全文获取类型
收费全文 | 1512篇 |
免费 | 201篇 |
国内免费 | 153篇 |
专业分类
化学 | 494篇 |
晶体学 | 5篇 |
力学 | 194篇 |
综合类 | 29篇 |
数学 | 599篇 |
物理学 | 545篇 |
出版年
2024年 | 2篇 |
2023年 | 18篇 |
2022年 | 27篇 |
2021年 | 35篇 |
2020年 | 32篇 |
2019年 | 43篇 |
2018年 | 38篇 |
2017年 | 45篇 |
2016年 | 37篇 |
2015年 | 38篇 |
2014年 | 77篇 |
2013年 | 91篇 |
2012年 | 91篇 |
2011年 | 94篇 |
2010年 | 78篇 |
2009年 | 77篇 |
2008年 | 74篇 |
2007年 | 93篇 |
2006年 | 85篇 |
2005年 | 81篇 |
2004年 | 63篇 |
2003年 | 84篇 |
2002年 | 78篇 |
2001年 | 53篇 |
2000年 | 60篇 |
1999年 | 60篇 |
1998年 | 46篇 |
1997年 | 41篇 |
1996年 | 33篇 |
1995年 | 28篇 |
1994年 | 26篇 |
1993年 | 22篇 |
1992年 | 18篇 |
1991年 | 17篇 |
1990年 | 9篇 |
1989年 | 13篇 |
1988年 | 8篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 5篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1866条查询结果,搜索用时 46 毫秒
171.
Hansen Alex Roux Stéphane Roux Aharony Amnon Feder Jens Jøssang Torstein Hardy H. H. 《Transport in Porous Media》1997,29(3):247-279
We present a spatial renormalization group algorithm to handle immiscibletwo-phase flow in heterogeneous porous media. We call this algorithmFRACTAM-R, where FRACTAM is an acronym for Fast Renormalization Algorithmfor Correlated Transport in Anisotropic Media, and the R stands for relativepermeability. Originally, FRACTAM was an approximate iterative process thatreplaces the L × L lattice of grid blocks, representing the reservoir,by a (L/2) × (L/2) one. In fact, FRACTAM replaces the original L× L lattice by a hierarchical (fractal) lattice, in such a way thatfinding the solution of the two-phase flow equations becomes trivial. Thistriviality translates in practice into computer efficiency. For N=L ×L grid blocks we find that the computer time necessary to calculatefractional flow F(t) and pressure P(t) as a function of time scales as N1.7 for FRACTAM-R. This should be contrasted with thecomputational time of a conventional grid simulator N2.3. The solution we find in this way is an accurateapproximation to the direct solution of the original problem. 相似文献
172.
The excess speed of sound, excess molar volume and excess molar isentropic compressibility of 52 binary mixtures containing Ionic Liquids at T = 298.15 K were calculated using selected literature speed of sound and density data. The second components were alcohols: methanol, or ethanol, or 1-propanol, or 2-propanol, or 1-butanol or other solvents: acetone, acetonitrile, tetrahydrofuran, dichloromethane and dimethylsulfoxide. The Balankina’s relative excesses, Xbal, i.e. the ratios between excess and ideal quantities XE/Xid were also determined to reduce the structural impact of pure components to absolute excesses. Analysis of quantities determined shows some patterns for concentration dependences of large groups of mixtures; thus, the scheme for influence of anion or cation of Ionic Liquids and solvent on Balankina’s relative excesses was proposed. It seems that presented analysis provide the knowledge about absolute and relative excess quantities for other mixtures without doing the experimental work. It is also visible that analysis of excess molar quantities and Xbal parameters can support the interpretation of interactions which occur between Ionic Liquids and solvent. 相似文献
173.
Anneli Kruve Riin Rebane Karin Kipper Maarja-Liisa Oldekop Hanno Evard Koit Herodes Pekka Ravio Ivo Leito 《Analytica chimica acta》2015
This is the part I of a tutorial review intending to give an overview of the state of the art of method validation in liquid chromatography mass spectrometry (LC–MS) and discuss specific issues that arise with MS (and MS/MS) detection in LC (as opposed to the “conventional” detectors). The Part I briefly introduces the principles of operation of LC–MS (emphasizing the aspects important from the validation point of view, in particular the ionization process and ionization suppression/enhancement); reviews the main validation guideline documents and discusses in detail the following performance parameters: selectivity/specificity/identity, ruggedness/robustness, limit of detection, limit of quantification, decision limit and detection capability. With every method performance characteristic its essence and terminology are addressed, the current status of treating it is reviewed and recommendations are given, how to determine it, specifically in the case of LC–MS methods. 相似文献
174.
许兴业 《高校应用数学学报(A辑)》2017,32(4)
研究一类奇异非线性多重调和方程?~mu=f(|x|,u,|▽u|)u~(-β),给出了方程存在正的径向对称整体解的充分必要条件和解的性质. 相似文献
175.
《Journal of separation science》2017,40(21):4191-4202
Psoraleae Fructus is one of the most popular traditional Chinese medicines. Coumarins, flavonoids, and meroterpenes are the main contributors to the biological activity of Psoraleae Fructus. In this study, a new method for the quality control of Psoraleae Fructus was developed, through the quantitative analysis of multicomponents by single marker with diode array detector. Thirteen components, including psoralenoside, isopsoralenoside, psoralen, isopsoralen, psoralidin, neobavaisoflavone, bavachin, corylin, isobavachalcone, corylifol A, bavachinin, bavachalcone, and bakuchiol were rapidly separated and identified within 12 min by the newly developed method. The feasibility and reliability of this method were corroborated. The method was also compared to the external standard method and detection by corona charged aerosol detector. The results of percent difference (%) and cos (θ) have shown that there were no significant differences observed between the quantitative analysis of multicomponents by single marker and external standard method analyses; psoralen and isopsoralen were undetectable with the corona charged aerosol detector due to their but the sensitivity for all the compounds except bakuchiol detected by corona charged aerosol detector are higher than those obtained by diode array detector. In addition, the newly method developed was applied to the quality evaluation of Chinese patent medicines containing Psoraleae Fructus. 相似文献
176.
我们研究了由仅有实零点的代数多项式导出的微分算子确定的广义Sobolev类利用指数型整函数作为逼近工具的最佳限制逼近问题.利用Fourier变换和周期化等方法,得到在L_2(R)范数下的广义Sobolev光滑函数类的相对平均宽度和最佳限制逼近的精确常数,以及当0是这个代数多项式的一个至多2重的零点时,得到最佳限制逼近在L_1(R)范数和一致范数下的广义Sobolev类的精确到阶的结果. 相似文献
177.
《Mathematische Nachrichten》2017,290(11-12):1732-1752
This paper provides various “contractivity” results for linear operators of the form where C are positive contractions on real ordered Banach spaces X . If A generates a positive contraction semigroup in Lebesgue spaces , we show (M. Pierre's result) that is a “contraction on the positive cone ”, i.e. for all provided that . We show also that this result is not true for 1 ⩽ . We give an extension of M. Pierre's result to general ordered Banach spaces X under a suitable uniform monotony assumption on the duality map on the positive cone . We deduce from this result that, in such spaces, is a contraction on for any positive projection C with norm 1. We give also a direct proof (by E. Ricard) of this last result if additionally the norm is smooth on the positive cone. For any positive contraction C on base‐norm spaces X (e.g. in real spaces or in preduals of hermitian part of von Neumann algebras), we show that for all where N is the canonical half‐norm in X . For any positive contraction C on order‐unit spaces X (e.g. on the hermitian part of a algebra), we show that is a contraction on . Applications to relative operator bounds, ergodic projections and conditional expectations are given. 相似文献
178.
对于聚集数据的线性模型,提出了广义聚集双参数估计的概念,给出了广义聚集双参数估计的两种相对效率,并得到了这两种相对效率的上界. 相似文献
179.
V. A. Storozhenko 《International Applied Mechanics》2003,39(12):1464-1472
A technique is proposed to identify the principal central axis of inertia in a joint-suspended inhomogeneous rigid body from its vertical revolution. The problem is reduced to synchronizing the revolution of the body with the revolution of a fictitious mathematical pendulum 相似文献
180.
Dale Magnar Ekrann Steinar Mykkeltveit Johannes Virnovsky George 《Transport in Porous Media》1997,26(3):229-260
The paper presents an analytical construction of effective two-phase parameters for one-dimensional heterogeneous porous media, and studies their properties. We base the computation of effective parameters on analytical solutions for steady-state saturation distributions. Special care has to be taken with respect to saturation and pressure discontinuities at the interface between different rocks. The ensuing effective relative permeabilities and effective capillary pressure will be functions of rate, flow direction, fluid viscosities, and spatial scale of the heterogeneities.The applicability of the effective parameters in dynamic displacement situations is studied by comparing fine-gridded simulations in heterogeneous media with simulations in their homogeneous (effective) counterparts. Performance is quite satisfactory, even with strong fronts present. Also, we report computations studying the applicability of capillary limit parameters outside the strict limit. 相似文献