1-氨基-1-肼基-2,2-二硝基乙烯（AHDNE）的非等温分解动力学，比热容和绝热至爆时间研究

利用DSC和TG/DTG法研究了1-氨基-1-肼基-2,2-二硝基乙烯（AHDNE）热分解行为及分解动力学,第一热分解过程的动力学方程为： ,其热爆炸临界温度为98.16 ºC。同时,利用微量热法测定了AHDNE的比热容,298.15K时的标准摩尔比热容为211.86 J•mol-1•K-1。计算得到了AHDNE的绝热至爆时间为59.21 s。AHDNE是不稳定的,其热稳定性远低于母体化合物FOX-7。     

Analysis of phenolic choline esters from seeds of Arabidopsis thaliana and Brassica napus by capillary liquid chromatography/electrospray‐ tandem mass spectrometry

Total phenolic choline ester fractions prepared from seeds of Arabidopsis thaliana and Brassica napus were analyzed by capillary LC/ESI‐QTOF‐MS and direct infusion ESI‐FTICR‐MS. In addition to the dominating sinapoylcholine, 30 phenolic choline esters could be identified based on accurate mass measurements, interpretation of collision‐induced dissociation (CID) mass spectra, and synthesis of selected representatives. The compounds identified so far include substituted hydroxycinnamoyl‐ and hydroxybenzoylcholines, respective monohexosides as well as oxidative coupling products of phenolic choline esters and monolignols. Phenolic choline esters are well separable by reversed‐phase liquid chromatography and sensitively detectable using electrospray ionization mass spectrometry in positive ion mode. CID mass spectra obtained from molecular ions facilitate the characterization of both the type and substitution pattern of such compounds. Therefore, LC/ESI‐MS/MS represents a valuable tool for comprehensive qualitative and quantitative analysis of this compound class. Copyright © 2008 John Wiley & Sons, Ltd.     

The pockels coefficient of new polymers for nonlinear optics and its time dependence after poling,compared with dielectric measurements

Epoxy polymers with donor–acceptor type side groups were synthesized for application in nonlinear optics. The stability of the Pockels coefficient was measured in thin films after poling. The relaxation times and their temperature dependence seem to be correlated with dielectric measurements. Guest–host systems (polystyrene and polymethylmethacrylate with dimethylaminonitrostilbene) were investigated for comparison.     

Polystyrene prepared by reactive extrusion: kinetics and effect of processing parameters

The conversion and residence time were investigated during the bulk polymerization of styrene in a twin screw extruder. It was found that polymerization mainly occurred in the zone between 400 and 1000 mm along the screw axis in the extruder, corresponding to the residence time of the reactants ranging from 1 to 4 min in the extruder. Furthermore, the processing conditions (feed rate, screw rotation rate) and average molecular weight of the polymer have a great effect on the residence time. Based on dimensionless analysis, a model of the residence time has been built‐up, which has been confirmed by the results of realistic measurements. A kinetic model of the polymerization has also been established under the assumption that the screw extruder can be regarded as an ideal plug flow reactor. Copyright © 2004 John Wiley & Sons, Ltd.     

WDM环形网络保护时间评估与优化分析

本文用逻辑等效方法分析了使用1:1保护配置的WDM环行网络的保护倒换规程,并且对需要信令协调的WDM环行网络的保护时间进行了分析,得到了保护时间的表达式.在分析各种因素对保护时间影响的基础上,提出了优化的思路.最后还给出了环行网络的保护倒换时序和实例.     

Low frequency dielectric spectroscopy of the Peierls-Mott insulating state in the deuterated copper-DCNQI systems

We report a detailed characterization of an unique 3-fold commensurate insulating state in single crystals of the organic – inorganic d hybrid Cu(DMe-DCNQI)₂ systems with deuterated and partially deuterated DCNQI ring, by means of low-frequency dielectric spectroscopy. A broad relaxation mode of strength centred at kHz is observed in the hysteresis temperature region in which the insulating phase coexists with metallic islands. At lower temperatures, outside the nucleation range, the relaxation narrows, approaching a Debye-like form for an overdamped response of a system with a single degree of freedom. Both, the relaxation strength and the mean relaxation time () are much larger than that expected for single-particle excitations. These features suggest the origin of the dielectric relaxation as an intrinsic property of the N = 3 charge density wave state. Received 1 December 1999 and Received in final form 5 April 2000     

Proper-Time Classical Electrodynamics

We construct a generalization of Maxwell's equations associated with the proper-time of the source which accounts for radiation reaction without any assumptions concerning the nature of the source. The theory leads to a new invariance group, related to the Lorentz group, which leaves the proper-time of the source fixed for all observers.     

连续动力系统时间序列的非线性检验

用相位随机化的替代数据方法，研究了连续混沌动力系统时间序列的非线性检验判定.研究发现，在不同的采样情况下，混沌时间序列的非线性特性检验有所差异，尤其对于过采样时间序列，往往会出现虚假的判断结果.针对过采样时间序列，最好采用能够反映非线性特征的参数，作为检验统计量进行检验判断. 关键词： 替代数据 关联维数 连续时间序列 非线性检验     

M-TIMES SECANT-LIKE MULTI-PROJCTION METHOD FOR SPARSE MINIMIZATION PROBLEM

M-TIMES SECANT-LIKE MULTI-PROJCTION METHOD FOR SPARSE MINIMIZATION PROBLEM@林正华 @宋岱才 @赵立芹~~     

时间尺度上Herglotz变分原理及其Noether定理

Herglotz变分原理的作用量是由微分方程定义的,不仅可以描述所有经典变分原理能够描述的动力学过程,还可以对经典变分原理不能适用的非保守系统或耗散系统进行变分描述．时间尺度上微积分理论提供了一种可同时研究离散系统和连续系统的有效方法．本文结合Herglotz变分原理和时间尺度微积分理论来研究时间尺度上的Herglotz变分原理及其Noether定理．首先,给出时间尺度上Lagrange系统的Herglotz变分原理．其次,根据Herglotz变分原理和Dubois-Reymond引理,推导出时间尺度上Lagrange系统的Herglotz变分问题的运动微分方程．再次,基于时间尺度上Hamilton-Herglotz作用量在群的无限小变换下的不变性,给出Noether对称性的定义并导出其Noether等式．最后,建立了时间尺度上Lagrange系统的Herglotz变分问题的Noether定理,给出了连续和离散两种情况下基于Herglotz变分问题的Noether守恒量．文末举例说明结果的应用．