.
Markus M. Hoffmann Hanna S. Sobstyl Vincent A. Badali 《Magnetic resonance in chemistry : MRC》2009,47(7):593-600
A number of suppression pulse sequences including Excitation Sculpting and WATERGATE were incorporated into the standard Carr‐Purcell‐Meiboom‐Gill (CPMG) program for T2 measurement and experimentally evaluated. The chosen suppression schemes were of varying complexity encompassing pulse program elements, such as presaturation, gradients, and selective pulses, which are typically utilized for solvent suppression. The quality of the spectral data and the accuracy of T2 measurements of the investigated suppression schemes were evaluated using three aqueous samples with increasing proton content in the water solvent, i.e. by volume 100% D2O, 80/20% D2O/H2O, and 20/80% D2O/H2O. For signals removed from the water signal, the T2 values were generally very consistent between all pulse sequences tested. T2 measurements can be unreliable for signals too close to the water signal such that they are significantly suppressed as well. Their intensity may actually grow initially through cross relaxation that transfers magnetization back to the solute signal. In turn, this relaxation phenomenon can be exploited to improve the spectral quality of conventional solvent suppression schemes. In favorable cases, even signals that are completely masked by the water signal can be recovered by adding a carefully chosen number of spin echoes with optimized evolution time to conventional water suppression pulse programs, such as Excitation Sculpting or WATERGATE. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
993.
994.
Sônia Cristina Poltroniere Kelly Cristina Poldi Franklina Maria Bragion Toledo Marcos Nereu Arenales 《Annals of Operations Research》2008,157(1):91-104
An important production programming problem arises in paper industries coupling multiple machine scheduling with cutting stocks.
Concerning machine scheduling: how can the production of the quantity of large rolls of paper of different types be determined.
These rolls are cut to meet demand of items. Scheduling that minimizes setups and production costs may produce rolls which
may increase waste in the cutting process. On the other hand, the best number of rolls in the point of view of minimizing
waste may lead to high setup costs. In this paper, coupled modeling and heuristic methods are proposed. Computational experiments
are presented. 相似文献
995.
J. Betzabe Gonzlez‐campos Evgen Prokhorov Gabriel Luna‐Brcenas A. Mendoza Galvn Isaac C. Sanchez Sergio M. Nuo Donlucas B. Garcia‐Gaitan Yuriy Kovalenko 《Journal of Polymer Science.Polymer Physics》2009,47(9):932-943
Relaxations in chitin have been investigated in the temperature range 298–523 K using impedance spectroscopy in the frequency range 10−1–108 Hz. The objective was to detect a glass‐transition temperature for this naturally occurring, semicrystalline polysaccharide. The impedance study was complemented with X‐ray diffraction, thermogravimetric, and differential scanning calorimetry measurements. Preliminary impedance data treatment includes the subtraction of the dc conductivity contribution, the exclusion of contact and interfacial polarization effects, and obtaining a condition of minimum moisture content for further analysis. When all these aspects are taken into account, two relaxations are clearly revealed in the impedance data. For the first time, evidence is presented for a relaxation process, which exhibits a non‐Arrhenius temperature dependence, in dry α‐chitin (∼0.1% moisture content), and likely represents the primary α‐relaxation. This evidence suggests a glass transition temperature for chitin of 335 ± 10 K estimated on the basis of the temperature dependence of the conductivity and of the relaxation time. A second relaxation in dry α‐chitin, not previously reported in the literature, is observed from 353 K to the onset of thermal degradation (∼483 K) and is identified as the σ‐relaxation often associated with proton mobility. It exhibits a normal Arrhenius‐type temperature dependence with activation energy of 113 ± 3 kJ/mol. The latter has not been previously reported in the literature. A high frequency secondary β‐relaxation is also observed with Arrhenius activation energy of 45 ± 1 kJ/mol. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 932–943, 2009 相似文献
996.
曲世亨 《广东微量元素科学》2001,8(3):50-52
阐述了一例胃底溃疡型腺癌伴周边器官淋巴组织广泛转移患者,行“贲门MT术”姑息治疗后,经九个月大剂量多种微量元素制剂补充达到很好的临床效果。 相似文献
997.
Time-resolved moderated luminescence of aromatic ketones (benzophenone, aceptophenone) in the presence of neutral and reactive
hydrogeneous foreign gases (ethylene, pentane, triethylamine) is investigated. It is shown that the addition of hydrogeneous
foreign gases leads to strong quenching of the triplet molecules of aromatic ketones. Effectivenesses of such bimolecular
processes as the collision detachment of a hydrogen atom and establishment of vibrational and thermal equilibrium are compared.
It is concluded that the vibrational degrees of freedom of the acceptors, the aromatic ketones, are inactive in the photochemical
process of collision detachment of a hydrogen atom that takes place after the establishment of vibrational equilibrium.
Institute of Molecular and Atomic Physics of the National Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072,
Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 1, pp. 73–77, January–February, 1999. 相似文献
998.
O. Carja 《Journal of Optimization Theory and Applications》2000,105(2):285-297
The present paper is concerned with the study of the Hamilton–Jacobi–Bellman equation for the time optimal control problem associated with infinite-dimensional linear control systems from the point of view of continuous contingent solutions. 相似文献
999.
We are interested in the problem of scheduling orders for different product types in a facility with a number of machines
in parallel. Each order asks for certain amounts of various different product types which can be produced concurrently. Each
product type can be produced on a subset of the machines. Two extreme cases of machine environments are of interest. In the
first case, each product type can be produced on one and only one machine which is dedicated to that product type. In the
second case, all machines are identical and flexible; each product type can be produced by any one of the machines. Moreover,
when a machine in this case switches over from one product type to another, no setup is required. Each order has a release
date and a weight. Preemptions are not allowed. The objective is minimizing the total weighted completion time of the orders.
Even when all orders are available at time 0, both types of machine environments have been shown to be NP-hard for any fixed
number (≥2) of machines. This paper focuses on the design and analysis of approximation algorithms for these two machine environments.
We also present empirical comparisons of the various algorithms. The conclusions from the empirical analyses provide insights
into the trade-offs with regard to solution quality, speed, and memory space.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users.
This research is supported by the National Science Foundation through grants DMI-0300156 and DMI-0245603. 相似文献
1000.
使用MTV模型与Morkowitz证券组合选择模型的投资决策系统 总被引:1,自引:0,他引:1
利用期望和方差的秩系数法、MTV模型、Morkowitz证券组合选择模型构造了一实用的投资决策系统. 相似文献