Modeling and Performance Optimization of an Irreversible Two-Stage Combined Thermal Brownian Heat Engine

Based on finite time thermodynamics, an irreversible combined thermal Brownian heat engine model is established in this paper. The model consists of two thermal Brownian heat engines which are operating in tandem with thermal contact with three heat reservoirs. The rates of heat transfer are finite between the heat engine and the reservoir. Considering the heat leakage and the losses caused by kinetic energy change of particles, the formulas of steady current, power output and efficiency are derived. The power output and efficiency of combined heat engine are smaller than that of single heat engine operating between reservoirs with same temperatures. When the potential filed is free from external load, the effects of asymmetry of the potential, barrier height and heat leakage on the performance of the combined heat engine are analyzed. When the potential field is free from external load, the effects of basic design parameters on the performance of the combined heat engine are analyzed. The optimal power and efficiency are obtained by optimizing the barrier heights of two heat engines. The optimal working regions are obtained. There is optimal temperature ratio which maximize the overall power output or efficiency. When the potential filed is subjected to external load, effect of external load is analyzed. The steady current decreases versus external load; the power output and efficiency are monotonically increasing versus external load.     

Comparison of ultrasound and microwave assisted extraction of diosgenin from Trigonella foenum graceum seed

From the recent market trend, there is a huge demand for the bioactive compounds from various food matrices that could be capable enough to combat the emerging health effects in day-to-day life. Fenugreek is a well-known spice from ancient times for its medicinal and health benefits. In the present study, two methods of green extraction microwave (MAE) and ultrasound (UAE) assisted were studied in regard of extraction of fenugreek diosgenin. In this study, solvent type (acetone, ethanol, hexane and petroleum ether), solvent concentration (40, 60, 80 and 100%) and treatment time (1.5, 3.0, 4.5 and 6.0 min and 30, 40, 50 and 60 min for MAE and UAE method respectively) was varied to observe the effect of these parameters over extract yield and diosgenin content. The results of this study revealed that treatment time, type of solvent and its concentration and method adopted for extraction of diosgenin has significant effect. In relation with better yield extract and diosgenin content, the yield of fenugreek seed extract was 7.83% with MAE and 21.48% with UAE of fenugreek seed powder at 80% ethanol concentration at 6 and 60 min respectively. The content of diosgenin was observed in fenugreek seed powder extract was 35.50 mg/100 g in MAE and 40.37 mg/100 g in UAE with 80% ethanol concentration at 6 and 60 min respectively. The overall range of yield of fenugreek extract was varied from 1.04% to 32.48% and diosgenin content was 15.82 mg/100 g to 40.37 mg/100 g of fenugreek seed powder including both extraction methods. This study revealed that UAE would impose better ways for preparing fenugreek extract and observing diosgenin content from fenugreek seeds.     

Modeling of cascaded high isolation bidirectional amplification in long-distance fiber-optic time and frequency synchronization system

We propose a physical model of estimating noise and asymmetry brought by high isolation Bi-directional erbiumdoped fiber amplifiers(Bi-EDFAs), no spontaneous lasing even with high gain, in longdistance fiber-optic time and frequency(T/F) synchronization system. It is found that the Rayleigh scattering noise can be suppressed due to the high isolation design, but the amplified spontaneous emission(ASE) noise generated by the high isolation Bi-EDFA and the bidirectional asymmetry of the transmission link caused by the high isolation Bi-EDFA will deteriorate the stability of the system.The calculated results show that under the influence of ASE noise, the frequency instability of a 1200 km system composed of 15 high isolation Bi-EDFAs is 1.773 × 10-13/1 s. And the instability caused by asymmetry is 2.6064 × 10-16/30000–35000 s if the total asymmetric length of the bidirectional link length is 30 m. The intensity noises originating from the laser and detector, the transfer delay fluctuations caused by the variation in ambient temperature and the jitter in laser output wavelength are also studied. The experiment composed of three high isolation Bi-EDFAs is done to confirm the theoretical analysis. In summary, the paper shows that the short-term instability of the T/F synchronization system composed of high isolation Bi-EDFAs is limited by the accumulation of ASE noise of amplifiers and the laser frequency drift, while the long-term instability is limited by the periodic variation in ambient temperature and the asymmetry of the amplifiers.The research results are useful for pointing out the direction to improve the stability of the fiber-optic T/F synchronization system.     

Exciton emission dynamics in single InAs/GaAs quantum dots due to the existence of plasmon-field-induced metastable states in the wetting layer

A very long lifetime exciton emission with non-single exponential decay characteristics has been reported for single InA-s/GaAs quantum dot(QD) samples,in which there exists a long-lived metastable state in the wetting layer(WL)through radiative field coupling between the exciton emissions in the WL and the dipole field of metal islands.In this article we have proposed a new three-level model to simulate the exciton emission decay curve.In this model,assuming that the excitons in a metastable state will diffuse and be trapped by QDs,and then emit fluorescence in QDs,a stretchedlike exponential decay formula is derived as I(t)=At~(β-1)e~(-(rt)β),which can describe well the long lifetime decay curve with an analytical expression of average lifetime     

基于1085 km实地光纤链路的双波长光纤时间同步研究

在长距离高精度光纤时间同步系统中,为了减少后向反射光与光纤色散对传输精度的影响,本文在双波长光纤时间同步传输方法之上,提出了一种具有色散误差修正功能的双波长光纤时间同步传输方法.以自行研制的工程样机在长度约为800 km的实验室光纤链路上和1085 km的实地光纤链路上进行了实验测试,也是国内首次实现千公里级实地光纤时间同步传输.在实验室光纤链路上,测得传输链路色散补偿后的色散时延误差为10 ps,时间同步标准差为5.7 ps,稳定度为1.12 ps@105 s,不确定度为18.4 ps.在实地光纤链路上,测得传输链路色散补偿后的色散时延误差为60 ps,时间同步标准差为18 ps,稳定度为5.4 ps@4×10⁴ s,不确定度为63.5 ps.     

Transition to chaos in lid-driven square cavity flow

To date, there are very few studies on the transition beyond second Hopf bifurcation in a lid-driven square cavity, due to the difficulties in theoretical analysis and numerical simulations. In this paper, we study the characteristics of the third Hopf bifurcation in a driven square cavity by applying a consistent fourth-order compact finite difference scheme rectently developed by us. We numerically identify the critical Reynolds number of the third Hopf bifurcation located in the interval of (13944.7021,13946.5333) by the method of bisection. Through Fourier analysis, it is discovered that the flow becomes chaotic with a characteristic of period-doubling bifurcation when the Reynolds number is beyond the third bifurcation critical interval. Nonlinear time series analysis further ascertains the flow chaotic behaviors via the phase diagram, Kolmogorov entropy and maximal Lyapunov exponent. The phase diagram changes interestingly from a closed curve with self-intersection to an unclosed curve and the attractor eventually becomes strange when the flow becomes chaotic.     

原位低场核磁共振弛豫法定量监测光催化Cr(Ⅵ)还原反应

本文利用原位低场核磁共振（LF-NMR）技术在真实固液反应环境中对光催化还原Cr（Ⅵ）反应进行了定量研究,并对Ag纳米颗粒负载量不同的Ag担载石墨相氮化碳复合光催化剂（Ag/g-C₃N₄）在可见光照射下催化Cr（Ⅵ）还原为Cr（Ⅲ）的性能进行了研究.研究发现,Ag纳米颗粒负载（负载量分别为1 wt.%、2 wt.%、5 wt.%和10 wt.%）可以有效提高g-C₃N₄的光催化性能;且负载量为5 wt.%时光催化性能最优,为无Ag负载的g-C₃N₄的4倍.此外,本文还通过横向弛豫时间（T₂）定量分析了反应体系中顺磁性Cr（Ⅲ）离子的浓度,证实了采用LF-NMR弛豫法评价光催化Cr（Ⅵ）还原反应性能的可行性.     

Global X2A′ potential energy surface of Li2H and quantum dynamics of H + Li2 (X1Σg+) → Li + LiH (X1Σ+) reaction

A global potential energy surface (PES) for the electronic ground state of Li₂H system is constructed over a large configuration space. About 30 000 ab initio energy points have been calculated by MRCI‐F12 method with aug‐cc‐pVTZ basis set. The neural network method is applied to fit the PES and the root mean square error of the current PES is only 1.296 meV. The reaction dynamics of the title reaction has been carried out by employing time‐dependent wave packet approach with second order split operator on the new PES. The reaction probability, integral cross section and thermal rate constant are obtained from the dynamics calculation. In most of the collision energy regions, the integral cross sections are in well agreement with the results reported by Gao et al. The rate constant calculated from the new PES increases in the temperature range of present investigation.     

Dielectric relaxation of Tripropylene glycol–water mixture using time domain reflectometry

The complex permittivity spectra of tripropylene glycol and water solutions have been obtained by time domain reflectometry (TDR) technique in the frequency range from 10 MHz to 30 GHz and the temperature range 20°C–05°C. The dielectric relaxation parameters such as static dielectric constant and relaxation time were obtained by using the non-linear least square fit method. The intermolecular hydrogen bonding of tripropylene glycol–water has been discussed using the Kirkwood correlation factor and thermodynamic parameters. The activation energy decreases with increase in water content in the mixture as expected in the Arrhenius behaviour. The dielectric constant for mixtures has been fitted to the Bruggeman mixture formula in the non-linear case.